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32. 发明申请

WO0214439A3 PROCESS FOR PRODUCING COATINGS USING SURFACE-ACTIVE PHOTOINITIATORS 审中-公开
标题翻译：使用表面活性光敏剂生产涂料的方法
公开(公告)号：WO0214439A3
公开(公告)日：2002-06-13
申请号：PCT/EP0109123
申请日：2001-08-07
申请人： CIBA SC HOLDING AG , BAUDIN GISELE , JUNG TUNJA
发明人： BAUDIN GISELE , JUNG TUNJA
IPC分类号： C07F7/18 , C07C69/738 , C07F7/08 , C08F2/48 , C08F2/50 , C08G77/14 , C08G77/38 , C09D4/00 , C09D4/06 , C09D5/00 , C09D7/06 , C09D7/12 , C09D183/10 , G03F7/029 , G03F7/031 , G03F7/075
CPC分类号： G03F7/0757 , B33Y70/00 , C07C69/738 , C08F2/50 , C09D4/06 , G03F7/029 , C08F290/067
摘要： Compounds of formula (I) in which r is a number 1 or 2; s is a number from 1 to 1000; R is radical of formula (II); or R is, for example, unsubstituted or substituted naphthyl, anthracyl, phenanthryl or a heterocyclic radical; R1, R2, R3, R4 and R5 independently of one another are, for example hydrogen; unsubstituted or substituted phenyl or C1-C12alkyl; A, if s is 1, is a surface-active radical of formula (III); or A, if s is 1, is a surface-active radical A0; or A, if s is a number greater than 1, is a radical of the formula (III) in which n corresponds to the number s, or A, if s is 2, is a radical A1; A0 is, for example, in each case unsubstituted or substituted C6-C30alkyl, C6-C30alkenyl, C6-C30alkynyl or C6-C30aralkyl; A1 is, for example, in each case unsubstituted or substituted C6-C30alkylene, C6-C30alkenylene, C6-C30alkynylene or C6-C30aralkylene; n is, for example, a number from 1 to 1000; m is a number from 0 to 100; p is a number 0-10000; x is a number from 1 to 10; Y, if r is 1, is a divalent group and Y, if r is 2, is a trivalent group, and Y, if A has the definition A0, is a single bond; G1, G2, R13, R14, R15, R16, R17, R18, R19, R20, R21 and R22 are, for exmple, C1-C18alkyl; are particularly suitable as photoinitiators which accumulate at the surface in a process for curing coatings.
摘要翻译：式（I）化合物，其中r为数1或2; s是从1到1000的数字; R是式（II）的基团; 或R为例如未取代或取代的萘基，蒽基，菲基或杂环基; R 1，R 2，R 3，R 4和R 5彼此独立地是例如氢; 未取代或取代的苯基或C 1 -C 12烷基; A，如果s为1，则为式（III）的表面活性基团; 或A，如果s为1，则为表面活性基团A0; 或A，如果s是大于1的数字，则是式（III）的基团，其中n对应于数字s，或者A如果s是2，则为基团A1; A0例如在每种情况下为未取代或取代的C 6 -C 30烷基，C 6 -C 30烯基，C 6 -C 30炔基或C 6 -C 30芳烷基; 例如，A1是未取代或取代的C 6 -C 30亚烷基，C 6 -C 30亚烯基，C 6 -C 30亚炔基或C 6 -C 30亚烷基; n例如为1〜1000的数; m是从0到100的数字; p是数字0-10000; x是从1到10的数字; Y如果r为1，则为二价基团，如果r为2，Y为三价基团，Y如果A为定义A0，则为单键; G1，G2，R13，R14，R15，R16，R17，R18，R19，R20，R21和R22优选为C1-C18烷基; 特别适用于在固化涂层的工艺中在表面积聚的光引发剂。

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