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21. 发明申请

WO2013131916A1 PROCESS FOR THE PRODUCTION OF HYDROGEN 审中-公开
标题翻译：生产氢过程
公开(公告)号：WO2013131916A1
公开(公告)日：2013-09-12
申请号：PCT/EP2013/054406
申请日：2013-03-05
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , SHELL OIL COMPANY
发明人： GUO, Chang Jie , SHU, Shu
IPC分类号： C01B3/38 , C01B3/48 , C01B3/52 , C01B3/56 , C01B3/50 , C10G45/00
CPC分类号： C01B3/384 , C01B3/48 , C01B3/501 , C01B3/52 , C01B3/56 , C01B2203/0233 , C01B2203/0283 , C01B2203/0405 , C01B2203/0415 , C01B2203/043 , C01B2203/0475 , C01B2203/065 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2203/1235 , C01B2203/142 , C01B2203/146 , C01B2203/148 , C10G45/02 , C10G45/58 , C10G47/00 , C10G49/007 , C10K1/32 , C10K3/04 , Y02P20/128
摘要： The invention relates to process for the production of hydrogen, comprising • a) subjecting a feedstock comprising a gaseous hydrocarbon to an endothermic steam reforming reaction by contacting the feedstock, in a steam reforming unit (4) and in the presence of steam (7), to obtain a steam reforming effluent comprising carbon monoxide, hydrogen and hydrocarbon, and wherein heat needed for the endothermic reaction is provided by a furnace fueled by a fuel gas; • b) subjecting the steam reforming effluent to a water-gas-shift reaction (12) to obtain a water-gas-shift effluent comprising carbon dioxide, hydrogen and hydrocarbon; • c) removing carbon dioxide from the water-gas-shift effluent (15) to obtain a carbon-dioxide depleted water-gas-shift effluent (17); • d) subjecting the carbon-dioxide depleted water-gas-shift effluent to pressure swing adsorption (18) to obtain a high purity hydrogen stream (19) and a low purity hydrogen stream comprising hydrocarbon (20); • e) separating the low purity hydrogen stream in a hydrocarbon-rich gas stream and a hydrogen-rich gas streamn (22) by means of membrane separation (21); • f) supplying the hydrogen-rich gas stream obtained in step e) to the furnace (6) as part of the fuel gas; and • g) recycling the hydrocarbon-rich gas stream to the steam reforming unit.
摘要翻译：本发明涉及氢的生产方法，包括。 a）通过在蒸汽重整单元（4）和蒸汽（7）的存在下使原料接触，使包含气态烃的原料进行吸热蒸汽重整反应，以获得包含一氧化碳，氢气和碳氢化合物，并且其中吸热反应所需的热量由燃料气体燃烧的炉提供; 。 b）使蒸汽重整流出物进行水煤气变换反应（12）以获得包含二氧化碳，氢气和烃的水煤气转移流出物; 。 c）从水煤气转移流出物（15）中除去二氧化碳，得到二氧化碳贫化水煤气流出物（17）; 。 d）使二氧化碳贫化的水煤气变换废气经受变压吸附（18），以获得高纯度氢气流（19）和包含烃（20）的低纯度氢气流; 。 e）通过膜分离（21）分离富烃气流中的低纯度氢气流和富氢气流（22）; 。 f）将作为燃料气体的一部分的步骤e）中获得的富氢气流供给到炉子（6）和。 g）将富烃气流再循环到蒸汽重整单元。

22. 发明申请

WO2013033294A3 INTEGRATED CRUDE REFINING WITH REDUCED COKE FORMATION 审中-公开
标题翻译：一体化原料精炼与减少焦化形成
公开(公告)号：WO2013033294A3
公开(公告)日：2013-07-25
申请号：PCT/US2012052983
申请日：2012-08-30
申请人： EXXONMOBIL RES & ENG CO , STRAUSS RAMON A , BROWN STEPHEN H , STRATTON DONALD E , CEULENMANS STEFAN
发明人： STRAUSS RAMON A , BROWN STEPHEN H , STRATTON DONALD E , CEULENMANS STEFAN
IPC分类号： C10G35/00 , C10G45/02 , C10G47/00 , C10G47/02 , C10G65/12 , C10G65/14
CPC分类号： C10G65/12 , B01J23/74 , B01J23/883 , B01J23/8885 , B01J35/023 , B01J35/1038 , B01J35/1042 , B01J35/1061 , B01J37/0201 , B01J37/0207 , B01J37/20 , C10G35/00 , C10G45/00 , C10G45/02 , C10G45/04 , C10G45/32 , C10G45/44 , C10G45/58 , C10G47/00 , C10G47/02 , C10G49/02 , C10G49/22 , C10G65/00 , C10G65/14 , C10G67/00 , C10G67/0454 , C10G2300/1037 , C10G2300/107 , C10G2300/1077 , C10G2300/202 , C10G2300/205 , C10G2300/206 , C10G2300/301 , C10G2300/305 , C10G2300/44 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10G2400/10 , C10G2400/26 , C10G2400/28
摘要： Methods are provided for processing crude oil feeds with reduced or minimized energy usage, reduced or minimized numbers of processing steps, improved allocation of hydrogen, and reduced or minimized formation of low value products. The methods reduce or minimize the use of vacuum distillation, and in many aspects reduce or minimize the use of both atmospheric and vacuum distillation. The methods also reduce or minimize the use of coking and fluid catalytic cracking processes.
摘要翻译：提供了用于以减少或最小化的能量使用来处理原油进料的方法，减少或最少数量的处理步骤，改善氢的分配，以及减少或最小化低价值产物的形成。该方法减少或最小化真空蒸馏的使用，并且在许多方面减少或最小化大气压和真空蒸馏的使用。该方法还减少或最小化焦化和流化催化裂化过程的使用。

23. 发明申请

WO2013096413A2 METHODS FOR SUPPRESSING ISOMERIZATION OF OLEFIN METATHESIS PRODUCTS, METHODS OF REFINING NATURAL OILS, AND METHODS OF PRODUCING FUEL COMPOSITIONS 审中-公开
标题翻译：用于抑制烯烃衍生产物异构化的方法，精制天然油的方法和生产燃料组合物的方法
公开(公告)号：WO2013096413A2
公开(公告)日：2013-06-27
申请号：PCT/US2012/070550
申请日：2012-12-19
申请人： ELEVANCE RENEWABLE SCIENCES, INC.
发明人： FIRTH, Bruce, E. , KIRK, Sharon, E.
IPC分类号： C07C7/20 , C11B5/00 , C07C7/04
CPC分类号： C10G45/00 , B01J31/2265 , B01J2231/54 , B01J2531/821 , C07C7/20 , C10G45/58 , C10G50/00 , C10G2300/1014 , C10G2300/304 , C10G2300/308 , C10G2300/705 , C10G2400/04 , C10G2400/08 , C10L1/08 , C11C3/00 , C11C3/003 , C11C3/12 , C07C11/02
摘要： A method for suppressing isomerization of an olefin metathesis product produced in a metathesis reaction includes adding an isomerization suppression agent to a mixture that includes the olefin metathesis product and residual metathesis catalyst from the metathesis reaction under conditions that are sufficient to passivate at least a portion of the residual metathesis catalyst. The isomerization suppression agent includes (i) a salt and/or an ester of a phosphorous oxo acid, and/or (ii) a derivative of the phosphorous oxo acid in which at least one P-H bond has been replaced by a P-C bond, and/or (iii) a salt and/or an ester of the derivative. Methods of refining natural oils and methods of producing fuel compositions are described.
摘要翻译：用于抑制在复分解反应中产生的烯烃复分解产物的异构化的方法包括在易位反应的条件下将异构化抑制剂添加到包含烯烃复分解产物和残余复分解催化剂的混合物中，所述条件足以钝化至少一部分残余复分解催化剂。异构化抑制剂包括（i）含磷酸的盐和/或酯，和/或（ii）至少一个PH键被PC键取代的含磷酸的衍生物，和 /或（iii）衍生物的盐和/或酯。描述了精炼天然油的方法和生产燃料组合物的方法。

24. 发明申请

WO2013033301A3 USE OF LOW BOILING POINT AROMATIC SOLVENT IN HYDROPROCESSING HEAVY HYDROCARBONS 审中-公开
标题翻译：低沸点芳香族溶剂在氢化重油中的应用
公开(公告)号：WO2013033301A3
公开(公告)日：2013-04-25
申请号：PCT/US2012052994
申请日：2012-08-30
申请人： EXXONMOBIL RES & ENG CO , BROWN STEPHEN HAROLD , HO TEH C , WOO HYUNG SUK , CHENG JANE CHI-YA
发明人： BROWN STEPHEN HAROLD , HO TEH C , WOO HYUNG SUK , CHENG JANE CHI-YA
IPC分类号： C10G45/02 , C10G47/00
CPC分类号： C10G45/00 , C10G45/02 , C10G45/32 , C10G45/44 , C10G45/58 , C10G47/00 , C10G2300/1037 , C10G2300/107 , C10G2300/1077 , C10G2300/202 , C10G2300/205 , C10G2300/206 , C10G2300/44
摘要： This invention is directed to a process for producing a hydroprocessed product. The invention is particularly advantageous in that substantially less hydrogen is absorbed during the process relative to conventional hydroprocessing methods. This benefit is achieved by using a particular solvent as a co-feed component. In particular, the solvent component contains at least one single ring aromatic compound and has a relatively low boiling point range compared to the heavy hydrocarbon oil component used as another co-feed component.
摘要翻译：本发明涉及一种加氢处理产物的生产方法。本发明特别有利的是，相对于常规的加氢处理方法，在该方法中吸收相对较少的氢。通过使用特定溶剂作为共进料组分来实现该益处。特别地，溶剂组分含有至少一种单环芳族化合物，并且与用作另一种共进料组分的重质烃油组分相比具有相对较低的沸点范围。

25. 发明申请

WO2012165909A3 HYDROCARBON ADVANCEMENT METHOD 审中-公开
标题翻译：油气推进方法
公开(公告)号：WO2012165909A3
公开(公告)日：2013-03-28
申请号：PCT/KR2012004359
申请日：2012-06-01
申请人： KOREA ENERGY RESEARCH INST , HWANG KYUNG-RAN , PARK JONG-SOO , LEE JIN-SUK , LEE SHIN-KUN , LEE CHUN-BOO , LEE SUNG-WOOK
发明人： HWANG KYUNG-RAN , PARK JONG-SOO , LEE JIN-SUK , LEE SHIN-KUN , LEE CHUN-BOO , LEE SUNG-WOOK
IPC分类号： C10G45/58 , B01D61/00 , C10G45/02 , C10G45/60 , C10G61/00
CPC分类号： C10G3/52 , B01D53/228 , B01D67/0072 , B01D69/10 , B01D71/022 , B01D2325/10 , C10G3/46 , C10G3/47 , C10G45/02 , C10G45/58 , C10G2300/1011 , Y02E50/13 , Y02P30/20
摘要： The present invention relates to a method for developing fuel such as various raw materials and biodiesel having hydrocarbon wherein a carbon-carbon double bond and oxygen are removed by a hydrotreating reaction using a proton medium having conductivity, and the present invention is capable of producing advanced biofuel at low costs from various hydrocarbon sources and improving energy efficiency and hydrogen usage efficiency.
摘要翻译：本发明涉及一种用于开发诸如各种原料的燃料和具有烃的生物柴油的方法，其中使用具有导电性的质子介质通过加氢处理反应除去碳 - 碳双键和氧，并且本发明能够生产高级生物燃料以低成本来自各种烃源，并提高能源效率和氢气使用效率。

26. 发明申请

WO2012170147A3 PROCESS FOR PRODUCING ONE OR MORE ALKYLATED AROMATICS 审中-公开
标题翻译：生产一种或多种碱性芳族化合物的方法
公开(公告)号：WO2012170147A3
公开(公告)日：2013-01-31
申请号：PCT/US2012037440
申请日：2012-05-11
申请人： UOP LLC , HAIZMANN ROBERT , LEONARD LAURA E , BOGDAN PAULA L
发明人： HAIZMANN ROBERT , LEONARD LAURA E , BOGDAN PAULA L
IPC分类号： C07C2/66 , C07C2/64 , C07C7/04 , C07C15/073
CPC分类号： C07C2/66 , C07C5/13 , C07C5/2791 , C07C5/367 , C07C6/123 , C07C6/126 , C07C7/12 , C07C7/14 , C07C2101/08 , C07C2101/14 , C07C2521/02 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2523/02 , C07C2523/08 , C07C2523/12 , C07C2523/14 , C07C2523/26 , C07C2523/36 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/75 , C07C2523/755 , C07C2529/08 , C07C2529/18 , C07C2529/85 , C07C2601/08 , C07C2601/14 , C10G11/18 , C10G29/205 , C10G45/58 , C10G45/64 , C10G57/005 , C10G69/04 , C10G69/123 , C10G2300/4087 , Y02P30/464 , C07C15/08 , C07C13/10 , C07C13/18 , C07C15/04 , C07C15/073
摘要： One exemplary embodiment may be a process for producing one or more alkylated aromatics. Generally, the process includes providing a first stream including an effective amount of benzene for alkylating benzene from a fractionation zone, providing a second stream including an effective amount of ethene for alkylating benzene from a fluid catalytic cracking zone, providing at least a portion of the first and second streams to an alkylation zone; and passing at least a portion of an effluent including ethylbenzene from the alkylation zone downstream of a para-xylene separation zone.
摘要翻译：一个示例性实施方案可以是用于生产一种或多种烷基化芳族化合物的方法。通常，该方法包括提供包含有效量的苯的第一流，用于从分馏区烷基化苯，提供包含有效量的用于从流化催化裂化区烷基化苯的乙烯的第二料流，提供至少一部分第一和第二流到烷基化区; 并使来自包含乙苯的至少一部分流出物从对二甲苯分离区下游的烷基化区通过。

27. 发明申请

WO2012124940A3 METHOD FOR ECONOMICALLY PREPARING HYDROGENATED BIODIESEL WITH IMPROVED LOW TEMPERATURE FLOWABILITY 审中-公开
标题翻译：经济地制备具有改进的低温流动性的氢化生物柴油的方法
公开(公告)号：WO2012124940A3
公开(公告)日：2012-12-27
申请号：PCT/KR2012001749
申请日：2012-03-09
申请人： SK INNOVATION CO LTD , SK ENERGY CO LTD , CHU YOUNG HWAN , KIM GYUNG ROK , RYU JAE WOOK , KIM DO WOAN , SONG JONG HEE , HWANG YOON MANG , CHOI SUN
发明人： CHU YOUNG HWAN , KIM GYUNG ROK , RYU JAE WOOK , KIM DO WOAN , SONG JONG HEE , HWANG YOON MANG , CHOI SUN
IPC分类号： C10G3/00 , C10L1/02
CPC分类号： C10G3/52 , C10G3/50 , C10G45/32 , C10G45/58 , C10G65/043 , C10G65/06 , C10G65/08 , C10G2300/802 , C10G2400/04 , C10L1/026 , C10L1/08 , Y02E50/13 , Y02P30/20
摘要： The present invention relates to a method for preparing biodiesel by isomerizing a part of the resultant of hydrodeoxygenation and recycling the isomerized product, and then hydrodeoxygenating a fresh feed in a diluted state again when oxygen is removed in the form of water, CO, and CO2 by adding hydrogen to a feed including triglyceride (TG).
摘要翻译：本发明涉及一种制备生物柴油的方法，其通过将加氢脱氧产物的一部分异构化并使异构化产物再循环，然后当以水，CO和CO 2形式除去氧时再次使处于稀释状态的新鲜进料加氢脱氧通过向包含甘油三酯（TG）的进料添加氢气。

28. 发明申请

WO2012149108A1 SELECTIVE ISOMERIZATION AND OLIGOMERIZATION OF OLEFIN FEEDSTOCKS FOR THE PRODUCTION OF TURBINE AND DIESEL FUELS 审中-公开
标题翻译：用于生产涡轮和柴油燃料的烯烃进料的选择性异构化和低级化
公开(公告)号：WO2012149108A1
公开(公告)日：2012-11-01
申请号：PCT/US2012/035121
申请日：2012-04-26
申请人： THE GOVERNMENT OF THE UNITED STATES OF AMERICA AS REPRESENTED BY THE SECRETARY OF THE NAVY , HARVEY, Benjamin, G. , WRIGHT, Michael, E.
发明人： HARVEY, Benjamin, G. , WRIGHT, Michael, E.
IPC分类号： C07C2/58 , C10L1/04
CPC分类号： B01J31/2295 , C10G3/42 , C10G3/44 , C10G45/00 , C10G45/58 , C10G45/60 , C10G45/62 , C10G50/00 , C10G65/043 , C10G69/126 , C10G2300/4037 , C10G2400/04 , C10G2400/20 , C10G2400/22 , C10L1/08
摘要： A process from converting alcohol feedstock to diesel/turbine fuels includes providing an alcohol-based feedstock and dehydrating the alcohol with at least one solid catalyst at a temperature ranging from about 200 °C to about 400 °C to produce an olefin mixture. The mixture is directly oligomerized with a Ziegler Natta catalyst and a cocatalyst to produce an oligomer mixture comprising oligomers and unreacted olefins. An isomerization catalyst is introduced to the oligomer mixture to produce, in situ, a bimetallic isomerization/oligomerization catalyst which converts the unreacted olefins to oligomers through 1,2-addition. The oligomers can be hydrogenated and distilled in producing the diesel/turbine fuels. In other aspects, in a one step process, the olefin mixture is oligomerized with at least one bimetallic isomerization/oligomerization catalyst that includes a metallocene based catalyst in conjunction with an isomerization catalyst to produce oligomers formed through 1,2-addition.
摘要翻译：将醇原料转化为柴油/涡轮机燃料的方法包括提供醇基原料，并用至少一种固体催化剂在约200℃至约400℃的温度范围内使醇脱水以产生烯烃混合物。该混合物用齐格勒纳塔催化剂和助催化剂直接低聚以产生包含低聚物和未反应烯烃的低聚物混合物。将异构化催化剂引入低聚物混合物中，原位生产通过1,2-加成将未反应的烯烃转化为低聚物的双金属异构化/低聚催化剂。低聚物可以在生产柴油/涡轮燃料时被氢化和蒸馏。在其它方面，在一步法中，烯烃混合物与至少一种双异构化/低聚催化剂低聚，该双金属异构化/低聚催化剂包括与异构化催化剂结合的茂金属系催化剂以产生通过1,2-加成形成的低聚物。

29. 发明申请

WO2012124940A2 저온 유동성을 개선한 경제적인 수첨 바이오디젤의 제조 방법 审中-公开
标题翻译：经济地制备加氢生物柴油的方法，具有改善的低温流动性
公开(公告)号：WO2012124940A2
公开(公告)日：2012-09-20
申请号：PCT/KR2012/001749
申请日：2012-03-09
申请人： 에스케이이노베이션 주식회사 , 에스케이에너지 주식회사 , 주영환 , 김경록 , 유재욱 , 김도완 , 송종희 , 황윤맹 , 최선
发明人： 주영환 , 김경록 , 유재욱 , 김도완 , 송종희 , 황윤맹 , 최선
IPC分类号： C10G3/00 , C10L1/02
CPC分类号： C10G3/52 , C10G3/50 , C10G45/32 , C10G45/58 , C10G65/043 , C10G65/06 , C10G65/08 , C10G2300/802 , C10G2400/04 , C10L1/026 , C10L1/08 , Y02E50/13 , Y02P30/20
摘要： 본 발명은 트리글리세리드(Triglyceride, TG)를 함유하는 공급원료에 수소를 첨가하여 물, CO, CO 2 형태로 산소를 제거하는데 있어서, 탈산소 반응의 결과물 중 일부를 이성화 반응시킨 후 재순환하여 신규 공급원료(Fresh Feed)를 희석한 상태로 다시 수첨 탈산소화 반응을 수행하여 바이오디젤을 제조하는 방법에 관한 것이다.
摘要翻译：本发明涉及一种通过使一部分加氢脱氧产生物异构化并再循环异构化产物，然后在以水，CO和CO 2的形式除去氧气时再次以稀释状态加热脱氧的生物柴油的方法。通过向包含甘油三酯（TG）的饲料中加入氢气。

30. 发明申请

WO2012057939A3 PROCESS OF SYNTHESIS GAS CONVERSION TO LIQUID HYDROCARBON MIXTURES USING ALTERNATING LAYERS OF SYNTHESIS GAS CONVERSION CATALYST, HYDROCRACKING AND HYDROISOMERIZATION CATALYST 审中-公开
标题翻译：利用合成气转化催化剂，加氢裂化和加氢异构化催化剂交替层合成气转化为液态烃混合物的工艺
公开(公告)号：WO2012057939A3
公开(公告)日：2012-06-21
申请号：PCT/US2011052551
申请日：2011-09-21
申请人： CHEVRON USA INC , SAXTON ROBERT J , KIBBY CHARLES L , JOTHIMURUGESAN KANDASWAMY , DAS TAPAN
发明人： SAXTON ROBERT J , KIBBY CHARLES L , JOTHIMURUGESAN KANDASWAMY , DAS TAPAN
IPC分类号： C07C1/04 , B01J23/46 , B01J29/44 , C07C4/06 , C07C9/00
CPC分类号： B01J37/0244 , B01J23/8913 , B01J29/42 , B01J29/74 , B01J37/024 , B01J37/04 , C10G2/32 , C10G2/333 , C10G2/341 , C10G45/58 , C10G45/64 , C10G47/00 , C10G47/14 , C10G65/12 , C10G2300/1022 , C10G2300/304 , C10G2400/02
摘要： Disclosed is a process for converting synthesis gas to liquid hydrocarbon mixtures useful in the production of fuels and petrochemicals. The synthesis gas is contacted with at least two layers of synthesis gas conversion catalyst wherein each synthesis gas conversion catalyst layer is followed by a layer of hydrocracking catalyst and hydroisomerization catalyst or separate layers of hydrocracking and hydroisomerization catalysts. The process can occur within a single reactor, at an essentially common reactor temperature and an essentially common reactor pressure. The process provides a high yield of naphtha range liquid hydrocarbons and a low yield of wax.
摘要翻译：公开了一种将合成气转化为可用于生产燃料和石化产品的液态烃混合物的方法。合成气与至少两层合成气转化催化剂接触，其中每个合成气转化催化剂层之后是加氢裂化催化剂和加氢异构化催化剂层或加氢裂化和加氢异构化催化剂的分开层。该方法可以在单个反应器内，在基本上常见的反应器温度和基本常见的反应器压力下进行。该方法提供了石脑油范围液体烃的高收率和低收率的蜡。

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