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21. 发明申请

WO2011094713A1 PREPARATION METHOD FOR MAKING TIN- CONTAINING CATALYST 审中-公开
标题翻译：制备含有催化剂的制备方法
公开(公告)号：WO2011094713A1
公开(公告)日：2011-08-04
申请号：PCT/US2011/023230
申请日：2011-01-31
申请人： CELANESE INTERNATIONAL CORPORATION , WEINER, Heiko , JOHNSTON, Victor J. , JEVTIC, Radmila
发明人： WEINER, Heiko , JOHNSTON, Victor J. , JEVTIC, Radmila
IPC分类号： C07C29/149 , C07C31/08 , B01J23/14 , B01J23/62 , B01J35/10 , B01J37/02
CPC分类号： B01J23/14 , B01J23/26 , B01J23/32 , B01J23/626 , B01J23/66 , B01J23/835 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J35/1066 , B01J37/0201 , B01J37/0203 , B01J37/0207 , B01J37/18 , C07C29/149 , C07C31/08
摘要： A process for producing a catalyst comprising the steps of contacting a support with a mixed metal precursor comprising tin oxalate, a second metal precursor, a solubilizing agent such as ammonium oxalate, and water to form an impregnated support and heating the impregnated support under conditions effective to remove at least a weight majority of the water and reduce the tin from the tin oxalate and the second metal from the second metal precursor and thereby form the catalyst.
摘要翻译：一种制备催化剂的方法，包括以下步骤：将载体与包含草酸锡，第二金属前体，增溶剂如草酸铵的混合金属前体和水接触，以形成浸渍的载体并在有效的条件下加热浸渍的载体去除至少大部分的水，并从锡的草酸盐和第二金属中除去锡，从而形成催化剂。

22. 发明申请

WO2011075278A1 PREPARATION OF PALLADIUM-GOLD CATALYST 审中-公开
标题翻译：铂金催化剂的制备
公开(公告)号：WO2011075278A1
公开(公告)日：2011-06-23
申请号：PCT/US2010/057373
申请日：2010-11-19
申请人： LYONDELL CHEMICAL TECHNOLOGY, L.P.
发明人： SHAY, Daniel, Travis
IPC分类号： B01J21/06 , B01J23/44 , B01J23/52 , C04B35/636 , C04B38/06 , C04B35/46 , B01J37/00 , C07C67/055
CPC分类号： C04B30/00 , B01J21/063 , B01J23/44 , B01J23/52 , B01J23/66 , B01J37/0018 , C04B24/383 , C04B26/285 , C04B35/46 , C04B35/462 , C04B35/465 , C04B35/49 , C04B35/6263 , C04B35/632 , C04B35/63488 , C04B35/6365 , C04B38/0645 , C04B2111/00129 , C04B2235/3217 , C04B2235/3244 , C04B2235/3418 , C04B2235/3445 , C04B2235/3463 , C04B2235/349 , C04B2235/6021 , C04B2235/606 , C04B2235/6562 , C04B2235/721 , C07C67/055 , C04B14/305 , C04B40/0268 , C04B38/067 , C07C69/15
摘要： A method for preparing a palladium-gold catalyst containing a titania extrudate is disclosed. The titania extrudate is produced by using a carboxyalkyl cellulose and a hydroxyalkyl cellulose as extrusion aids. The titania extrudate has improved processibility and/or mechanical properties. After calcination, the extrudate is used as a carrier for the palladium-gold catalyst. The catalyst is useful in producing vinyl acetate by oxidizing ethylene with oxygen in the presence of acetic acid.
摘要翻译：公开了一种制备含有二氧化钛挤出物的钯 - 金催化剂的方法。二氧化钛挤出物通过使用羧基烷基纤维素和羟烷基纤维素作为挤出助剂来制备。二氧化钛挤出物具有改进的加工性和/或机械性能。煅烧后，挤出物用作钯 - 金催化剂的载体。该催化剂可用于通过在乙酸存在下用氧气氧化乙烯来生产乙酸乙烯酯。

23. 发明申请

WO2011075277A1 TITANIA-CONTAINING EXTRUDATE 审中-公开
标题翻译：包含TITANIA的EXIT
公开(公告)号：WO2011075277A1
公开(公告)日：2011-06-23
申请号：PCT/US2010/057365
申请日：2010-11-19
申请人： LYONDELL CHEMICAL TECHNOLOGY, L.P.
发明人： SHAY, Daniel, Travis
IPC分类号： B01J21/06 , B01J23/44 , B01J23/52 , C04B35/636 , C04B38/06 , C04B35/46 , B01J37/00 , C07C67/055
CPC分类号： C04B30/00 , B01J21/063 , B01J23/44 , B01J23/52 , B01J23/66 , B01J37/0018 , C04B24/383 , C04B26/285 , C04B35/46 , C04B35/462 , C04B35/465 , C04B35/49 , C04B35/6263 , C04B35/632 , C04B35/63488 , C04B35/6365 , C04B38/0645 , C04B2111/00129 , C04B2235/3217 , C04B2235/3244 , C04B2235/3418 , C04B2235/3445 , C04B2235/3463 , C04B2235/349 , C04B2235/6021 , C04B2235/606 , C04B2235/6562 , C04B2235/721 , C07C67/055 , C04B14/305 , C04B40/0268 , C04B38/067 , C07C69/15
摘要： An extrudate comprising titania, a carboxyalkyl cellulose, and a hydroxyalkyl cellulose is disclosed. The extrudates have a smooth outer surface when they exit the extruder. The extrusion processibility is improved.
摘要翻译：公开了包含二氧化钛，羧基烷基纤维素和羟烷基纤维素的挤出物。当挤出物离开挤出机时，挤出物具有光滑的外表面。挤出加工性得到改善。

24. 发明申请

WO2011008311A1 PROCESS FOR USING LAYERED SPHERE CATALYSTS WITH HIGH ACCESSIBILITY INDEXES 审中-公开
标题翻译：使用具有高可接受性指数的层状球形催化剂的方法
公开(公告)号：WO2011008311A1
公开(公告)日：2011-01-20
申请号：PCT/US2010/027082
申请日：2010-03-12
申请人： UOP LLC , GAJDA, Gregory J. , GLOVER, Bryan K. , NEGIZ, Antoine , RILEY, Mark G. , SENETAR, John J. , HOLMGREEN, Erik M.
发明人： GAJDA, Gregory J. , GLOVER, Bryan K. , NEGIZ, Antoine , RILEY, Mark G. , SENETAR, John J. , HOLMGREEN, Erik M.
IPC分类号： C07C2/10 , C07C5/09 , C07C4/06 , C07C11/04 , B01J35/08
CPC分类号： C07C7/163 , B01J21/04 , B01J23/40 , B01J23/44 , B01J23/50 , B01J23/58 , B01J23/66 , B01J35/002 , B01J35/008 , B01J37/0221 , C07C7/167 , C10G45/40 , Y02P20/52 , C07C11/04
摘要： A process and catalyst for use in the selective hydrogenation of acetylene to ethylene is presented. The catalyst comprises a layered structure, wherein the catalyst has an inner core and an outer layer of active material. The catalyst further includes a metal deposited on the outer layer, and the catalyst is formed such that the catalyst has an accessibility index between 3 and 500.
摘要翻译：提出了一种用于将乙炔选择性氢化成乙烯的方法和催化剂。催化剂包括层状结构，其中催化剂具有内核和活性材料的外层。催化剂还包括沉积在外层上的金属，并且形成催化剂使得催化剂的可接近指数在3和500之间。

25. 发明申请

WO2010101736A3 SELECTIVE HYDROGENATION CATALYST AND METHODS OF MAKING AND USING SAME 审中-公开
标题翻译：选择性氢化催化剂及其制备方法和使用方法
公开(公告)号：WO2010101736A3
公开(公告)日：2011-01-13
申请号：PCT/US2010025038
申请日：2010-02-23
申请人： CHEVRON PHILLIPS CHEMICAL CO , CHEUNG TIN-TACK PETER , HONG ZONGXUAN
发明人： CHEUNG TIN-TACK PETER , HONG ZONGXUAN
IPC分类号： B01J31/18 , B01J31/16 , B01J31/24 , C10G45/40
CPC分类号： C07C5/09 , B01J23/44 , B01J23/66 , B01J27/13 , B01J31/0271 , B01J31/1616 , B01J31/1845 , B01J31/185 , B01J31/1865 , B01J31/1875 , B01J31/24 , B01J31/2404 , B01J35/008 , B01J35/023 , B01J35/1009 , B01J35/1014 , B01J37/0203 , B01J37/024 , B01J37/28 , B01J2231/645 , B01J2531/824 , C07C5/05 , C07C2521/04 , C07C2531/26 , C10G45/40 , C10G2300/703
摘要： A composition comprising a supported hydrogenation catalyst comprising palladium and an organophosphorous compound, the supported hydrogenation catalyst being capable of selectively hydrogenating highly unsaturated hydrocarbons to unsaturated hydrocarbons. A method of making a selective hydrogenation catalyst comprising contacting a support with a palladium-containing compound to form a palladium supported composition, contacting the palladium supported composition with an organophosphorus compound to form a catalyst precursor, and reducing the catalyst precursor to form the catalyst. A method of selectively hydrogenating highly unsaturated hydrocarbons to an unsaturated hydrocarbon enriched composition comprising contacting a supported catalyst comprising palladium and an organophosphorous compound with a feed comprising highly unsaturated hydrocarbon under conditions suitable for hydrogenating at least a portion of the highly unsaturated hydrocarbon feed to form the unsaturated hydrocarbon enriched composition.
摘要翻译：一种组合物，其包含负载型氢化催化剂，其包含钯和有机磷化合物，所述负载氢化催化剂能够将高度不饱和烃选择性氢化为不饱和烃。制备选择性氢化催化剂的方法包括将载体与含钯化合物接触以形成负载钯的组合物，使钯负载的组合物与有机磷化合物接触以形成催化剂前体，还原催化剂前体以形成催化剂。将高度不饱和烃选择性氢化为不饱和烃富集组合物的方法，其包括使包含钯和有机磷化合物的负载催化剂与包含高度不饱和烃的进料在适于氢化至少一部分高度不饱和烃进料的条件下接触以形成不饱和烃富集组合物。

26. 发明申请

WO2010070030A3 CATALYST AND PROCESS FOR SELECTIVE HYDROGENATION OF ALKYNES AND DIENES. 审中-公开
标题翻译：催化剂和碱选择性氢化方法。
公开(公告)号：WO2010070030A3
公开(公告)日：2010-09-23
申请号：PCT/EP2009067373
申请日：2009-12-17
申请人： TOTAL PETROCHEMICALS RES FELUY , VULPESCU GEORGE , GENIN FRANCINE , HORTMANN KAI , DATH JEAN-PIERRE
发明人： VULPESCU GEORGE , GENIN FRANCINE , HORTMANN KAI , DATH JEAN-PIERRE
IPC分类号： B01J23/44 , B01J23/66 , B01J27/224 , B01J37/02
CPC分类号： B01J37/0201 , B01J23/44 , B01J23/66 , B01J27/224
摘要： Selective hydrogenation process comprising: ° contacting in the presence of hydrogen an hydrocarbon feedstock comprising at least one unsaturated compound selected from the group consisting of al kynes and dienes and mixtures thereof with a first hydrogenation catalyst in a first reaction zone to produce a first product stream having a reduced proportion of alkynes and/or dienes; and ° contacting the first product stream in a second reaction zone having an inlet and an outlet, in the presence of optional additional hydrogen, with a second hydrogenation catalyst to produce a second product stream, wherein, the first hydrogenation catalyst comprises: ° a first constituent of at least one metal or metal-based component selected from the elements consisting of Groups 1-10 of the Periodic Table of Elements (new IUPAC notation) and optionally a second constituent of at least one metal or metal-based component selected from the elements consisting of Groups 11-14 of the Periodic Table of Elements, and said first constituent and optional second constituent are on a carrier made essentially of SiC or of an alkaline earth metal silicate. Hydrogenation catalyst comprising : ° a first constituent of at least one metal or metal-based component selected from the elements consisting of Groups 1-10 of the Periodic Table of Elements (new IUPAC notation) and a second constituent of at least one metal or metal-based component selected from the elements consisting of Groups 11 -14 of the Periodic Table of Elements, and ° said first constituent and second constituent are on a carrier made essentially of an alkaline earth metal silicate or of SiC, ° the second constituent is optional if the carrier is made essentially of SiC.
摘要翻译：选择性氢化方法，包括：在氢的存在下，在第一反应区中，将包含至少一种选自由炔烃和二烯的不饱和化合物和其混合物与第一氢化催化剂组成的烃原料接触，以产生第一产物流炔和/或二烯的比例降低; 并且在具有入口和出口的第二反应区中，在任选的附加氢存在下，使第一产物流与第二氢化催化剂接触以产生第二产物流，其中第一氢化催化剂包括：至少一种金属或金属基组分的组分，其选自由元素周期表第1-10族（新的IUPAC符号）组成的元素和任选的至少一种金属或金属基成分的第二组分，所述金属或金属基组分选自由元素周期表第11-14部分组成的元素，以及所述第一组分和任选的第二组分在基本上由SiC或碱土金属硅酸盐制成的载体上。氢化催化剂，其包含：选自由元素周期表第1-10族（新的IUPAC符号）组成的元素中的至少一种金属或金属基成分的第一组分和至少一种金属或金属的第二组分基元素选自由元素周期表第11-14族组成的元素，且所述第一组分和第二组分位于基本上由碱土金属硅酸盐或SiC制成的载体上，第二组分是任选的如果载体基本上由SiC制成。

27. 发明申请

WO2010097424A2 KATALYSATOR FÜR DIE CHLORWASSERSTOFFOXIDATION ENTHALTEND RUTHENIUM UND SILBER UND/ODER CALCIUM 审中-公开
标题翻译：催化剂的氯化氢氧化含钌，银和/或钙
公开(公告)号：WO2010097424A2
公开(公告)日：2010-09-02
申请号：PCT/EP2010/052378
申请日：2010-02-25
申请人： BASF SE , HENZE, Guido , URTEL, Heiko , SESING, Martin , KARCHES, Martin
发明人： HENZE, Guido , URTEL, Heiko , SESING, Martin , KARCHES, Martin
IPC分类号： B01J23/46
CPC分类号： B01J23/50 , B01J21/04 , B01J23/58 , B01J23/66 , B01J37/0009 , B01J37/0201 , B01J37/0205 , C01B7/04
摘要： Katalysator für die katalytische Oxidation von Chlorwasserstoff mit Sauerstoff zu Chlor enthaltend Ruthenium auf einem Träger, dadurch gekennzeichnet, dass der Katalysator 0,01 bis 10 Gew.-% Silber und/oder Calcium als Dotierung enthält. Vorzugsweise besteht der Träger im Wesentlichen aus alpha-Aluminiumoxid. Bevorzugt enthält der Katalysator a) 0,1 bis 10 Gew.-% Ruthenium, b) 0,01 bis 5 Gew.-% Silber und/oder 0,01 bis 5 Gew.-% Calcium, c) 0 bis 5 Gew.-% eines oder mehrerer Erdalkalimetalle, d) 0 bis 5 Gew.-% eines oder mehrerer Alkalimetalle, e) 0 bis 5 Gew.-% eines oder mehrerer Seltenerdmetalle, f) 0 bis 5 Gew.-% eines oder mehrerer weiterer Metalle, ausgewählt aus der Gruppe bestehend aus Nickel, Palladium, Platin, Iridium und Rhenium, jeweils bezogen auf das Gesamtgewicht des Katalysators.
摘要翻译：催化剂的氯化氢与氧含氯在载体上的钌催化氧化，其特征在于该催化剂含有0.01〜10重量的银和/或含有作为掺杂剂的钙％。优选地，所述载体基本上α-氧化铝组成。优选地，催化剂含有：a）0.1〜10重量钌的％，B）0.01至5重量％的银和/或0.01至5重量％的钙，c）中从0％至第五 - 一种或多种碱土金属，D）0至5重量％的一种或多种碱金属的％，E）0至5重量％的一种或多种稀土金属的％，F）0至5重量％的一种或多种其它金属的％选自由镍，钯，铂，铱和铼组成的组中，在基于所述催化剂的总重量计。

28. 发明申请

WO2010083342A1 CATALYSTS BY DISPERSION OF NANOPARTICLES ONTO SUPPORT STRUCTURES 审中-公开
标题翻译：通过将纳米颗粒分散在支持结构上的催化剂
公开(公告)号：WO2010083342A1
公开(公告)日：2010-07-22
申请号：PCT/US2010/021085
申请日：2010-01-14
申请人： QUANTUMSPHERE, INC.
发明人： RINALDI, Fabrizio
IPC分类号： B01J35/00 , B82B3/00
CPC分类号： B01J35/0013 , B01J23/50 , B01J23/66 , B01J37/0211 , B01J37/0215
摘要： Methods are disclosed herein for improving efficient catalyst utilization in processes including thermal catalysis using dry nanoparticle promoters, rather than salts of metal promoters in liquid form. Using selected process steps, the nanoparticles are more controllably dispersed on primary support particles, for effective use on secondary supports when it desired to bring reactants into contact with the secondary support. Applications that generally make use of these catalysts can be but are not limited to: emission abatement catalysts, generation of syngas, generation of liquid fuels from syngas, safety systems (hydrogen recombination catalysts in nuclear power plants) and many industrial processes.
摘要翻译：本文公开了用于在包括使用干燥纳米颗粒促进剂的热催化的方法中改进有效的催化剂利用的方法，而不是液体形式的金属促进剂的盐。使用所选择的工艺步骤，纳米颗粒更可控地分散在主要载体颗粒上，以便当希望使反应物与次级载体接触时有效地用于次级载体上。通常利用这些催化剂的应用可以但不限于：减排催化剂，合成气的产生，合成气产生液体燃料，安全系统（核电站中的氢复合催化剂）以及许多工业过程。

29. 发明申请

WO2010008920A2 MULLITE-CONTAINING CARRIER FOR ETHYLENE OXIDE CATALYSTS 审中-公开
标题翻译：用于乙烯氧化物催化剂的含莫来石载体
公开(公告)号：WO2010008920A2
公开(公告)日：2010-01-21
申请号：PCT/US2009048816
申请日：2009-06-26
申请人： SCIENT DESIGN CO , PAK SERGUEI , ROKICKI ANDRZEJ , KAWABATA SHUJI
发明人： PAK SERGUEI , ROKICKI ANDRZEJ , KAWABATA SHUJI
IPC分类号： B01J21/04 , B01J21/06 , B01J23/02 , B01J23/30 , B01J23/36
CPC分类号： B01J23/688 , B01J21/16 , B01J23/66 , B01J27/055 , B01J35/1038 , B01J35/1042 , B01J35/1066 , B01J35/1071 , B01J35/1076 , B01J35/108 , B01J35/109 , C07D301/10 , Y02P20/52
摘要： The present invention relates to an improved carrier for an ethylene epoxidation catalyst, the carrier comprising alumina in combination with a stability-enhancing amount of mullite. The invention is also directed to an improved catalyst containing the improved carrier, as well as an improved process for the epoxidation of ethylene using the catalyst of the invention.
摘要翻译：本发明涉及用于乙烯环氧化催化剂的改进的载体，该载体包含氧化铝和增加稳定性量的莫来石。本发明还涉及含有改进的载体的改进的催化剂，以及使用本发明的催化剂使乙烯环氧化的改进方法。

30. 发明申请

WO2010008919A2 MULLITE-CONTAINING CARRIER FOR ETHYLENE OXIDE CATALYSTS 审中-公开
标题翻译：用于乙烯氧化物催化剂的含莫来石载体
公开(公告)号：WO2010008919A2
公开(公告)日：2010-01-21
申请号：PCT/US2009/048804
申请日：2009-06-26
申请人： SCIENTIFIC DESIGN COMPANY, INC. , PAK, Serguei , ROKICKI, Andrzej , KAWABATA, Shuji
发明人： PAK, Serguei , ROKICKI, Andrzej , KAWABATA, Shuji
CPC分类号： B01J23/688 , B01J21/16 , B01J23/66 , B01J27/055 , B01J35/1038 , B01J35/1042 , B01J35/1066 , B01J35/1071 , B01J35/1076 , B01J35/108 , B01J35/109 , C07D301/10 , Y02P20/52
摘要： The present invention relates to an improved carrier for an ethylene epoxidation catalyst, the carrier comprising alumina in combination with a stability-enhancing amount of mullite. The invention is also directed to an improved catalyst containing the improved carrier, as well as an improved process for the epoxidation of ethylene using the catalyst of the invention.
摘要翻译：本发明涉及用于乙烯环氧化催化剂的改进的载体，该载体包含氧化铝以及增加稳定性量的莫来石。本发明还涉及含有改进的载体的改进的催化剂，以及使用本发明的催化剂使乙烯环氧化的改进方法。

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