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31. 发明申请

WO2012084961A1 BRIDGED METALLOCENE CATALYSTS 审中-公开
标题翻译： BRIDGED METALLOCENE催化剂
公开(公告)号：WO2012084961A1
公开(公告)日：2012-06-28
申请号：PCT/EP2011/073426
申请日：2011-12-20
申请人： BOREALIS AG , RESCONI, Luigi , CASTRO, Pascal , VOSKOBOYNIKOV, Alexander Z , IZMER, Vyatcheslav V , KONOVICH, Dmitry S
发明人： RESCONI, Luigi , CASTRO, Pascal , VOSKOBOYNIKOV, Alexander Z , IZMER, Vyatcheslav V , KONOVICH, Dmitry S
IPC分类号： C08F10/00 , C08F4/6592
CPC分类号： C08F4/76 , B01J31/2295 , B01J2231/122 , B01J2531/48 , B01J2531/49 , C07F17/00 , C08F4/52 , C08F4/65908 , C08F4/65927 , C08F10/00 , C08F110/06 , C08F210/06 , C08F4/65912 , C08F2500/03 , C08F2500/12 , C08F210/16
摘要： A solid, particulate catalyst comprising: (i) a complex of formula (I) wherein M is zirconium or hafnium; each X is a sigma ligand; L is a divalent bridge selected from -R '2 C-, -R' 2 C-CR' 2 -, -R' 2 Si-, -R' 2 Si-SiR' 2 -, -R' 2 Ge-, wherein each R' is independently a hydrogen atom, C1-C20-hydrocarbyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl; each R 1 is a C4-C20 hydrocarbyl radical branched at the β-atom to the cyclopentadienyl ring, optionally containing one or more heteroatoms belonging to groups 14-16, or is a C3-C20 hydrocarbyl radical branched at the β-atom to the cyclopentadienyl ring where the β-atom is an Si-atom; each R 18 is a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; each R 4 is a hydrogen atom or a C 1-6 -hydrocarbyl radical; each W is a 5 or 6 membered aryl or heteroaryl ring wherein each atom of said ring is optionally substituted with at least one R 5 group; each R 5 is the same or different and is a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; and optionally two adjacent R 5 groups taken together can form a further mono or multicyclic ring condensed to W optionally substituted by one or two groups R 5 ; and each R 7 is a C1-C20 hydrocarbyl radical; and (ii) a cocatalyst, preferably comprising an organometallic compound of a Group 13 metal.
摘要翻译：一种固体颗粒催化剂，其包含：（i）式（I）的络合物，其中M为锆或铪; 每个X是σ配体; L是选自-R'2C-，-R'2C-CR'2-，-R'2Si-，-R'2Si-SiR'2-，-R'2Ge-的二价桥，其中每个R' 独立地为氢原子，C 1 -C 20烃基，三（C 1 -C 20烷基）甲硅烷基，C 6 -C 20 - 芳基，C 7 -C 20 - 芳基烷基或C 7 -C 20 - 烷基芳基; 每个R 1是在β原子处与环戊二烯基环支链的C 4 -C 20烃基，任选地含有一个或多个属于第14-16族的杂原子，或者是在β原子处支化至环戊二烯基的C 3 -C 20烃基其中β原子是Si原子; 每个R18是任选地含有一个或多个属于第14-16族的杂原子的C1-C20烃基; 每个R 4是氢原子或C 1-6烃基; 每个W是5或6元芳基或杂芳基环，其中所述环的每个原子任选被至少一个R 5基团取代; 每个R 5相同或不同，并且是任选地含有一个或多个属于第14-16族的杂原子的C 1 -C 20烃基; 并且任选地两个相邻的R5基团可以形成另外的一个或多个环稠合成可任选地被一个或两个基团R 5取代的W 1; 并且每个R 7是C 1 -C 20烃基; 和（ii）助催化剂，优选包含第13族金属的有机金属化合物。

32. 发明申请

WO2012001052A2 CATALYSTS 审中-公开
标题翻译：催化剂
公开(公告)号：WO2012001052A2
公开(公告)日：2012-01-05
申请号：PCT/EP2011/060921
申请日：2011-06-29
申请人： BOREALIS AG , CASTRO, Pascal , RESCONI, Luigi , HUHTANEN, Lauri
发明人： CASTRO, Pascal , RESCONI, Luigi , HUHTANEN, Lauri
IPC分类号： C07F17/00 , B01J31/12
CPC分类号： C08F4/65912 , C07F17/00 , C08F4/65927 , C08F110/06 , Y10S526/943 , C08F2500/03 , C08F2500/12
摘要： A complex of formula (I): wherein M is zirconium or hafnium; each X is a sigma ligand; L is a divalent bridge selected from -R' 2 C-, -R' 2 C-CR' 2 -, -R' 2 Si-, -R' 2 Si-SiR' 2 -, -R' 2 Ge-, wherein each R' is independently a hydrogen atom, C1-C20-hydrocarbyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl; each R 1 is a C4-C20 hydrocarbyl radical branched at the β-atom to the cyclopentadienyl ring, optionally containing one or more heteroatoms belonging to groups 14-16, or is a C3-C20 hydrocarbyl radical branched at the β-atom to the cyclopentadienyl ring where the β-atom is an Si-atom; n is 0-3; each R 18 is the same or different and may be a C1 -C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; each R 4 is a hydrogen atom or a C 1-6 -hydrocarbyl radical; each W is a 5 or 6 membered aryl or heteroaryl ring wherein each atom of said ring is optionally substituted with an R 5 group each R 5 is the same or different and is a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; and optionally two adjacent R 5 groups taken together can form a further mono or multicyclic ring condensed to W optionally substituted by one or two groups R 5 .
摘要翻译：式（I）的络合物：其中M为锆或铪; 每个X是σ配体; L是选自-R'2C-，-R'2C-CR'2-，-R'2Si-，-R'2Si-SiR'2-，-R'2Ge-的二价桥，其中每个R' 独立地为氢原子，C 1 -C 20烃基，三（C 1 -C 20烷基）甲硅烷基，C 6 -C 20 - 芳基，C 7 -C 20 - 芳基烷基或C 7 -C 20 - 烷基芳基; 每个R 1是在β原子处与环戊二烯基环支链的C 4 -C 20烃基，任选地含有一个或多个属于第14-16族的杂原子，或者是在β原子处支化至环戊二烯基的C 3 -C 20烃基其中β原子是Si原子; n为0-3; 每个R 18相同或不同，并且可以是任选地含有一个或多个属于第14-16族的杂原子的C 1 -C 20烃基; 每个R 4是氢原子或C 1-6烃基; 每个W是5或6元芳基或杂芳基环，其中所述环的每个原子任选被R 5基团取代。R 5相同或不同，是任选地含有一个或多个属于第14-16族的杂原子的C 1 -C 20烃基 ; 并且任选地两个相邻的R5基团可以形成另外的单环或多环稠合至可任选被一个或两个基团R 5取代的W。

33. 发明申请

WO2018122031A1 POLYPROPYLENE COMPOSITION COMBINING LOW SEALING INITIATION TEMPERATURE AND HIGH MELTING TEMPERATURE 审中-公开
公开(公告)号：WO2018122031A1
公开(公告)日：2018-07-05
申请号：PCT/EP2017/083463
申请日：2017-12-19
申请人： BOREALIS AG
发明人： BORAGNO, Luca , RESCONI, Luigi , HOFF, Matthias , DAS, Shital , ALASTALO, Kauno , VAHTERI, Markku , BERGER, Friedrich , TRANCHIDA, Davide
IPC分类号： C08F210/06 , C08F2/00 , C08J5/18 , B32B27/32 , C08F210/08 , C08F210/16 , C08F4/651
摘要： The invention relates to a polypropylene composition which combines low sealing initiation temperature (SIT) and high melting point (Tm), thus having a broad sealing window.

34. 发明申请

WO2018091684A1 CATALYSTS 审中-公开
公开(公告)号：WO2018091684A1
公开(公告)日：2018-05-24
申请号：PCT/EP2017/079662
申请日：2017-11-17
申请人： BOREALIS AG
发明人： AJELLAL, Noureddine , RESCONI, Luigi , IZMER, Vyatcheslav V. , KONONOVICH, Dmitry S. , OSKOBOYNIKOV, Alexander Z. , VIRKKUNEN, Ville
IPC分类号： C07F7/08 , C08F4/649 , C08F10/06 , C07C13/465
摘要： A complex of formula (I) wherein M is zirconium or hafnium; each X independently is a sigma ligand; L is a divalent bridge selected from -R' 2 C-, -R' 2 C-CR' 2 -, -R' 2 Si-, -R' 2 Si-SiR' 2 -, -R' 2 Ge-, wherein each R' is independently a hydrogen atom or a C 1 -C 20 -hydrocarbyl group optionally containing one or more silicon atoms or heteroatoms of Group 14-16 of the periodic table or fluorine atoms, and optionally two R' groups taken together can form a ring; R 2 and R 2' are each independently a C 1 -C 20 hydrocarbyl group, -OC 1- hydrocarbyl group or -SC 1-20 hydrocarbyl group; R 5 is a -OC 1-20 hydrocarbyl group or -SC 1-20 hydrocarbyl group, said R 5 group being optionally substituted by one or more halo groups; R 5' is hydrogen or a C 1-20 hydrocarbyl group; -OC 1-20 hydrocarbyl group or -SC 1-20 hydrocarbyl group; said C 1-20 hydrocarbyl group being optionally substituted by one or more halo groups; R 6 and R 6' are each independently a C 1-20 hydrocarbyl group; -OC 1-20 hydrocarbyl group or -SC 1-20 hydrocarbyl group; each R 1 and R 1' are independently -CH 2 R x wherein R x are each independently H, or a C 1-20 hydrocarbyl group, optionally containing heteroatoms.

35. 发明申请

WO2017001474A1 PROCESS FOR PREPARING PROPYLENE POLYMER COMPOSITIONS 审中-公开
标题翻译：制备丙烯聚合物组合物的方法
公开(公告)号：WO2017001474A1
公开(公告)日：2017-01-05
申请号：PCT/EP2016/065139
申请日：2016-06-29
申请人： BOREALIS AG
发明人： RESCONI, Luigi , SHUTOV, Pavel , TÖLTSCH, Wilfried
IPC分类号： C08F210/06 , C08F4/646
CPC分类号： C08F210/06 , C08F210/16 , C08F2800/20 , C08F210/08 , C08F2500/12 , C08F2500/26 , C08F4/6494 , C08F4/6465 , C08F4/6546 , C08F4/6492
摘要： The present invention relates to an olefin polymerization process, wherein propylene and a C4 to C10 a-olefin, preferably 1-butene and optionally ethylene are reacted in the presence of a Ziegler-Natta catalyst so as to obtain a polypropylene, wherein the polypropylene comprises C4 to C10 a-olefin, preferablyl-butene-derived comonomer units in an amount of from 0.5 wt% to 15 wt% and ethylene-derived comonomer units in an amount of 0 wt% to 3 wt%, and wherein the Ziegler-Natta catalyst comprises i) an external donor of the formula (I): (R 3 ) z (R 2 O) y Si(R 1 )x and ii) a solid Ziegler-Natta catalyst component being free of external carrier material.
摘要翻译：烯烃聚合方法本发明涉及一种烯烃聚合方法，其中丙烯和C 4至C 10α-烯烃，优选1-丁烯和任选的乙烯在齐格勒 - 纳塔催化剂存在下反应以获得聚丙烯，其中聚丙烯包含 C 5〜C 10α-烯烃，优选1-丁烯衍生的共聚单体单元，其量为0.5重量％〜15重量％，乙烯衍生的共聚单体单元的量为0重量％〜3重量％，其中齐格勒 - 纳塔催化剂包括：i）式（I）的外部供体：（R3）z（R2O）ySi（R1）x和ii）不含外部载体材料的固体齐格勒 - 纳塔催化剂组分。

36. 发明申请

WO2016139162A1 C2C3 RANDOM COPOLYMER COMPOSITION WITH IMPROVED BALANCE BETWEEN SEALING INITIATION TEMPERATURE AND MELTING POINT 审中-公开
标题翻译： C2C3随机共聚物组合物在密封启动温度和熔点之间具有改善的平衡
公开(公告)号：WO2016139162A1
公开(公告)日：2016-09-09
申请号：PCT/EP2016/054190
申请日：2016-02-29
申请人： BOREALIS AG
发明人： TRANNINGER, Cornelia , RESCONI, Luigi , FRIEDRICH, Karlheinz
IPC分类号： C08F4/16 , C08F2/00 , C08L23/14
CPC分类号： C08L23/14 , B29C55/28 , B29K2023/08 , B29K2023/14 , B29K2105/0085 , C08F4/65916 , C08J5/18 , C08J2323/14 , C08J2423/14 , C08L2205/025 , C08L2205/03 , C08F210/06 , C08F2/001 , C08F4/65927 , C08F210/16 , C08F2500/12 , C08F2500/26
摘要： C 2 C 3 random copolymer composition with an improved balance between sealing initiation temperature (SIT) and melting point (Tm), i.e. low SIT and high melting point. In addition the inventive composition shows a broad sealing window, low hexane solubles and good optical properties, like low haze.
摘要翻译： C2C3无规共聚物组合物，其密封起始温度（SIT）和熔点（Tm）之间的平衡改善，即低SIT和高熔点。此外，本发明的组合物显示出宽的密封窗口，低的可溶物质和良好的光学性能，如低雾度。

37. 发明申请

WO2015177094A1 POLYPROPYLENE COMPOSITION FOR AUTOMOTIVE INTERIOR APPLICATIONS 审中-公开
标题翻译：用于汽车内部应用的聚丙烯组合物
公开(公告)号：WO2015177094A1
公开(公告)日：2015-11-26
申请号：PCT/EP2015/060896
申请日：2015-05-18
申请人： BOREALIS AG
发明人： WANG, Jingbo , RESCONI, Luigi , DOSHEV, Petar , GAHLEITNER, Markus
IPC分类号： C08L23/12
CPC分类号： C08L23/14 , C08K3/34 , C08L23/06 , C08L23/0815 , C08L23/12 , C08L23/16 , C08L2205/025 , C08L2205/03 , C08L2207/02 , C08L2207/04 , C08L2207/062
摘要： Polypropylene composition comprising a heterophasic propylene copolymer and a mineral filler,wherein said heterophasic propylene copolymer has a melting temperature in the range of 140 to 155 °C, a xylene cold soluble content in the range of 20 to 35 wt.-% and a comonomer content of the xylene cold soluble fraction in the range of 18 to 95 wt.-%, wherein further the weight ratio between heterophasic propylene copolymer and the mineral filler is in the range of 2/1 to 4/1.
摘要翻译：包含异相丙烯共聚物和矿物填料的聚丙烯组合物，其中所述多相丙烯共聚物的熔融温度在140至155℃范围内，二甲苯冷可溶物含量在20至35重量％范围内，共聚单体二甲苯冷可溶成分的含量在18至95重量％的范围内，其中异相丙烯共聚物和矿物填料之间的重量比进一步在2/1至4/1的范围内。

38. 发明申请

WO2015107020A1 PROCESS FOR PREPARING PROPYLENE/1-BUTENE COPOLYMERS 审中-公开
标题翻译：制备丙烯/ 1-丁烯共聚物的方法
公开(公告)号：WO2015107020A1
公开(公告)日：2015-07-23
申请号：PCT/EP2015/050406
申请日：2015-01-12
申请人： BOREALIS AG
发明人： REICHELT, Kristin , TÖLTSCH, Wilfried , RESCONI, Luigi
IPC分类号： C08F210/06 , C08F4/646
CPC分类号： C08F210/06 , B32B27/32 , B32B2307/518 , C08F110/02 , C08F2410/00 , C08F2410/04 , C08F2500/12 , C08F2500/26 , C08F2800/10 , C08J5/18 , C08J2323/14 , C08F210/08 , C08F210/16 , C08F210/14 , C08F4/6492 , C08F4/6465
摘要： The present invention relates to an olefin polymerization process, wherein propylene and 1 - butene and optionally ethylene are reacted in the presence of a Ziegler-Natta catalyst system so as to obtain a polypropylene, wherein the polypropylene comprises 1 -butene- derived comonomer units in an amount of from 5 to 20 wt % and optionally ethylene- derived comonomer units in an amount of up to 3 wt %, and the Ziegler-Natta catalyst system comprises an external donor of the following formula (I): (R 3 ) z (R 2 O) y Si(R 1 ) x .
摘要翻译：本发明涉及烯烃聚合方法，其中丙烯和1-丁烯和任选的乙烯在齐格勒 - 纳塔催化剂体系的存在下反应，以获得聚丙烯，其中聚丙烯包含1-丁烯衍生的共聚单体单元 5至20重量％的量和任选的含量高达3重量％的乙烯衍生的共聚单体单元，齐格勒 - 纳塔催化剂体系包含下式（I）的外给体：（R3）z（ R2O）YSI（R1）X。

39. 发明申请

WO2015059229A1 LOW MELTING PP HOMOPOLYMER WITH HIGH CONTENT OF REGIOERRORS AND HIGH MOLECULAR WEIGHT 审中-公开
标题翻译：低熔点PP共聚物，具有高分子量和高分子量
公开(公告)号：WO2015059229A1
公开(公告)日：2015-04-30
申请号：PCT/EP2014/072763
申请日：2014-10-23
申请人： BOREALIS AG
发明人： RESCONI, Luigi , REICHELT, Kristin
IPC分类号： C08F110/06 , C08F4/6592
CPC分类号： C08F110/06 , C08L23/12 , C08L2203/12 , C08L2203/16 , C08L2203/18 , C08L2205/025 , F16L9/12 , C08F4/65927 , C08F2500/01 , C08F2500/15
摘要： The present invention relates to a polypropylene homopolymer, a process for the preparation of such polypropylene homopolymer and a polypropylene blend comprising such polypropylene homopolymer as well as a pipe, sheet, film, fiber, moulded article or extrusion coating comprising such polypropylene homopolymer or polypropylene blend.
摘要翻译：本发明涉及聚丙烯均聚物，制备这种聚丙烯均聚物的方法和包含这种聚丙烯均聚物的聚丙烯共混物以及包含这种聚丙烯均聚物或聚丙烯混合物的管，片，膜，纤维，模塑制品或挤出涂层。

40. 发明申请

WO2015022127A1 PROPYLENE COMPOSITION WITH IMPROVED IMPACT RESISTANCE AT LOW TEMPERATURE 审中-公开
标题翻译：丙烯组合物在低温下具有改善的耐冲击性
公开(公告)号：WO2015022127A1
公开(公告)日：2015-02-19
申请号：PCT/EP2014/065010
申请日：2014-07-14
申请人： BOREALIS AG
发明人： TÖLTSCH, Wilfried , RESCONI, Luigi , REICHELT, Kristin
IPC分类号： C08L23/10 , C08L23/14 , C08F210/02 , C08F210/06 , C08F210/14
CPC分类号： C08L23/14 , C08F4/65912 , C08F4/65927 , C08F210/06 , C08L23/12 , C08L23/142 , C08L2205/025 , C08L2308/00 , C08F2/001 , C08F4/6492 , C08F210/16 , C08F2500/14 , C08F2500/12 , C08F2500/17
摘要： Polypropylene composition comprising comonomer units derived from ethylene in an amount of from 9.0 to 52.0 mol-% and comonomer units derived from a higher a-olefin in an amount of from 0.4 to 3.0 mol-%, wherein said polypropylene composition has an amount of xylene cold solubles of at least 30 wt.-%, wherein further the xylene cold soluble fraction has an ethylene content of from 20.0 to 80.0 mol-% and a higher a-olefin content from 0.1 to 1.5 mol-%.
摘要翻译：聚丙烯组合物包含衍生自乙烯的共聚单体单元，其量为9.0-52.0mol％，衍生自高级α-烯烃的共聚单体单元的量为0.4-3.0mol％，其中所述聚丙烯组合物具有一定量的二甲苯至少30重量％的可冷却可溶物，其中二甲苯冷可溶部分进一步具有20.0至80.0摩尔％的乙烯含量和0.1至1.5摩尔％的较高的α-烯烃含量。

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