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    • 17. 发明申请
    • PROCESS AND REACTOR FOR THE PRODUCTION OF HYDROGEN AND CARBON DIOXIDE AND A FUEL CELL SYSTEM
    • 生产氢气和二氧化碳以及燃料电池系统的工艺和反应器
    • WO2008000782A3
    • 2008-03-20
    • PCT/EP2007056453
    • 2007-06-28
    • SHELL INT RESEARCHASSINK GERRIT JAN BARENDKRAMER GERT JANNIJMEIJER ARIANVAN SINT ANNALAND MARTIN
    • ASSINK GERRIT JAN BARENDKRAMER GERT JANNIJMEIJER ARIANVAN SINT ANNALAND MARTIN
    • C01B3/38B01J19/24C01B3/50C01B32/50
    • C01B3/501B01D63/06B01D2315/08B01J8/009B01J8/18C01B3/384C01B32/50C01B2203/0233C01B2203/041C01B2203/0475
    • The invention relates to a process for the production of hydrogen and carbon dioxide from a hydrocarbonaceous feedstock, comprising: a) supplying a gaseous hydrocarbonaceous feedstock and steam to a reaction zone comprising a steam reforming catalyst and catalytically reforming the hydrocarbonaceous feedstock to produce a reformed gas comprising hydrogen and carbon dioxide; b) supplying a molecular oxygen-comprising gas to the permeate side of a first hydrogen separation membrane; c) contacting a part of the hydrogen with a first hydrogen separation membrane, allowing the hydrogen to permeate through the first hydrogen separation membrane and combusting the hydrogen with the molecular oxygen at a permeate side of the first hydrogen separation membrane to produce all heat necessary for catalytic reforming the hydrocarbonaceous feedstock; d) contacting the remainder of the hydrogen with a second hydrogen separation membrane, which is separate from the first hydrogen separation membrane, and allowing the hydrogen to permeate through the second hydrogen separation membrane to obtain a first effluent comprising a substantially pure stream of hydrogen; and e) removing a stream rich in carbon dioxide from the reaction zone as a second effluent. The invention further related to a reactor for such process and to a fuel cell system comprising in series such reactor and a fuel cell.
    • 本发明涉及从含烃原料生产氢气和二氧化碳的方法,其包括:a)将气态含烃原料和蒸汽供应到包含蒸汽转化催化剂的反应区,并催化转化含烃原料以产生转化气体 包含氢气和二氧化碳; b)将含分子氧的气体供应至第一氢分离膜的渗透侧; c)使一部分氢与第一氢分离膜接触,使氢透过第一氢分离膜并在第一氢分离膜的渗透侧与分子氧一起燃烧氢以产生所需的 催化重整含烃原料; d)使剩余的氢与第二氢分离膜接触,该第二氢分离膜与第一氢分离膜分离,并使氢透过第二氢分离膜以获得包含基本上纯的氢气流的第一流出物; 和e)从反应区排出富含二氧化碳的物流作为第二流出物。 本发明还涉及用于这种方法的反应器和涉及串联包括这种反应器和燃料电池的燃料电池系统。