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    • 12. 发明申请
    • ORGANIC LIGHT EMITTING DEVICE
    • WO2020074379A1
    • 2020-04-16
    • PCT/EP2019/076882
    • 2019-10-04
    • NOVALED GMBH
    • ROSENOW, ThomasHUMMERT, Markus
    • H01L51/54
    • The present Invention relates to an organic light emitting device comprising: (i) an anode; (ii) a cathode; (iii) at least one light emitting layer arranged between the anode and the cathode; (iv) optionally a first hole injection layer comprising a first hole injection compound, the first hole injection layer being arranged between the anode and the light emitting layer and the hole injection layer being adjacent to the anode; (v) a first hole transport layer comprising a first hole transport matrix compound, wherein the first hole transport layer is arranged a) between the first hole injection layer and the light emitting layer and adjacent to the first hole injection layer; or b) between the anode and the light emitting layer and adjacent to the anode; (vi) a second hole injection layer arranged between the first hole transport layer and the light emitting layer, wherein the second hole injection layer is adjacent to the first hole transport layer and wherein the second hole injection layer comprises a second hole injection compound; wherein the second hole injection compound is a halogenated fullerene, a partially or fully halogenated metal complex or a mixture thereof.
    • 14. 发明申请
    • SUBSTITUTED 1,2,3-TRIYLIDENETRIS(CYANOMETHANYLYLIDENE)) CYCLOPROPANES FOR VTE, ELECTRONIC DEVICES AND SEMICONDUCTING MATERIALS USING THEM
    • 取代的1,2,3-三氯苯(CYANOMETHANYLYLIDENE))用于VTE,电子器件和半导体材料的CYCLOPROPANES
    • WO2016097017A1
    • 2016-06-23
    • PCT/EP2015/080046
    • 2015-12-16
    • NOVALED GMBH
    • HUMMERT, MarkusBRUCH, AchimKÖHN, ChristianeNÜLLEN, Max P.
    • C07C255/35C09K11/06H01L51/00
    • H01L51/005C07C255/35C07C255/51C07C2601/02C07C2601/16C07D213/84C07D239/30C09K11/06C09K2211/1007C09K2211/1018H01L51/001H01L51/0067H01L51/506H01L51/5088H01L2251/554
    • The present invention relates to a process for preparation of an electrically doped semiconducting material comprising a [3]-radialene p-dopant or for preparation of an electronic device containing a layer comprising a [3]-radialene p-dopant, the process comprising the steps : (i) loading an evaporation source with the [3]-radialene p-dopant; and (ii) evaporating the [3]-radialene p-dopant at an elevated temperature and at a reduced pressure, wherein the [3]-radialene p-dopant is selected from compounds having a structure according to formula (I) wherein A 1 and A 2 are independently aryl- or heteroaryl- substituted cyanomethylidene groups, the aryl and/or heteroaryl is selected independently in A 1 and A 2 from 4-cyano-2,3,5,6-tetrafluorphenyl,2,3,5,6-tetrafluorpyridine-4-yl, 4-trifluormethyl-2,3,5,6-tetrafluorphenyl, 2,4-bis(trifluormethyl)-3,5,6-trifluorphenyl, 2,5-bis(trifluormethyl)-3,4,6-trifluorphenyl, 2,4,6-tris(trifluormethyl)-1,3-diazine-5-yl, 3,4-dicyano-2,5,6-trifluorphenyl, 2-cyano-3,5,6-trifluorpyridine-4-yl, 2-trifluormethyl-3,5,6-trifluorpyridine-4-yl, 2,5,6-trifluor-1,3-diazine-4-yl and 3-trifluormethyl-4-cyano-2,5,6-trifluophenyl), and at least one aryl or heteroaryl is 2,3,5,6-tetrafluorpirydine-4-yl, 2,4-bis(trifluormethyl)-3,5,6-trifluorphenyI, 2,5-bis(trifluormethyl)-3,4,6-trifluorphenyl, 2,4,6-tris(trifluormethyl)-1,3-diazine-5-yl, 3,4-dicyano-2,5,6-trifluorphenyl, 2-cyano-3,5,6-trifluorpyridine-4-yl, 2-trifluormethyl-3,5,6-trifluorphenyl, provided that the heteroaryl in both A 1 and A 2 cannot be 2,3,5,6-tetrafluorpyridine-4-yl at the same time, respective [3]-radialene compounds, and semiconducting materials and layer, and electronic devices comprising said compounds.
    • 本发明涉及一种制备包含[3] - 苊烯p-掺杂剂的电掺杂半导体材料的方法或用于制备含有包含[3] - ]芘p掺杂剂的层的电子器件,该方法包括 步骤:(i)加载具有[3] - 苊烯p-掺杂剂的蒸发源; 和(ii)在升高的温度和降低的压力下蒸发[3] - ]对 - 掺杂剂,其中[3] - ]芘对掺杂剂选自具有式(I)结构的化合物,其中A1和 A2独立地是芳基或杂芳基取代的氰基亚甲基,芳基和/或杂芳基在A1和A2中独立地选自4-氰基-2,3,5,6-四氟苯基,2,3,5,6-四氟吡啶 - 4-三氟甲基-2,3,5,6-四氟苯基,2,4-双(三氟甲基)-3,5,6-三氟苯基,2,5-双(三氟甲基)-3,4,6- 三氟苯基,2,4,6-三(三氟甲基)-1,3-二嗪-5-基,3,4-二氰基-2,5,6-三氟苯基,2-氰基-3,5,6-三氟吡啶-4 - 基,2-三氟甲基-3,5,6-三氟吡啶-4-基,2,5,6-三氟-1,3-二嗪-4-基和3-三氟甲基-4-氰基-2,5,6 - 三氟苯基),并且至少一个芳基或杂芳基是2,3,5,6-四氟吡啶-4-基,2,4-双(三氟甲基)-3,5,6-三氟苯基,2,5-双(三氟甲基 )-3,4,6-三氟苯基,2,4,6-三(三氟甲基) 或甲基)-1,3-二嗪-5-基,3,4-二氰基-2,5,6-三氟苯基,2-氰基-3,5,6-三氟吡啶-4-基,2-三氟甲基-3,5 ,6-三氟苯基,条件是A1和A2两者中的杂芳基不能同时为2,3,5,6-四氟吡啶-4-基,各自为[3] - ] ene烯化合物,半导体材料和层,以及电子 包含所述化合物的装置。