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21. 发明申请

WO2008140533A3 PROCESSES FOR MAKING COMPOSITES AND BLENDS OF LOOSE SINGLE-WALLED CARBON NANOTUBE ROPES (SWNT-RS) AND OTHER CARBON NANOTUBE ROPES WITH ACID SOLUBLE POLYMERS AND OTHER MATERIALS, AND PRODUCTS MADE THEREFROM 审中-公开
标题翻译：制备复合材料和松散单层碳纳米管（SWNT-RS）和其他碳纳米管的混合物与酸溶性聚合物和其他材料的制备方法及其制备方法
公开(公告)号：WO2008140533A3
公开(公告)日：2009-02-12
申请号：PCT/US2007077026
申请日：2007-08-28
申请人： UNIV RICE WILLIAM M , HWANG WEN-FANG , CHEN ZHEYI , TOUR JAMES M
发明人： HWANG WEN-FANG , CHEN ZHEYI , TOUR JAMES M
IPC分类号： C08J3/21 , C08J3/215 , C08K9/04
CPC分类号： C08J5/005 , B82Y30/00 , C08J3/215 , C08K9/04
摘要： Processes to make these composite materials or blends, and their shaped articles such as fibers, films and 3-D parts include mixing an acid intercalated SWNT-Rs with an acid soluble polymer and subjecting the resultant mixture to shear stresses. Composites and blends include loose single-walled carbon nanotube ropes (SWNT-Rs) and other acid-intercalatable carbon nanotube ropes with polymers such as aliphatic polyamides (nylon), aromatic polyamides (such as poly-p-phenylene terephthalamide, PPTA), or heterocyclic aromatic polymers (such as poly-p-phenylenebisbenzoxazole, PBO), or other materials which are soluble in common acidic media. Products such as fibers, films, and 3-dimensional articles are made from these materials.
摘要翻译：制备这些复合材料或共混物及其成型制品如纤维，膜和3-D部分的方法包括将酸插层的SWNT-Rs与酸溶性聚合物混合并使所得混合物经受剪切应力。复合材料和共混物包括松散的单壁碳纳米管绳索（SWNT-Rs）和其它具有聚合物如酸性可嵌入碳纳米管绳索的聚合物，例如脂族聚酰胺（尼龙），芳族聚酰胺（例如聚对苯二甲酰对苯二胺，PPTA）或杂环芳族聚合物（如聚对亚苯基双苯并恶唑，PBO）或其它可溶于普通酸性介质的材料。诸如纤维，薄膜和三维制品的产品由这些材料制成。

22. 发明申请

WO2007089322A3 PREPARATION OF THIN FILM TRANSISTORS (TFTs) OR RADIO FREQUENCY IDENTIFICATION (RFID) TAGS OR OTHER PRINTABLE ELECTRONICS USING INK-JET PRINTER AND CARBON NANOTUBE INKS 审中-公开
标题翻译：使用喷墨打印机和碳纳米管墨水制备薄膜晶体管（TFT）或无线电频率识别（RFID）标签或其他可打印电子
公开(公告)号：WO2007089322A3
公开(公告)日：2008-03-06
申请号：PCT/US2006045388
申请日：2006-11-24
申请人： UNIV RICE WILLIAM M , CHO GYOU-JIN , JUNG MIN HUN , HUDSON JARED L , TOUR JAMES M
发明人： CHO GYOU-JIN , JUNG MIN HUN , HUDSON JARED L , TOUR JAMES M
IPC分类号： H01L51/10
CPC分类号： H01L51/0005 , B82Y10/00 , H01L51/0022 , H01L51/0048 , H01L51/0049 , H01L51/0545 , Y10S977/847 , Y10S977/938
摘要： The invented ink-jet printing method for the construction of thin film transistors using all SWNTs on flexible plastic films is a new process. This method is more practical than all of exiting printing methods in the construction TFT and RFID tags because SWNTs have superior properties of both electrical and mechanical over organic conducting oligomers and polymers which often used for TFT. Furthermore, this method can be applied on thin films such as paper and plastic films while silicon based techniques can not used on such flexible films. These are superior to the traditional conducting polymers used in printable devices since they need no dopant and they are more stable. They could be used in conjunction with conducting polymers, or as stand-alone inks.
摘要翻译：本发明的用于在柔性塑料薄膜上构造使用所有SWNT的薄膜晶体管的喷墨打印方法是一个新的过程。该方法比建筑TFT和RFID标签中的所有现有印刷方法更实用，因为SWNT具有优于常用于TFT的有机导电低聚物和聚合物的电和机械性能。此外，该方法可以应用于诸如纸和塑料膜的薄膜上，而基于硅的技术不能用于这种柔性膜。它们优于用于可印刷装置的传统导电聚合物，因为它们不需要掺杂剂并且它们更稳定。它们可以与导电聚合物一起使用，或者作为独立的油墨使用。

23. 发明申请

WO2005012172A3 SELECTIVE FUNCTIONALIZATION OF CARBON NANOTUBES 审中-公开
标题翻译：碳纳米管的选择性功能化
公开(公告)号：WO2005012172A3
公开(公告)日：2006-03-30
申请号：PCT/US2004024507
申请日：2004-07-29
申请人： UNIV RICE WILLIAM M , UNIV ILLINOIS , STRANO MICHAEL S , USREY MONICA , BARONE PAUL , DYKE CHRISTOPHER A , TOUR JAMES M , KITTRELL W CARTER , HAUGE ROBERT H , SMALLEY RICHARD E
发明人： STRANO MICHAEL S , USREY MONICA , BARONE PAUL , DYKE CHRISTOPHER A , TOUR JAMES M , KITTRELL W CARTER , HAUGE ROBERT H , SMALLEY RICHARD E
IPC分类号： C01B31/02 , C08K9/08 , C09C1/44 , C09C1/56 , D01F11/14
CPC分类号： D01F11/14 , B82Y30/00 , B82Y40/00 , C01B32/172 , C01B32/174 , C01B2202/02 , C01B2202/22 , C01P2002/82 , C01P2002/84 , C01P2004/13 , C01P2004/133 , C01P2004/64 , C09C1/44 , C09C1/48 , C09C1/56 , Y10S977/734 , Y10S977/742 , Y10S977/745 , Y10S977/748
摘要： The present invention is directed toward methods of selectively functionalizing carbon nanotubes of a specific type or range of types, based on their electronic properties, using diazonium chemistry. The present invention is also directed toward methods of separating carbon nanotubes into populations of specific types or range(s) of types via selective functionalization and electrophoresis, and also to the novel compositions generated by such separations.
摘要翻译：本发明涉及使用重氮化学，基于其电子性质选择性官能化特定类型或范围的类型的碳纳米管的方法。本发明还涉及通过选择性官能化和电泳将碳纳米管分离成特定类型或范围的种类的方法，以及通过这种分离产生的新型组合物的方法。

24. 发明申请

WO2017011052A3 VERTICALLY ALIGNED CARBON NANOTUBE ARRAYS AS ELECTRODES 审中-公开
标题翻译：垂直排列的碳纳米管阵列作为电极
公开(公告)号：WO2017011052A3
公开(公告)日：2017-02-23
申请号：PCT/US2016029184
申请日：2016-04-25
申请人： UNIV RICE WILLIAM M
发明人： TOUR JAMES M , RAJI ABDUL-RAHMAN O , SALVATIERRA RODRIGO V
IPC分类号： H01J1/63 , H01J17/49 , H01J63/04
CPC分类号： H01M10/0525 , H01G11/06 , H01G11/28 , H01G11/36 , H01G11/68 , H01G11/86 , H01M4/045 , H01M4/587 , H01M4/625 , H01M4/66 , H01M4/661 , H01M4/663 , Y02E60/13
摘要： Embodiments of the present disclosure pertain to electrodes that include a plurality of vertically aligned carbon nanotubes and a metal associated with the vertically aligned carbon nanotubes. The vertically aligned carbon nanotubes may be in the form of a graphene-carbon nanotube hybrid material that includes a graphene film covalently linked to the vertically aligned carbon nanotubes. The metal may become reversibly associated with the carbon nanotubes in situ during electrode operation and lack any dendrites or mossy aggregates. The metal may be in the form of a non-dendritic or non-mossy coating on surfaces of the vertically aligned carbon nanotubes. The metal may also be infiltrated within bundles of the vertically aligned carbon nanotubes. Additional embodiments pertain to energy storage devices that contain the electrodes of the present disclosure. Further embodiments pertain to methods of forming said electrodes by applying a metal to a plurality of vertically aligned carbon nanotubes.
摘要翻译：本公开的实施例涉及包括多个垂直排列的碳纳米管和与垂直排列的碳纳米管相关联的金属的电极。垂直排列的碳纳米管可以是石墨烯 - 碳纳米管混合材料的形式，其包括与垂直排列的碳纳米管共价连接的石墨烯膜。在电极操作过程中，金属可能与碳纳米管原位可逆地结合，并且缺乏任何树突或苔状聚集体。金属可以在垂直排列的碳纳米管的表面上呈非树枝状或非苔藓状涂层的形式。金属也可以渗入垂直排列的碳纳米管束内。另外的实施例涉及包含本公开的电极的能量存储装置。其他实施例涉及通过将金属施加到多个垂直排列的碳纳米管来形成所述电极的方法。

25. 发明申请

WO2013162660A3 SYNTHESIS OF MAGNETIC CARBON NANORIBBONS AND MAGNETIC FUNCTIONALIZED CARBON NANORIBBONS 审中-公开
标题翻译：磁性纳米颗粒和磁性功能碳纳米管的合成
公开(公告)号：WO2013162660A3
公开(公告)日：2013-12-19
申请号：PCT/US2013023472
申请日：2013-01-28
申请人： UNIV RICE WILLIAM M , MI LLC
发明人： TOUR JAMES M , GENORIO BOSTJAN , LU WEI , PRICE-HOELSCHER BRANDI KATHERINE
IPC分类号： H01F1/34 , C01B31/02
CPC分类号： H01F1/01 , B82Y30/00 , B82Y40/00 , C01B32/168 , C01B32/194 , C09K8/032 , C09K8/32 , C09K8/36 , C09K2208/10 , E21B21/00 , E21B47/12
摘要： Various embodiments of the present disclosure pertain to methods of making magnetic carbon nanoribbons. Such methods generally include: (1) forming carbon nanoribbons by splitting carbon nanomaterials; and (2) associating graphene nanoribbons with magnetic materials, precursors of magnetic materials, or combinations thereof. Further embodiments of the present disclosure also include a step of reducing the precursors of magnetic materials to magnetic materials. In various embodiments, the associating occurs before, during or after the splitting of the carbon nanomaterials. In some embodiments, the methods of the present disclosure further comprise a step of (3) functionalizing the carbon nanoribbons with functionalizing agents. In more specific embodiments, the functionalizing occurs in situ during the splitting of carbon nanomaterials. In further embodiments, the carbon nanoribbons are edge-functionalized. Additional embodiments of the present disclosure pertain to magnetic carbon nanoribbon compositions that were formed in accordance with the methods of the present disclosure.
摘要翻译：本公开的各种实施方案涉及制备磁性碳纳米带的方法。这些方法通常包括：（1）通过分解碳纳米材料形成碳纳米带; 和（2）将石墨烯纳米带与磁性材料，磁性材料的前体或其组合相关联。本公开的另外的实施方案还包括将磁性材料的前体还原成磁性材料的步骤。在各种实施方案中，缔合发生在碳纳米材料分裂之前，期间或之后。在一些实施方案中，本公开的方法还包括（3）用官能化试剂官能化碳纳米带的步骤。在更具体的实施方案中，官能化在碳纳米材料分裂过程中就地发生。在另外的实施方案中，碳纳米带是边缘官能化的。本公开的另外的实施方案涉及根据本公开的方法形成的磁性碳纳米纤维组合物。

26. 发明申请

WO2016133571A3 LASER INDUCED GRAPHENE HYBRID MATERIALS FOR ELECTRONIC DEVICES 审中-公开
标题翻译：用于电子设备的激光诱导石墨混合材料
公开(公告)号：WO2016133571A3
公开(公告)日：2016-10-13
申请号：PCT/US2015062832
申请日：2015-11-27
申请人： UNIV RICE WILLIAM M
发明人： TOUR JAMES M , LI LEI , PENG ZHIWEI , ZHANG JIBO
IPC分类号： B32B9/00 , B32B3/00
CPC分类号： H01G11/36 , C01B32/184 , C01B32/194 , C01B32/20 , C01B2204/04 , C01B2204/22 , C01B2204/32 , H01M4/587 , H01M4/625 , Y02E60/13
摘要： In some embodiments, the present disclosure pertains to methods of producing a graphene hybrid material by exposing a graphene precursor material to a laser source to form a laser-induced graphene, where the laser-induced graphene is derived from the graphene precursor material. The methods of the present disclosure also include a step of associating a pseudocapacitive material (e.g., a conducting polymer or a metal oxide) with the laser-induced graphene to form the graphene hybrid material. The formed graphene hybrid material can become embedded with or separated from the graphene precursor material. The graphene hybrid materials can also be utilized as components of an electronic device, such as electrodes in a microsupercapacitor. Additional embodiments of the present disclosure pertain to the aforementioned graphene hybrid materials and electronic devices.
摘要翻译：在一些实施方案中，本公开内容涉及通过将石墨烯前体材料暴露于激光源以形成激光诱导的石墨烯来生产石墨烯混合材料的方法，其中所述激光诱导的石墨烯衍生自所述石墨烯前体材料。本公开的方法还包括将假电容材料（例如，导电聚合物或金属氧化物）与激光诱导的石墨烯缔合以形成石墨烯混合材料的步骤。形成的石墨烯混合材料可以与石墨烯前体材料嵌入或分离。石墨烯混合材料也可以用作电子器件的组件，例如微型电容器中的电极。本公开的另外的实施方案涉及上述石墨烯混合材料和电子装置。

27. 发明申请

WO2015175060A3 LASER INDUCED GRAPHENE MATERIALS AND THEIR USE IN ELECTRONIC DEVICES 审中-公开
标题翻译：激光诱导的石墨材料及其在电子设备中的应用
公开(公告)号：WO2015175060A3
公开(公告)日：2016-02-25
申请号：PCT/US2015016165
申请日：2015-02-17
申请人： UNIV RICE WILLIAM M
发明人： TOUR JAMES M , LIN JIAN , PENG ZHIWEI , KITTRELL CARTER
IPC分类号： C01B31/04
CPC分类号： H01M4/587 , C01B32/184 , C01B2204/04 , C01P2006/40 , C08G73/10 , H01G11/06 , H01G11/36 , H01G11/68 , H01G11/70 , H01M4/366 , H01M4/625 , H01M4/663 , H01M10/0525 , H01M10/054 , Y02E60/13
摘要： In some embodiments, the present disclosure pertains to methods of producing a graphene material by exposing a polymer to a laser source. In some embodiments, the exposing results in formation of a graphene from the polymer. In some embodiments, the methods of the present disclosure also include a step of separating the formed graphene from the polymer to form an isolated graphene. In some embodiments, the methods of the present disclosure also include a step of incorporating the graphene material or the isolated graphene into an electronic device, such as an energy storage device. In some embodiments, the graphene is utilized as at least one of an electrode, current collector or additive in the electronic device. Additional embodiments of the present disclosure pertain to the graphene materials, isolated graphenes, and electronic devices that are formed by the methods of the present disclosure.
摘要翻译：在一些实施方案中，本公开涉及通过将聚合物暴露于激光源来生产石墨烯材料的方法。在一些实施方案中，曝光导致从聚合物形成石墨烯。在一些实施方案中，本公开的方法还包括将形成的石墨烯与聚合物分离以形成分离的石墨烯的步骤。在一些实施例中，本公开的方法还包括将石墨烯材料或分离的石墨烯结合到诸如能量存储装置的电子装置中的步骤。在一些实施例中，石墨烯被用作电子设备中的电极，集电器或添加剂中的至少一个。本公开的另外的实施方案涉及通过本公开的方法形成的石墨烯材料，分离的石墨烯和电子器件。

28. 发明申请

WO2014089214A3 CARBON NANOPARTICLE ADDITIVES FOR WELLBORE FLUID CONDUCTIVITY 审中-公开
标题翻译：碳纳米管添加剂用于井筒流体电导率
公开(公告)号：WO2014089214A3
公开(公告)日：2014-09-04
申请号：PCT/US2013073123
申请日：2013-12-04
申请人： UNIV RICE WILLIAM M , MI LLC
发明人： TOUR JAMES M , CERIOTTI GABRIEL , SLESAREV ALEXANDER , YE RUQUAN , PRICE-HOELSCHER KATHERINE , BOVET CARA , FRIEDHEIM JIM , YOUNG STEVE
IPC分类号： B82Y30/00 , C09K8/34 , E21B7/15
CPC分类号： C09K8/32 , C09K8/03 , C09K2208/10 , E21B47/12 , G01V3/18 , G01V3/24 , Y02A90/342
摘要： Various embodiments of the present disclosure provide methods of making wellbore fluids with enhanced electrical conductivities. In some embodiments, such methods comprise: (1) pre-treating a carbon material with an acid; and (2) adding the carbon material to the wellbore fluid. Further embodiments of the present disclosure pertain to wellbore fluids formed by the methods of the present disclosure. Additional embodiments of the present disclosure pertain to methods for logging a subterranean well by utilizing the aforementioned wellbore fluids.
摘要翻译：本公开的各种实施方案提供了制造具有增强的电导率的井筒流体的方法。在一些实施方案中，这些方法包括：（1）用酸预处理碳材料; 和（2）将碳材料加入到井筒流体中。本公开的另外的实施例涉及通过本公开的方法形成的井眼流体。本公开的另外的实施例涉及通过利用上述井眼流体测井地下井的方法。

29. 发明申请

WO2015179035A3 PRODUCTION AND USE OF FLEXIBLE CONDUCTIVE FILMS AND INORGANIC LAYERS IN ELECTRONIC DEVICES 审中-公开
标题翻译：电子设备中柔性导电膜和无机层的生产和使用
公开(公告)号：WO2015179035A3
公开(公告)日：2016-03-03
申请号：PCT/US2015024945
申请日：2015-04-08
申请人： UNIV RICE WILLIAM M
发明人： TOUR JAMES M , YANG YANG , RUAN GEDENG
IPC分类号： B29D22/00
CPC分类号： H01M10/056 , C23C14/205 , C23C28/023 , C23C30/00 , C25D3/12 , C25D5/48 , C25D7/00 , C25D11/04 , C25D11/30 , C25D11/32 , C25D11/34 , H01B1/02 , H01G9/00 , H01G9/0036 , H01G9/025 , H01G9/042 , H01G9/15 , H01G11/00 , H01G11/30 , H01G11/56 , H01G11/86 , H01M4/582 , H01M4/663 , H01M10/0525 , H01M2004/021 , H01M2300/0091
摘要： Embodiments of the present disclosure pertain to methods of making conductive films by associating an inorganic composition with an insulating substrate, and forming a porous inorganic layer from the inorganic composition on the insulating substrate. The inorganic layer may include a nanoporous metal layer, such as nickel fluoride. The methods of the present disclosure may also include a step of incorporating the conductive films into an electronic device. The methods of the present disclosure may also include a step of associating the conductive films with a solid electrolyte prior to its incorporation into an electronic device. The methods of the present disclosure may also include a step of separating the inorganic layer from the conductive film to form a freestanding inorganic layer. Further embodiments of the present disclosure pertain to the conductive films and freestanding inorganic layers.
摘要翻译：本公开的实施例涉及通过将无机组合物与绝缘基板缔合而制造导电膜的方法，以及在绝缘基板上从无机组合物形成多孔无机层。无机层可以包括纳米多孔金属层，例如氟化镍。本公开的方法还可以包括将导电膜并入到电子器件中的步骤。本公开的方法还可以包括将导电膜与固体电解质结合到其结合到电子器件中之前的步骤。本公开的方法还可以包括从导电膜分离无机层以形成独立无机层的步骤。本公开的另外的实施方案涉及导电膜和独立无机层。

30. 发明申请

WO2016025051A2 GRAPHENE QUANTUM DOT-POLYMER COMPOSITES AND METHODS OF MAKING THE SAME 审中-公开
标题翻译：石墨量子聚合物复合材料及其制备方法
公开(公告)号：WO2016025051A2
公开(公告)日：2016-02-18
申请号：PCT/US2015032209
申请日：2015-05-22
申请人： UNIV RICE WILLIAM M
发明人： TOUR JAMES M , KOVALCHUK ANTON , XIANG CHANGSHENG
IPC分类号： C08K3/04 , H01L33/26
CPC分类号： C08F2/44 , C08J5/18 , C08J2329/04 , C08K3/042 , C08K2201/011 , C08L29/04
摘要： Various embodiments of the present disclosure pertain to methods of forming polymer composites that include polymers and graphene quantum dots. The methods occur by mixing a polymer component (e.g., polymers, polymer precursors and combinations thereof) with graphene quantum dots. In some embodiments, the polymers are in the form of a polymer matrix, and the graphene quantum dots are homogenously dispersed within the polymer matrix. In some embodiments, the graphene quantum dots include, without limitation, coal-derived graphene quantum dots, coke-derived graphene quantum dots, unfunctionalized graphene quantum dots, functionalized graphene quantum dots, pristine graphene quantum dots, and combinations thereof. Additional embodiments of the present disclosure pertain to polymer composites that are formed by the methods of the present disclosure. In some embodiments, the polymer composites of the present disclosure are fluorescent and optically transparent. In some embodiments, the polymer composites of the present disclosure are in the form of a film.
摘要翻译：本公开的各种实施方案涉及形成包括聚合物和石墨烯量子点的聚合物复合材料的方法。该方法通过将聚合物组分（例如聚合物，聚合物前体及其组合）与石墨烯量子点混合而发生。在一些实施方案中，聚合物是聚合物基质的形式，并且石墨烯量子点均匀地分散在聚合物基质内。在一些实施方案中，石墨烯量子点包括但不限于由煤衍生的石墨烯量子点，焦炭衍生的石墨烯量子点，未官能化石墨烯量子点，官能化石墨烯量子点，原始石墨烯量子点及其组合。本公开的另外的实施方案涉及通过本公开的方法形成的聚合物复合材料。在一些实施方案中，本公开的聚合物复合物是荧光和光学透明的。在一些实施方案中，本公开的聚合物复合材料为膜的形式。

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