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11. 发明申请

WO2015128469A1 GAS PHASE POLYMERIZATION PROCESS 审中-公开
标题翻译：气相聚合方法
公开(公告)号：WO2015128469A1
公开(公告)日：2015-09-03
申请号：PCT/EP2015/054149
申请日：2015-02-27
申请人： BOREALIS AG
发明人： KANELLOPOULOS, Vasileios , KRALLIS, Apostolos , AL-HAJ ALI, Mohammad , TUPE, Ravindra
IPC分类号： C08F2/01 , C08F2/34
CPC分类号： C08F2/34 , C08F2/01 , C08F110/02
摘要： An olefin polymerization process comprising polymerizing olefins in gas phase in a fluidized bed in the presence of an olefin polymerization catalyst in a polymerization reactor having a vertical body; a generally conical downwards tapering bottom zone; a generally cylindrical middle zone having a height to diameter ratio L/D of at least 4, above and connected to said bottom zone; and a generally conical upwards tapering top zone above and connected to said middle zone wherein (i) fluidization gas is introduced to the bottom zone of the reactor from where it passes upwards through the reactor; (ii) the fluidization gas is withdrawn from the top zone of the reactor, filtered, compressed, cooled and returned into the bottom zone of the reactor; (iii) a fluidized bed is formed within the reactor where the growing polymer particles are suspended in the upwards rising gas stream; and (iv) there is no fluidization grid in the reactor; characterized in that the gas velocity is maintained in the reactor such that N Br is within the range of from 2.5 to 7.
摘要翻译：一种烯烃聚合方法，包括在具有垂直体的聚合反应器中，在烯烃聚合催化剂存在下，在流化床中气相聚合烯烃; 大致圆锥形的向下锥形底部区域; 大致圆柱形的中间区域，其高度与直径之比L / D至少为4，高于并连接到所述底部区域; 以及在所述中间区域上方并连接到所述中间区域的大致锥形的向上锥形顶部区域，其中（i）流化气体被引导到反应器的底部区域，从该区域向上通过反应器; （ii）流化气体从反应器的顶部区域排出，过滤，压缩，冷却并返回到反应器的底部区域; （iii）在反应器内形成流化床，其中生长的聚合物颗粒悬浮在向上升的气流中; 和（iv）反应器中不存在流化栅; 其特征在于，气体速度保持在反应器中，使得NBr在2.5至7的范围内。

12. 发明申请

WO2022069410A1 ETHYLENE COPOLYMERS WITH IMPROVED MELTING AND GLASS TRANSITION TEMPERATURE 审中-公开
公开(公告)号：WO2022069410A1
公开(公告)日：2022-04-07
申请号：PCT/EP2021/076517
申请日：2021-09-27
申请人： BOREALIS AG
发明人： AJELLAL, Noureddine , AL-HAJ ALI, Mohammad , RUSKEENIEMI, Jari-Jussi , SLEIJSTER, Henry , VERDURMEN, Edwin M.F.J. , DEFOER, Johan
IPC分类号： C08L23/08 , C08F210/16 , C08F2/06 , C08F4/6592
摘要： The present inventions concerns a copolymer of ethylene and an C3 to C8 alpha-olefin, wherein the copolymer has a density of 890 to 915 kg/m3 measured according to ISO 1183 and a MFR2 of 0.5 to 8.0 g/10min measured according to ISO 1133, wherein the alpha-olefin is present in the copolymer in an amount of 10 to 20 wt.%, wherein the copolymer has a melt point Tm between 100 and 120°C measured according to ISO 11357-3 and a Vicat softening temperature Tvicat of 80 to 96 °C.

13. 发明申请

WO2022069409A1 PLANT AND METHOD FOR THE PRODUCTION OF AN IN-LINE BLENDED POLYMER 审中-公开
公开(公告)号：WO2022069409A1
公开(公告)日：2022-04-07
申请号：PCT/EP2021/076502
申请日：2021-09-27
申请人： BOREALIS AG
发明人： AL-HAJ ALI, Mohammad , AJELLAL, Noureddine
IPC分类号： C08F2/01 , C08L23/08 , C08F210/16 , B01J19/18 , B01J19/24 , C08F2/06
摘要： The present inventions concerns a plant producing an in-line blended polymer comprising a first polymerisation reactor and a second polymerisation reactor, the first and second polymerisation reactors having different internal volumes, and a method for producing an in-line blended polymer.

14. 发明申请

WO2021144179A1 PROCESS FOR AVOIDING PHASE SEPARATION DURING SOLUTION POLYMERIZATION OF ETHYLENE-1-BUTENE COPOLYMERS 审中-公开
公开(公告)号：WO2021144179A1
公开(公告)日：2021-07-22
申请号：PCT/EP2021/050147
申请日：2021-01-07
申请人： BOREALIS AG
发明人： AL-HAJ ALI, Mohammad , AJELLAL, Noureddine
IPC分类号： C08F210/16 , C08F2/06 , C08F210/08
摘要： The present invention relates to a process for polymerizing ethylene-1-butene copolymers in a solution polymerization process by firstly modelling polymer systems for solution polymerization of ethylene-1-butene copolymers and then transferring pressure and temperature conditions from said modelled polymer systems to a solution polymerization process to ensure that the polymerized ethylene- 1-butene copolymer is completely solved in the solvent during the polymerization process.

15. 发明申请

WO2021122992A1 POLYMERIZATION PROCESS AND REACTOR FOR CONTROLLING MOLECULAR WEIGHT DISTRIBUTION AND COMONOMER COMPOSITION DISTRIBUTION 审中-公开
公开(公告)号：WO2021122992A1
公开(公告)日：2021-06-24
申请号：PCT/EP2020/086768
申请日：2020-12-17
申请人： BOREALIS AG
发明人： AL-HAJ ALI, Mohammad
IPC分类号： C08F210/16 , B01J19/26 , C08F4/6592 , C08F2/06 , B01J4/00 , B01J19/18 , B01J19/0013 , B01J19/0066 , B01J19/1806 , B01J19/1812 , B01J19/1837 , B01J2219/00123 , B01J2219/00159 , B01J2219/00186 , B01J4/008
摘要： A reactor for the polymerization of olefins comprising a first inlet for introducing a first stream comprising monomer(s), catalyst(s) and optionally hydrogen, solvent or comonomer(s) and/or mixtures thereof, at least one outlet for withdrawing a product stream, characterized in that the reactor further comprises at least one second inlet for introducing a second stream comprising monomer(s), catalyst(s) and optionally hydrogen, solvent or comonomer(s) and/or mixtures thereof; and a process for polymerizing olefins in a reactor according to the present invention, comprising the steps of introducing monomer(s), catalyst(s), and optionally hydrogen, solvent or comonomer(s) and/or mixtures thereof as the first stream via the first inlet into the reactor forming a reaction mixture; polymerizing a polymer from the reaction mixture; withdrawing the product stream via the at least one outlet from the reactor; characterized in that the process comprises a further step of introducing a second stream comprising monomer(s), catalyst(s), and optionally hydrogen, solvent or comonomer(s) and/or mixtures thereof into the reactor via the at least one second inlet into the reactor.

16. 发明申请

WO2019162448A1 PROCESS 审中-公开
公开(公告)号：WO2019162448A1
公开(公告)日：2019-08-29
申请号：PCT/EP2019/054457
申请日：2019-02-22
申请人： BOREALIS AG
发明人： AL-HAJ ALI, Mohammad , AJELLAL, Noureddine , KANELLOPOULOS, Vasileios , SLEIJSTER, Henry , ZITTING, Samuli , SAEED, Irfan
IPC分类号： B01J8/00 , C08F2/01 , C08F2/06 , C08F10/02
摘要： The invention provides process for separating hydrogen from a fluid feed stream in a polymerisation process, comprising the steps i) polymerising an olefin monomer and optionally at least one olefin comonomer in the presence of a solvent, optionally in the presence of hydrogen, so as to form a polymerisation reaction mixture comprising a polyolefin polymer, unreacted monomer(s), solvent andhydrogen; ii) separating said polyolefin polymer from said unreacted monomer(s), solvent and hydrogen, and optionally feeding said unreacted monomer(s), solvent and hydrogen to a heat exchanger,so as to produce said fluid feed stream comprising unreacted monomer(s), solvent and hydrogen; and iii) contacting said fluid feed stream with a heterogeneous hydrogenation catalyst so as to form a hydrogen-lean fluid stream.

17. 发明申请

WO2019162445A1 PROCESS 审中-公开
公开(公告)号：WO2019162445A1
公开(公告)日：2019-08-29
申请号：PCT/EP2019/054452
申请日：2019-02-22
申请人： BOREALIS AG
发明人： AL-HAJ ALI, Mohammad
IPC分类号： B01J8/00 , C08F2/01 , C08F2/06 , C08F10/02
摘要： The invention provides a process for separating hydrogen from a gaseous feed stream in a polymerisation process, comprising the steps i) polymerising an olefin monomer and optionally at least one olefin comonomer in the presence of a solvent, optionally in the presence of hydrogen, so as to form a polymerisation reaction mixture comprising a polyolefin polymer, unreacted monomer(s), solvent and hydrogen; (ii) separating said polyolefin polymer from said unreacted monomer(s), solvent and hydrogen so as to form said vapour feed stream comprising unreacted monomer(s), solvent and hydrogen; (iii) feeding said vapour feed stream to a heat exchanger so as to form a liquid feed stream comprising unreacted monomer(s), solvent and hydrogen; and (iv) contacting said liquid feed stream with a packed-bed stripping column so as to form a hydrogen-rich gaseous stream and a hydrogen-lean liquid stream.

18. 发明申请

WO2019002137A1 A METHOD OF REDUCING THE ENTRAINMENT OF POLYMER IN THE POLYMER-LEAN LIQUID PHASE IN A SEPARATOR 审中-公开
公开(公告)号：WO2019002137A1
公开(公告)日：2019-01-03
申请号：PCT/EP2018/066788
申请日：2018-06-22
申请人： BOREALIS AG
发明人： AL-HAJ ALI, Mohammad
IPC分类号： B01D17/02 , C08F6/00
摘要： The present invention relates to a method of reducing the entrainment of polymer in the polymer-lean liquid phase in a separator, comprising the steps of: (i) Selecting the diameter of the polymer droplets in the polymer solution entering the separator; (ii) Determining the traveling time of the polymer droplets in the separator; and (iii) Adjusting the residence time of the polymer-dense phase in the separator to be at least the traveling time of the polymer droplets, a solution polymerization process using said method for reducing the entrainment of polymer in the polymer-lean liquid phase in the separator and the use of said method for determining the minimum residence time of the polymer solution in the separator required to ensure efficient separation of a polymer solution into a polymer-lean phase and a polymer-rich phase.

19. 发明申请

WO2017108969A1 A PROCESS AND APPARATUS FOR IN-LINE BLENDING OF POLYMERS 审中-公开
标题翻译：用于在线共混聚合物的方法和设备
公开(公告)号：WO2017108969A1
公开(公告)日：2017-06-29
申请号：PCT/EP2016/082207
申请日：2016-12-21
申请人： BOREALIS AG
发明人： AL-HAJ ALI, Mohammad , BERGSTRA, Michiel , ERIKSSON, Erik , MATHIVANAN, Guhan , RÄSÄNEN, Jukka , SLEIJSTER, Henry , VIJAY, Sameer , WURNITSCH, Christof , ZITTING, Samuli , KANELLOPOULOS, Vasileios , AHO, Jani
IPC分类号： C08F2/06 , C08F6/00 , C08F6/12 , C08J11/02 , C08F2/00
CPC分类号： C08F6/003 , C08F2/001 , C08F2/06 , C08F6/12 , C08J11/02 , Y02P20/582 , C08L23/00
摘要： The present invention deals with a process for polymerising olefins in a solution and withdrawing a stream of the solution from the polymerisation reactor and passing it to a sequence of heating steps. The heated solution is passed to a separation step, which is conducted at a pressure of no more than 15 bar and in which separation step a liquid phase comprising the polymer and a vapour phase coexist. A vapour stream and a concentrated solution stream comprising the polymer are withdrawn from the separation step. At least a part of the vapour stream is passed to the first polymerisation reactor, to the second polymerisation reactor or to both.
摘要翻译：本发明涉及在溶液中聚合烯烃并从聚合反应器中取出溶液流并将其送入一系列加热步骤的方法。将加热后的溶液通入分离步骤，分离步骤在不超过15巴的压力下进行，并且在分离步骤中将包含聚合物和气相的液相共存。从分离步骤中取出蒸气流和包含聚合物的浓缩溶液流。至少一部分蒸气流被传送到第一聚合反应器，第二聚合反应器或两者。

20. 发明申请

WO2017097577A1 PROCESS FOR POLYMERISING ALPHA-OLEFIN MONOMERS 审中-公开
标题翻译：聚合α-烯烃单体的方法
公开(公告)号：WO2017097577A1
公开(公告)日：2017-06-15
申请号：PCT/EP2016/078380
申请日：2016-11-22
申请人： BOREALIS AG
发明人： ALASTALO, Kauno , AL-HAJ ALI, Mohammad , KANELLOPOULOS, Vasileios , KRALLIS, Apostolos
IPC分类号： C08F2/01 , B01J19/18 , B01J19/24 , C08F2/12
CPC分类号： C08F2/01 , B01J19/1837 , C08F2/12
摘要： A process for polymerising alpha-olefin monomers in a loop reactor comprising the steps of introducing a main feed stream (2) comprising at least one alpha-olefin monomer into the loop reactor (1); introducing a polymerisation catalyst into the loop reactor (1); polymerising the at least one alpha-olefin monomer in the presence of the polymerisation catalyst in the loop reactor (1) to produce a slurry comprising polyolefin particles; withdrawing an outlet stream (4) comprising at least a portion of the slurry from the loop reactor (1); adding a first feed stream (9) comprising the at least one alpha-olefin monomer and/or hydrogen to the outlet stream (4) to form a concentrator inlet stream (8); introducing the concentrator inlet stream (8) into a concentrator (5); withdrawing from the concentrator (5) an overflow stream (6) comprising the polyolefin particles, wherein the concentration of the polyolefin particles in the overflow stream (6) is smaller than in the concentrator inlet stream (8); withdrawing from the concentrator (5) a bottom outlet stream (12) comprising the polyolefin particles, wherein the concentration of the polyolefin particles in the bottom outlet stream (12) is greater than in the concentrator inlet stream (8); returning the overflow stream (6) into the loop reactor (1) in an area different from that from which the outlet stream (4) is withdrawn.
摘要翻译：一种在环管反应器中聚合α-烯烃单体的方法，包括以下步骤：将包含至少一种α-烯烃单体的主进料流（2）引入环管反应器（1）中; 将聚合催化剂引入环流反应器（1）中; 在回路反应器（1）中在聚合催化剂存在下聚合至少一种α-烯烃单体以产生包含聚烯烃颗粒的浆料; 从回路反应器（1）中取出包含至少一部分淤浆的出口流（4）; 将包含所述至少一种α-烯烃单体和/或氢气的第一进料流（9）加入所述出口流（4）以形成浓缩器入口流（8）; 将浓缩器入口流（8）引入浓缩器（5）中; 从浓缩器（5）中排出包含聚烯烃颗粒的溢流流（6），其中溢流流（6）中聚烯烃颗粒的浓度小于浓缩器入口流（8）中的浓度; 从浓缩器（5）中排出包含聚烯烃颗粒的底部出口流（12），其中底部出口流（12）中的聚烯烃颗粒的浓度大于浓缩器入口流（8）中的聚烯烃颗粒的浓度; 在与出口物流（4）被抽出的区域不同的区域中将溢流物流（6）返回到环流反应器（1）中。

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