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    • 45. 发明申请
    • VISIBLE LIGHT CURABLE FREE RADICAL COMPOSITIONS CONTAINING 'pi'-ARENE METAL COMPLEXES
    • 可见光可固化自由基组合物,含有金属复合物
    • WO1988002879A1
    • 1988-04-21
    • PCT/US1987002619
    • 1987-10-13
    • LOCTITE CORPORATION
    • LOCTITE CORPORATIONWOODS, JohnROONEY, John, M.COAKLEY, Mary, P.
    • G03C01/68
    • C08G75/045C08F2/50G03F7/029
    • A visible light polymerisable composition comprises 1) free radically polymerisable material such as one or more monomers and/or prepolymers containing acrylate or methacrylate groups or a copolymerisable monomer combination based on a polythiol and a polyene. 2) a p-arene metal complex of formula (I), where a stands for 1 or 2 and n and q independently of each other each stand for an integer from 1 to 3, M is the cation of a monovalent to trivalent metal from groups IVb, VIIb, VIII or Ib of the periodic system, m is an integer corresponding to the valence of L + q, Q is a halogen and L is a metal or nonmetal with a valence of 2 to 7, R is a pi -arene and R is a pi -arene or the anion of a pi -arene. 3) a free radical rate accelerator such as a peroxide or hydroperoxide compound. More particularly, the pi -arene metal complex is a complex salt of a eta , eta iron arene cation and a non-nucleophilic anion, which is of formula (VII), where R is a eta arene selected from benzene, alkyl benzenes, alkyloxybenzenes, halobenzenes, haloalkylbenzenes, naphthalene, alkoxynaphthalenes, alkylnaphthalenes, halonaphthalenes, biphenyl, indene, pyrene or diphenylsulphide; R is the anion of a cyclopentadienyl compound, L is di- to heptavalent metal or metaloid, Z is a halogen and k is equal to 1 plus the valence of L.
    • 可见光可聚合组合物包含1)可自由基聚合的材料,例如含有丙烯酸酯或甲基丙烯酸酯基团的一种或多种单体和/或预聚物或基于多硫醇和多烯的可共聚单体组合。 2)式(I)的对芳族金属络合物,其中a代表1或2,n和q彼此独立地代表1至3的整数,M是一价至三价金属的阳离子 第IVb,VIIb,VIII或Ib族,m是对应于L + q的化合价的整数,Q是卤素,L是金属或非金属,价数为2至7,R 1为 一个芳基和一个R 2是一个仲芳基或一个芳香族的阴离子。 3)自由基速率促进剂如过氧化氢或过氧化氢化合物。 更具体地,所述π-芳族金属络合物是η6,η5铁芳族阳离子和非亲核阴离子的复合盐,其具有式(VII),其中R 6是η 选自苯,烷基苯,烷氧基苯,卤代苯,卤代烷基苯,萘,烷氧基萘,烷基萘,卤萘,联苯,茚,芘或二苯硫醚的芳烃; R 7是环戊二烯基化合物的阴离子,L是二价至七价金属或金属络合物,Z是卤素,k等于1加上L的化合价。
    • 46. 发明申请
    • POTTED ELECTRICAL/MECHANICAL DEVICES, AND DUAL CURE POTTING METHOD
    • 电动/机械装置和双固定方法
    • WO1988000135A1
    • 1988-01-14
    • PCT/US1987001593
    • 1987-07-02
    • LOCTITE CORPORATIONDRAIN, Kieran, FrancisNATIVI, Larry, Armand
    • LOCTITE CORPORATION
    • B32B27/16
    • H01C1/034B29C35/02B29C39/10B29C70/72B29C2035/0827B29C2035/0833B29C2791/001B29K2033/08B29K2063/00B29K2105/0088B29L2031/3406G01F15/006H01B3/302H01B3/40H01B3/44H05K5/0095
    • A device, e.g., an electrical or electromechanical assembly (62), comprising a housing (64) with a mechanism (66) disposed therein which is potted by a cured mass of self-leveling liquid composition. The composition comprises an actinic radiation cured first resin component (102) preferably (meth)acrylate resins, which immobilize the partially cured mass, and a subsequently cured second resin component (100), preferably epoxy resins, which is non-cured under the actinic radiation but curable at ambient or elevated temperature. Depending on the depth of the composition which is to be cured in the housing, it may be desirable to utilize the self-leveling liquid composition as either a single homogeneous mixture of the first and second resin components, or, where the depth of the housing is greater than the depth of UV penetration, as cured mass wherein the first resin component is in a separate and discrete resin layer overlying a lower resin layer containing the second resin component but not the first resin component.
    • 一种装置,例如电气或机电组件(62),其包括具有设置在其中的机构(66)的壳体(64),其被固化的自流平液体组合物封装。 该组合物包含光固化辐射固化的第一树脂组分(102),优选(甲基)丙烯酸酯树脂,其固定部分固化的物质,以及随后固化的第二树脂组分(100),优选环氧树脂,其在光化反应下未固化 辐射,但可在环境温度或高温下固化。 根据要在壳体中固化的组合物的深度,可能希望将自流平液体组合物用作第一和第二树脂组分的单一均匀混合物,或者其中壳体的深度 大于紫外线穿透的深度,作为固化物质,其中第一树脂组分位于包含含有第二树脂组分而不是第一树脂组分的下树脂层的分离和分散的树脂层中。