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    • 32. 发明申请
    • COATING AGENT, ITS USE AND PROCESS FOR PRODUCING MULTILAYERED COATINGS
    • 涂层剂,它们的使用和工艺生产复合涂层
    • WO1997006197A1
    • 1997-02-20
    • PCT/EP1996003402
    • 1996-08-02
    • HERBERTS GESELLSCHAFT MIT BESCHRÄNKTER HAFTUNGFLOSBACH, CarmenHERRMANN, FriedrichKERBER, HermannREIFFERSCHEIDT, Heinz-WalterSCHLOESSER, CarmenSCHUBERT, Walter
    • HERBERTS GESELLSCHAFT MIT BESCHRÄNKTER HAFTUNG
    • C08G18/62
    • C08G18/6204C08G18/6229
    • A coating agent useful for producing multilayered stove-coatings contains as binder: (A) 20 to 40 % by weight of a hydroxyfunctional (meth)acrylic copolymer obtained from styrene and/or styrene derivatives; hydroxyethyl-, hydroxypropyl- and/or hydroxybutyl(meth)acrylate; non-functionalised (cyclo)alkyl(meth)acrylates with 8 to 18 C atoms in the (cyclo)alkyl rest; (meth)acrylic acid and optionally non-functionalised (cyclo)alkyl(meth)acrylates with up to 7 C atoms in the (cyclo)alkyl rest; (B) 20 to 40 % by weight hydroxyfunctional (meth)acrylic copolymers obtained from hydroxyethyl-, hydroxypropyl- and/or hydroxybutyl(meth)acrylate; non-functionalised (cyclo)alkyl(meth)acrylates with 8 to 18 C atoms in the (cyclo)alkyl rest; non-functionalised (cyclo)alkyl(meth)acrylates with up to 7 C atoms in the (cyclo)alkyl rest and (meth)acrylic acid; (C) 0 to 40 % by weight of a hydroxyfunctional binder different from (A) and (B); (D) 10 to 50 % by weight free or blocked polyisocyanates; and (E) 0 to 40 % by weight triazine-based constituents that can be cross-linked with the hydroxyl groups of constituents (A), (B) and optionally (C), forming ether and/or ester groups.
    • WT A)20至40 .-%的羟基官能(甲基)丙烯酸共聚物,由苯乙烯和/或苯乙烯衍生物获得;含有作为粘合剂用于老化多层涂层合适的包衣剂 羟乙基,羟丙基和/或羟丁基(甲基)丙烯酸酯; 非官能化的(环)烷基(甲基)丙烯酸烷基具有8至在(环)小于18个碳原子; (甲基)丙烯酸以及任选的非官能化的(环)烷基(甲基)丙烯酸酯,具有至多7个碳原子的(环)烷基; B)20〜40重量%的羟基官能(甲基)丙烯酸共聚物,可得(从羟乙基,羟丙基和/或羟丁基甲基)丙烯酸酯; 非官能化的(环)烷基(甲基)丙烯酸烷基具有8至在(环)小于18个碳原子; 非官能化的(环)烷基(甲基)丙烯酸酯具有至多在(环)7个碳原子的烷基和(甲基)丙烯酸; C)0至40重量A的%)和B)的不同羟基官能的粘合剂; D)10至50重量的游离或封端多异氰酸酯%; 和E)0〜40重量%与A成分中的羟基基团),B)和任选的C),醚和/或酯基团的交联形成的三嗪类的组件。
    • 35. 发明申请
    • COATING AGENT- THE MANUFACTURE AND USE THEREOF
    • 涂层剂,生产和使用
    • WO1998027172A1
    • 1998-06-25
    • PCT/EP1997006911
    • 1997-12-11
    • HERBERTS GESELLSCHAFT MIT BESCHRÄNKTER HAFTUNGDUECOFFRE, VolkerSCHUBERT, WalterHERRMANN, FriedrichFLOSBACH, CarmenLECKEBUSCH, Claudia
    • HERBERTS GESELLSCHAFT MIT BESCHRÄNKTER HAFTUNG
    • C09D133/00
    • C09D133/064C08G18/4063C08G18/6258C08L33/064C08L33/068C09D133/068C08L2666/04
    • The invention relates to a coating agent for multi-layer enamel with a bonding agent composition containing: a) 25-75 wt. % carboxy-functional (meth)acryl copolymers and/or carboxy-functional polyesters, whose carboxy-functionality corresponds to an acid number ranging from 15-300 mg KOH/g; b) 25-75 wt. % epoxide functionalized cross-linking agent resins of which at least one is a (meth)acryl copolymer produced by additionally using a tertiary butyl (meth)acrylate; c) 0-60 wt % polyols with at least two hydroxyl functions in the molecule; d) 0-40 wt % constituents cross-linking with hydroxyl groups and thus forming ether and/or a triazine-based cross-linking agent; e) 0-40 wt. % polyisocyanates; f) 0-60 wt. % of at least one organic polyanhydride with at least two cyclic carboxylic acid anhydride groups per molecule; g) 0-20 wt. % reactive diluent with an epoxy function; h) 0-10 wt. % catalysts for the reaction of the carboxyl and epoxide groups.
    • 对于多层涂层具有包含粘合剂组合物合适的涂布剂:A)25至75重量%的羧基官能的(甲基)丙烯酸共聚物和/或carboxyfunkionelle聚酯,其羧基功能对应于15至300毫克KOH / g的酸值,B)25至75 重量%的环氧官能化的交联树脂,其的一(甲基)丙烯酸类共聚物中的至少一种取与伴随使用叔丁基(甲基)丙烯酸酯的制备,C)0至在分子中具有至少两个羟基官能团40度%(重量)的多元醇,D) 0至40重量%的羟基基团与下交联组分醚的形成和/或基于三嗪交联剂,E)0至40重量%的多异氰酸酯,F)0至60重量%的至少一种具有有机聚酐的至少两个环型的羧酸的% 每分子,G)为0〜20,其具有从0环氧函数,H)到10升重量%的催化剂的羧基和环氧基团的反应重量%反应性稀释剂 ,
    • 36. 发明申请
    • AQUEOUS TWO-COMPONENT COATING AGENT AND USE THEREOF
    • 水性双组分涂层剂及其使用
    • WO1998018875A1
    • 1998-05-07
    • PCT/EP1997005791
    • 1997-10-21
    • HERBERTS GESELLSCHAFT MIT BESCHRÄNKTER HAFTUNGGOECKE, StefanieSCHREIBER, PeterWINDMANN, Reinhard
    • HERBERTS GESELLSCHAFT MIT BESCHRÄNKTER HAFTUNG
    • C09D175/04
    • C08J7/047C08G18/0819C08J2475/00C08L2201/04C09D175/04C08L23/00C08L23/26
    • The invention concerns an aqueous two-component coating agent based on one or a plurality of polyols and one or a plurality of polyisocyanates, in particular for coating plastics substrates, the polyol(s) being present in a first component and the polyisocyanate(s) being present in a second component and the components being combined before application. When the components have been combined, the coating agent comprises the following constituents: between 10 and 40 wt % of one or a plurality of polyols with a number average of the molecular mass of between 300 and 2,000,000, an OH number of between 10 and 400 mg KOH/g and a content of up to 400 milliequivalents/100g of solid resin of ionic groups and/or groups which can be converted into ionic groups; between 0.5 and 10 wt % of one or a plurality of chlorinated and/or unchlorinated polyolefins; between 1 and 35 wt % of electrically conductive pigments and/or fillers; between 5 and 30 wt % of one or a plurality of organic solvents; between 25 and 75 wt % water; and between 1 and 30 wt % polyisocyanates with an average of at least two free isocyanate groups per molecule, the total of these constituents being 100 wt % and the quantitative proportion between the polyisocyanate component and the polyol component being such that the ratio between the number of reactive NCO groups and the number of OH groups is between 5:1 and 0.5:1.
    • 本发明涉及基于一种或多种多元醇与一种或多种多异氰酸酯的水性双成分涂料组合物,特别是用于涂覆塑料基材,其中,在第一组分中的一种或多种多元醇以及已知的或在第二组分中的多异氰酸酯和所述部件之前 应用组合。 涂布剂中含有后Vereiningung成分的下述成分:10〜40重量%的一种或多种多元醇的%具有300的数均分子量为200万,10至400mg KOH / g的OH值和的一个内容 400毫当量/ 100g的离子基团和/或可转化为离子基团的基团的固体树脂; 为0.5〜10重量的一种或多种氯化和/或氯化的聚烯烃%; 1〜35重量导电颜料和/或填料的%; 5〜30重量%的一种或多种有机溶剂的%; 25至75重量%的水; 和具有每分子平均至少两个游离异氰酸酯基团为1〜30重量%多异氰酸酯,上述成分的总和为100重量%,被选择为使得反应性NCO的数量多异氰酸酯组分和多元醇组分的量比 基团与OH基团的在5:1的比率的数量:1到0.5:1。