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31. 发明申请

WO2012094045A2 LAYER-BY-LAYER REMOVAL OF GRAPHENE 审中-公开
标题翻译：逐层去除石墨
公开(公告)号：WO2012094045A2
公开(公告)日：2012-07-12
申请号：PCT/US2011/055747
申请日：2011-10-11
申请人： WILLIAM MARSH RICE UNIVERSITY , TOUR, James, M. , DIMIEV, Ayrat, M. , KOSYNKIN, Dmitry, V.
发明人： TOUR, James, M. , DIMIEV, Ayrat, M. , KOSYNKIN, Dmitry, V.
IPC分类号： C01B31/04
CPC分类号： C01B31/0484 , B82Y30/00 , B82Y40/00 , C01B32/182 , C01B32/19 , C01B32/192 , C01B32/194 , H01L21/30604 , H01L21/3085
摘要： The present invention provides methods of selectively removing one or more graphene layers from a graphene material by: (1) applying a metal to a surface of the graphene material; and (2) applying a hydrogen containing solution to the surface of the graphene material that is associated with the metal. The hydrogen containing solution dissolves the metal along with one or more layers of graphene associated with the metal, thereby removing the layer(s) of graphene from the graphene material. In some embodiments, the hydrogen containing solution is an acidic solution, such as hydrochloric acid. In some embodiments, the metal is zinc. In some embodiments, the methods of the present invention are utilized to selectively remove one or more layers of graphene from one or more targeted sites on the surface of a graphene material.
摘要翻译：本发明提供了通过以下步骤从石墨烯材料中选择性地去除一个或多个石墨烯层的方法：（1）将金属施加到石墨烯材料的表面; 和（2）将含氢溶液施加到与金属相关联的石墨烯材料的表面。含氢溶液与一个或多个与金属相关的石墨烯层一起溶解金属，从而从石墨烯材料去除石墨烯层。在一些实施方案中，含氢溶液是酸性溶液，例如盐酸。在一些实施方案中，金属是锌。在一些实施方案中，本发明的方法用于从石墨烯材料表面上的一个或多个目标位点选择性地除去一层或多层石墨烯。

32. 发明申请

WO2012083533A1 氟化石墨烯及其制备方法审中-公开
公开(公告)号：WO2012083533A1
公开(公告)日：2012-06-28
申请号：PCT/CN2010/080123
申请日：2010-12-22
申请人：海洋王照明科技股份有限公司 , 周明杰 , 刘大喜 , 王要兵
发明人：周明杰 , 刘大喜 , 王要兵
IPC分类号： C01B31/02
CPC分类号： C01B31/0484 , B82Y30/00 , B82Y40/00 , C01B32/182 , C01B32/192 , C01B32/194 , C01B32/23

33. 发明申请

WO2010030361A1 MESOPOROUS METAL OXIDE GRAPHENE NANOCOMPOSITE MATERIALS 审中-公开
标题翻译： MOPOPOROUS金属氧化物石墨纳米复合材料
公开(公告)号：WO2010030361A1
公开(公告)日：2010-03-18
申请号：PCT/US2009/005085
申请日：2009-09-09
申请人： BATTELLE MEMORIAL INSTITUTE , THE TRUSTEES OF PRINCETON UNIVERSITY , JUN, Liu , AKSAY, Iihan, A. , KOU, Rong , WANG, Donghai
发明人： JUN, Liu , AKSAY, Iihan, A. , KOU, Rong , WANG, Donghai
IPC分类号： C01B31/02 , C01B31/04 , H01M10/00 , H01M10/36 , H01M16/00 , H01M10/052
CPC分类号： C01B31/0484 , B82Y30/00 , B82Y40/00 , C01B32/194 , H01G11/36 , H01G11/46 , H01M4/92 , H01M4/926 , Y02E60/13 , Y10T428/249978 , Y10T428/24999
摘要： A nanocomposite material formed of graphene and a mesoporous metal oxide having a demonstrated specific capacity of more than 200 F/g with particular utility when employed in supercapacitor applications. A method for making these nanocomposite materials by first forming a mixture of graphene, a surfactant, and a metal oxide precursor, precipitating the metal oxide precursor with the surfactant from the mixture to form a mesoporous metal oxide. The mesoporous metal oxide is then deposited onto a surface of the graphene.
摘要翻译：由石墨烯和中孔金属氧化物形成的纳米复合材料，其具有超过200F / g的特异性容量，并且在超级电容器应用中具有特别的用途。一种通过首先形成石墨烯，表面活性剂和金属氧化物前体的混合物来制备这些纳米复合材料的方法，从混合物中用表面活性剂沉淀金属氧化物前体以形成中孔金属氧化物。然后将介孔金属氧化物沉积到石墨烯的表面上。

34. 发明申请

WO2016072959A1 METHOD FOR CARBON MATERIALS SURFACE MODIFICATION BY THE FLUOROCARBONS AND DERIVATIVES 审中-公开
标题翻译：用碳氟化合物和衍生物对碳材料表面进行改性的方法
公开(公告)号：WO2016072959A1
公开(公告)日：2016-05-12
申请号：PCT/UA2015000104
申请日：2015-11-03
申请人： ZADERKO ALEXANDER , PRUSOV VASYL , DIYUK VITALIY
发明人： ZADERKO ALEXANDER
IPC分类号： C01B31/00 , C01B31/04
CPC分类号： C01B31/005 , B82Y30/00 , B82Y40/00 , C01B31/0253 , C01B31/0484 , C01B31/083 , C01B32/00 , C01B32/10 , C01B32/168 , C01B32/194 , C01B32/354 , C01B2202/06 , C07C17/281 , C09C1/56 , Y10S977/748 , Y10S977/752 , Y10S977/847
摘要： A chemical vapor deposition method for fluorine-containing carbon materials preparation provided. The claimed method comprises treating of carbons with fluorocarbons or derivatives that passes at a moderate high temperature. The fluorine-containing carbon materials show hydrophobicity, high thermal stability and can be used as catalysts support, lithium battery anodes, and hydrophobic materials or as surface precursor. Surface fluorine characterized by intensive signal in the XPS spectrum, found in a range of 685- 687 eV. Obtained fluoro-containing functionalities is stable at a temperature about 1000 °C.
摘要翻译：提供一种用于含氟碳材料制备的化学气相沉积方法。要求保护的方法包括用碳氟化合物或在中等高温下通过的衍生物处理碳。含氟碳材料具有疏水性，热稳定性高，可用作催化剂载体，锂电池阳极，疏水材料或表面前驱体。表面氟的特征是在XPS光谱中有强烈的信号，发现其范围为685-687 eV。获得的含氟官能团在约1000℃的温度下稳定。

35. 发明申请

WO2016066843A1 HIERARCHICAL COMPOSITE STRUCTURES BASED ON GRAPHENE FOAM OR GRAPHENE-LIKE FOAM 审中-公开
标题翻译：基于石墨泡沫或类似石墨的泡沫的分层复合结构
公开(公告)号：WO2016066843A1
公开(公告)日：2016-05-06
申请号：PCT/EP2015/075347
申请日：2015-10-30
申请人： REPSOL, S.A.
发明人： PEDRÓS, Jorge , BOSCÁ, Alberto , MARTÍNEZ, Javier , CALLE, Fernando , RUIZ-GÓMEZ, Sandra , PÉREZ, Lucas , BARRANCO, Violeta , PÁEZ DUEÑAS, Antonio , SAN LUIS, Jesús García
IPC分类号： C04B35/52 , C01B31/02 , C01B31/04 , C04B35/528 , C04B38/00 , H01G11/24 , H01G11/26 , H01G11/32 , H01G11/48 , H01M4/04 , H01M4/583 , H01M4/66
CPC分类号： H01M4/667 , C01B31/0453 , C01B31/0484 , C01B32/186 , C01B32/194 , C01B2204/22 , C01P2006/40 , C04B35/522 , C04B38/0022 , C04B38/0032 , C04B38/0096 , C04B2235/6028 , H01G11/24 , H01G11/26 , H01G11/32 , H01G11/48 , H01G11/52 , H01G11/86 , H01M4/0416 , H01M4/0452 , H01M4/0459 , H01M4/583 , H01M4/602 , H01M4/663 , H01M4/665 , H01M4/808 , Y02E60/13 , Y02T10/7022
摘要： The present invention relates to a hierarchical composite structure comprising an open cell graphene foam or graphene-like foam, wherein the graphene foam or graphene-like foam is coated with a conductive nanoporous spongy structure and wherein at least 10% v/v of the hollow of the pores of the graphene foam or graphene-like foam is filled with the conductive nanoporous spongy structure. The invention also relates to a process for preparing a hierarchical composite structure wherein a conductive nanoporous spongy structure is electrodeposited so as to coat the open-cell graphene foam or graphene-like foam and to partially fill the hollow of the pores of the graphene foam or graphene-like foam.
摘要翻译：本发明涉及包括开孔石墨烯泡沫或石墨烯类泡沫的分级复合结构，其中所述石墨烯泡沫或石墨烯类泡沫涂覆有导电纳米多孔海绵结构，并且其中至少10％v / v的所述中空的石墨烯泡沫或石墨烯状泡沫的孔填充有导电纳米孔隙海绵结构。本发明还涉及一种制备分级复合结构的方法，其中电沉积导电纳米多孔海绵结构以便涂覆开孔的石墨烯泡沫或石墨烯状泡沫，并部分填充石墨烯泡沫的孔的中空部分石墨烯样泡沫。

36. 发明申请

WO2016027934A1 그래핀-실리콘 양자점 하이브리드 구조를 이용한 포토 다이오드 및 그 제조방법 审中-公开
标题翻译：使用石墨硅量子掺杂结构的光致抗体及其制备方法
公开(公告)号：WO2016027934A1
公开(公告)日：2016-02-25
申请号：PCT/KR2014/011176
申请日：2014-11-20
申请人： 경희대학교산학협력단
发明人： 최석호 , 신동희 , 김성
IPC分类号： H01L31/10 , C01B31/04
CPC分类号： H01L31/1804 , B82Y30/00 , B82Y40/00 , C01B31/0453 , C01B31/0484 , C01B32/182 , H01L31/0288 , H01L31/035218 , H01L31/03529 , H01L31/0384 , H01L31/09 , H01L31/10 , H01L31/109 , Y10S977/734 , Y10S977/774 , Y10S977/814 , Y10S977/843 , Y10S977/847 , Y10S977/89 , Y10S977/896 , Y10S977/948
摘要： 실리콘 양자점의 사이즈와, 그래핀의 도핑 농도의 제어를 통하여 광학적 특성 및 전기적 특성을 향상시킨 그래핀-실리콘 양자점 하이브리드 구조를 포함하는 포토 다이오드를 제공한다. 본 발명의 그래핀-실리콘 양자점 하이브리드 구조를 포함하는 포토 다이오드는 제작이 용이하고, 대면적 제작이 가능하며 자외선 영역에서 근적외선 영역까지 광검출 대역이 넓고, 선택적으로 흡수 에너지의 조절이 가능하다.
摘要翻译：提供了包括石墨烯 - 硅量子点混合结构的光电二极管，通过控制硅量子点的尺寸和石墨烯的掺杂浓度，光电二极管具有增强的光学特性和电性能。包括石墨烯 - 硅量子点混合结构的光电二极管能够容易地制造，大面积制造和选择性地控制吸收的能量，并且具有从紫外区域到近红外区域的宽的光检测带。

37. 发明申请

WO2015026181A1 그래핀의 개질 방법 및 장치 审中-公开
标题翻译：用于修饰石墨的方法和装置
公开(公告)号：WO2015026181A1
公开(公告)日：2015-02-26
申请号：PCT/KR2014/007785
申请日：2014-08-21
申请人： 한화케미칼 주식회사
发明人： 도승회 , 이진서 , 전성윤 , 공정호
IPC分类号： C01B31/02 , B01J19/24
CPC分类号： C01B31/0484 , B01J8/02 , B01J2208/00539 , B01J2208/024 , C01B32/194 , C01B2204/22 , C01B2204/32 , Y02P20/544
摘要： 본 발명은 그래핀의 개질 방법 및 장치에 관한 것이다. 보다 상세하게는, 아임계 또는 초임계 이산화탄소에 의한 그래핀의 개질 과정을 여러 번 반복하여 목적하는 결정 크기의 그래핀을 얻을 수 있는 그래핀의 개질 방법 및 장치에 관한 것이다. 본 발명의 그래핀 개질 방법 및 장치에 따르면, 전기전도도 및 분산성이 우수한 그래핀을 얻을 수 있다.
摘要翻译：本发明涉及一种用于修饰石墨烯的方法和装置，更具体地说，涉及一种用于通过用亚临界或超临界二氧化碳重复石墨烯改性工艺几次来获得具有所需晶体尺寸的石墨烯来修饰石墨烯的方法和装置。根据本发明的石墨烯改性方法和装置，可以获得具有显着的导电性和分散性的石墨烯。

38. 发明申请

WO2014188454A1 PROCESS FOR PREPARATION OF NANOPOROUS GRAPHENE AND GRAPHENE QUANTUM DOTS 审中-公开
标题翻译：制备纳米石墨和石墨量子的方法
公开(公告)号：WO2014188454A1
公开(公告)日：2014-11-27
申请号：PCT/IN2014/000354
申请日：2014-05-26
申请人： COUNCIL OF SCIENTIFIC AND INDUSTRIAL RESEARCH
发明人： KURUNGOT, Sreekumar , PALANISELVAM, Thangavelu
IPC分类号： C01B31/04 , B82Y40/00
CPC分类号： C01B31/0484 , B01J20/20 , B82Y40/00 , C01B32/182 , C01B32/184 , C01B32/194 , C01B2204/02 , C01B2204/065 , C01B2204/32 , H01M4/96 , Y02E60/324 , Y10S977/774
摘要： The present invention discloses a simple and easily scalable process for preparation of two potentially value added carbonaceous materials from graphene. The invention further discloses simultaneous preparation of graphene quantum dots (GQDs,) and porous graphene (pGr) from graphene. The invention further relates to nitrogen doped porous graphene having excellent activity towards electrochemical oxygen reduction reaction (ORR).
摘要翻译：本发明公开了一种用于从石墨烯制备两种潜在的增值碳质材料的简单且易于扩展的方法。本发明还公开了从石墨烯同时制备石墨烯量子点（GQDs）和多孔石墨烯（pGr）。本发明还涉及对电化学氧还原反应（ORR）具有优异活性的氮掺杂多孔石墨烯。

39. 发明申请

WO2014135455A1 CONCENTRATED WATER DISPERSION OF GRAPHENE AND METHOD FOR THE PREPARATION THEREOF 审中-公开
标题翻译：浓缩水分散石墨及其制备方法
公开(公告)号：WO2014135455A1
公开(公告)日：2014-09-12
申请号：PCT/EP2014/053966
申请日：2014-02-28
申请人： DIRECTA PLUS S.P.A.
发明人： CESAREO, Giulio , PARRINI, Maria Riccardo , RIZZI, Laura Giorgia
IPC分类号： C01B31/04
CPC分类号： C01B31/0484 , B82Y30/00 , B82Y40/00 , C01B32/19 , C01B32/194 , C01B2204/32 , C08K3/04 , C08K3/042 , C09D7/61 , D06M11/74
摘要： Concentrated dispersion from 5 to 50 % by weight of nanoparticles of graphene in water with a lateral size from 10 to 5000 nm and thickness from 0.34 to 30 nm. The production process comprises the dispersion in water of flakes of expanded graphite and the subsequent treatment with ultrasounds at an energy level of from 100 to 2000 W for a period from 1 to 100 hours.
摘要翻译： 5至50重量％浓度的分散体，其水中的石墨烯纳米颗粒的横向尺寸为10至5000nm，厚度为0.34至30nm。生产方法包括在膨胀石墨薄片的水中分散，然后用100至2000W的能量水平进行超声波处理1至100小时。

40. 发明申请

WO2014015173A1 SPIRAL DESIGN GRAPHENE NANORIBBON 审中-公开
标题翻译：螺旋设计石墨NANORIBBON
公开(公告)号：WO2014015173A1
公开(公告)日：2014-01-23
申请号：PCT/US2013/051134
申请日：2013-07-18
申请人： LOCKHEED MARTIN CORPORATION
发明人： SCHWARTZ, Rebecca , GARGA, Amulya
IPC分类号： C01B31/04
CPC分类号： C01B31/0484 , C01B32/184 , C01B2204/06
摘要： Graphene nanoribbons and methods for fabricating graphene nanoribbons, particularly those with long lengths, are provided. In one embodiment, a method (400) for fabricating a graphene nanoribbon (100) includes preparing (410) a mask for application on a substrate (102). The mask may include a continuous line of masking material spiraling outward from a first end (104) of the line to a second end (106). The method (400) also includes depositing (420) a graphene layer (108) over a top surface (102A) of the substrate (102), applying (430) the mask to the substrate (102) over the graphene layer (108), removing (440) an unmasked portion of the graphene layer (108), and removing (450) the masking material from a remaining portion of the graphene layer (108) to leave a continuous line of graphene on the surface (102A) of the substrate (100) corresponding with the mask.
摘要翻译：提供石墨烯纳米带和制造石墨烯纳米带的方法，特别是长度长的那些。在一个实施例中，用于制造石墨烯纳米棒（100）的方法（400）包括制备（410）掩模以施加在基底（102）上。掩模可以包括从线的第一端（104）向外螺旋到第二端（106）的连续的掩模材料线。所述方法（400）还包括在所述基底（102）的顶表面（102A）上沉积（420）石墨烯层（108），将所述掩模施加到所述石墨烯层（108）上的所述基底（102）去除（440）所述石墨烯层（108）的未掩蔽部分，以及从所述石墨烯层（108）的剩余部分去除（450）所述掩蔽材料，以在所述石墨烯层（108）的表面（102A）上留下连续的石墨烯线衬底（100）。

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