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11. 发明申请

WO1998012158A1 PROCESS FOR THE TREATMENT OF LIGHT NAPHTHA HYDROCARBON STREAMS 审中-公开
标题翻译：用于处理轻质石墨烃流程的方法
公开(公告)号：WO1998012158A1
公开(公告)日：1998-03-26
申请号：PCT/US1997015133
申请日：1997-08-28
申请人： CHEMICAL RESEARCH & LICENSING COMPANY
发明人： CHEMICAL RESEARCH & LICENSING COMPANY , HEARN, Dennis , GILDERT, Gary, R.
IPC分类号： C07C05/00
CPC分类号： C10G65/06 , C10G2300/4087 , Y10S203/06
摘要： A process for treating a light cracked naphtha (1) to be used as an etherification or alkylation feedstock in which the mercaptans and diolefins react in a single pass fixed bed reactor (20) and are removed in a distillation column reactor (10) which hydrogenate the unreacted diolefins. The mercaptans are reacted with the diolefins to form sulfides which are higher boiling than that portion of the naphtha which is used as feed to the etherification or alkylation unit. The higher boiling sulfides are removed as bottoms along with any C6 and heavier materials. Any diolefins not converted to sulfides are selectively hydrogenated to mono-olefins for use in the etherification process. Certain C5 olefins, for example pentene-1 and 3-methyl butene-1 are isomerized during the process to more beneficial isomers.
摘要翻译：一种用于处理轻度裂化石脑油（1）的方法，其用作醚化或烷基化原料，其中硫醇和二烯烃在单程固定床反应器（20）中反应，并在蒸馏塔反应器（10）中除去，氢气化未反应的二烯烃。硫醇与二烯烃反应形成沸点高于用作醚化或烷基化单元的进料的石脑油部分的硫化物。较高沸点的硫化物作为底部以及任何C6和较重的材料被除去。任何未转化成硫化物的二烯烃都被选择性氢化成单烯烃，用于醚化过程。某些C5烯烃，例如戊烯-1和3-甲基丁烯-1在该过程中被异构化为更有益的异构体。

12. 发明申请

WO1998009930A1 SELECTIVE HYDROGENATION OF AROMATICS IN HYDROCARBON STREAMS 审中-公开
标题翻译：油气藏中芳烃选择性氢化
公开(公告)号：WO1998009930A1
公开(公告)日：1998-03-12
申请号：PCT/US1997014530
申请日：1997-08-18
申请人： CHEMICAL RESEARCH & LICENSING COMPANY
发明人： CHEMICAL RESEARCH & LICENSING COMPANY , GILDERT, Gary, R. , PUTMAN, Hugh, M. , HEARN, Dennis
IPC分类号： C07C05/10
CPC分类号： C10G45/44 , Y02P20/127 , Y10S203/06
摘要： A process for the hydrogenation of a selected aromatic, such as benzene contained in a naphtha stream to cyclohexane wherein the distillation column reactor (10) is operated such that the portion of the naphtha containing the benzene is maintained in the catalyst bed such that essentially only benzene is hydrogenated. The reactor is operated at a pressure wherein the reaction mixture is boiling under low hydrogen partial pressure in the range of about 0.1 psi to less than 70 psia at 0 to 350 psig. The catalyst is provided as a catalytic distillation structure (12) such that the reaction is concurrently occurring with a distillation. A portion of the overheads is returned as reflux to provide cooling within the catalyst bed and concurrent condensation of some of the gaseous material within the bed.
摘要翻译：将选择的芳族化合物，例如石脑油中所含的苯加氢至环己烷的方法，其中蒸馏塔反应器（10）的操作使得含有苯的部分石脑油保持在催化剂床中，使得基本上仅苯被氢化。反应器在压力下操作，其中反应混合物在0至350psig下在约0.1psi至小于70psia的低氢分压下沸腾。提供催化剂作为催化蒸馏结构（12），使得反应同时进行蒸馏。塔顶馏出物的一部分作为回流返回，以在催化剂床内提供冷却，同时使一些气态物质在床内冷凝。

13. 发明申请

WO1998006687A1 PROCESS FOR THE PRODUCTION OF MTBE 审中-公开
标题翻译：生产MTBE的方法
公开(公告)号：WO1998006687A1
公开(公告)日：1998-02-19
申请号：PCT/US1997007171
申请日：1997-04-28
申请人： CHEMICAL RESEARCH & LICENSING COMPANY , HICKEY, Thomas, P. , SMITH, Lawrence, A., Jr.
发明人： CHEMICAL RESEARCH & LICENSING COMPANY
IPC分类号： C07C43/04
CPC分类号： C07C41/06 , B01D3/009 , C07C41/42 , Y02P20/127 , C07C43/046
摘要： A process in which a dilute isobutylene stream containing normal butenes is hydroisomerized to remove butadiene and to isomerize the butene-1 to butene-2 and concurrently separate the higher boiling butene-2 from the remainder of the C4 stream in a distillation column reactor. The overheads containing a concentrated isobutene feed from the distillation column reactor are fed along with methanol to an etherification reactor where the isobutylene reacts with the methanol to form MTBE. The butene-2 bottoms may be skeletally isomerized to isobutene and utilized in an etherification reactor.
摘要翻译：将含有正丁烯的稀异丁烯流加氢异构化以除去丁二烯并使丁烯-1异构化为丁烯-2并同时将高沸点丁烯-2与蒸馏塔反应器中的C4流的剩余部分分离的方法。将含有来自蒸馏塔反应器的浓缩异丁烯进料的塔顶馏出物与甲醇一起进料至醚化反应器，其中异丁烯与甲醇反应形成MTBE。丁烯-2底部可以骨架异构化为异丁烯并用于醚化反应器中。

14. 发明申请

WO1998000366A1 ANTIMONY PENTAFLUORIDE 审中-公开
标题翻译：抗真菌药
公开(公告)号：WO1998000366A1
公开(公告)日：1998-01-08
申请号：PCT/US1997008006
申请日：1997-05-12
申请人： CHEMICAL RESEARCH & LICENSING COMPANY
发明人： CHEMICAL RESEARCH & LICENSING COMPANY , JOHNSON, Alan , WOODS, H., J. , CONNOR, H., J.
IPC分类号： C01G28/00
CPC分类号： B01J27/12 , C01G30/007
摘要： A method of preparing antimony pentafluoride comprising converting antimony compounds to hydroxonium fluoroantimonates by reaction of the antimony compounds with fluorinating material, such as hydrogen fluoride, in the presence of an oxidizing agent, such as hydrogen peroxide, removing water from the reaction product to concentrate the hydroxonium fluoroantimonates and reacting the hydroxonium fluoroantimonates with carbonyl difluoride to produce antimony pentafluoride. In one embodiment the hydroxonium fluoroantimonates are prepared by recovering the antimony from spent alkylation catalyst comprising SbF5 deposited on silica. The silica can also be recovered and recycled to produce a remanufactured alkylation catalyst.
摘要翻译：一种制备五氟化锑的方法，其包括在氧化剂如过氧化氢存在下，通过锑化合物与氟化物等氟化物质的反应，将锑化合物转化成氟代异头翁酸，从反应产物中除去水氟代异羟肟酸酯，并使氟代异羟肟酸羟基与二氟化碳羰基反应，生成五氟化锑。在一个实施方案中，通过从沉积在二氧化硅上的包含SbF 5的废烷基化催化剂回收锑来制备氟代异头物。二氧化硅也可回收再循环，生产再制烷基化催化剂。

15. 发明申请

WO1995032166A1 ALKYLATION OF ORGANIC AROMATIC COMPOUNDS 审中-公开
标题翻译：有机芳香化合物的烷基化
公开(公告)号：WO1995032166A1
公开(公告)日：1995-11-30
申请号：PCT/US1995004961
申请日：1995-05-03
申请人： CHEMICAL RESEARCH & LICENSING COMPANY
发明人： CHEMICAL RESEARCH & LICENSING COMPANY , SMITH, Lawrence, A., Jr.
IPC分类号： C07C02/64
CPC分类号： C07C15/073 , B01D3/009 , B01D3/14 , C07B37/02 , C07C2/66 , Y02P20/127 , Y10S203/06
摘要： The aging rate of the catalyst in a process for the concurrent alkylation of aromatic with olefin and distillation of reaction components (reactants and products) in a distillation column reactor (10) in a catalyst bed (101) wherein the catalyst also serves as the distillation structure, is retarded by limiting the conversion of olefin in the catalyst bed to about 90 percent. A portion up to and including the entire unreacted aromatic and olefin in the overhead (3) from the distillation column reactor are condensed and fed to a fixed bed alkylation reactor (20) to substantially finish the conversion with a portion of the effluent from the fixed bed reactor (13) recycled thereto to control the olefin content in the fixed bed reactor inlet to less than one volume percent, preferably less than 0.50 volume percent and thereby reduce the aging in that catalyst. A fixed bed transalkylation reactor (30) is used to convert the polysubstituted alkylated aromatic products to mono-substituted alkylated aromatic products.
摘要翻译：催化剂在催化剂床（101）中的蒸馏塔反应器（10）中的同时烷基化烯烃和蒸馏反应组分（反应物和产物）的方法中的催化剂的老化速率，其中催化剂也用作蒸馏结构通过将催化剂床中烯烃的转化率限制在约90％来阻止。将来自蒸馏塔反应器的塔顶馏出物（3）中直至并包括整个未反应的芳族和烯烃的部分冷凝并进料到固定床烷基化反应器（20）中以基本上完成来自固定的部分流出物的转化回收其中的床反应器（13）以控制固定床反应器入口中的烯烃含量小于一体积百分比，优选小于0.50体积％，从而减少催化剂中的老化。使用固定床烷基转移反应器（30）将多取代的烷基化芳族化合物转化成单取代的烷基化芳族化合物。

16. 发明申请

WO1994029010A1 CATALYTIC DISTILLATION STRUCTURE 审中-公开
标题翻译：催化蒸馏结构
公开(公告)号：WO1994029010A1
公开(公告)日：1994-12-22
申请号：PCT/US1994005621
申请日：1994-05-19
申请人： CHEMICAL RESEARCH & LICENSING COMPANY
发明人： CHEMICAL RESEARCH & LICENSING COMPANY , JOHNSON, Kenneth, H. , DALLAS, Albert, Bert
IPC分类号： B01F03/04
CPC分类号： B01J8/02 , B01J19/32 , B01J2219/3221 , B01J2219/3222 , B01J2219/32227 , B01J2219/32466 , Y02P20/127 , Y10S203/06
摘要： A catalytic distillation structure (10) having a plurality of corrugated vertically disposed catalyst containing elements (12) separated by inert spacing elements (24) is disclosed. The catalyst containing elements (12) each have two layers of gas permeable material (18, 20), such as wire mesh, joined together at regularly spaced intervals (13) to form a single sheet (12) having pockets (22) disposed on the surface. A particulate catalyst (26) is disposed within the pockets (22). The catalyst (26) within the pockets (22) provides a reaction zone where catalytic reactions may occur and the gas permeable sheets (18, 22) provide mass transfer surfaces to effect a fractional distillation. The spacing elements (14) allow for a variation of the catalyst density and loading.
摘要翻译：公开了一种催化蒸馏结构（10），其具有由惰性间隔元件（24）分开的多个波纹垂直设置的含催化剂的元件（12）。含有催化剂的元件（12）各自具有两层气体可渗透材料（18,20），例如金属丝网，以规则间隔的间隔（13）连接在一起，以形成具有凹口（22）的单个片材（12）表面。颗粒催化剂（26）设置在袋（22）内。袋（22）内的催化剂（26）提供反应区，其中可发生催化反应，并且透气片（18,22）提供传质表面以进行分馏。间隔元件（14）允许催化剂密度和负载的变化。

17. 发明申请

WO1997035834A1 AMINATION PROCESS 审中-公开
标题翻译：建筑工艺
公开(公告)号：WO1997035834A1
公开(公告)日：1997-10-02
申请号：PCT/US1997002822
申请日：1997-02-25
申请人： CHEMICAL RESEARCH & LICENSING COMPANY
发明人： CHEMICAL RESEARCH & LICENSING COMPANY , NEMPHOS, Speros, Peter , HEARN, Dennis
IPC分类号： C07C211/03
CPC分类号： C07C209/16 , Y02P20/127
摘要： A process for the amination of aliphatic alkane derivatives such as alcohols (mono and polyhydric) which uses catalytic distillation to take advantage of the condensing distillate within the distillation reaction zone in the distillation column reactor. The operation of the distillation column reactor results in both a liquid and vapor phase within the distillation reaction zone. The catalyst is prepared in the form of a distillation structure. The reaction is carried out in a distillation column reactor at a low hydrogen partial pressure, e.g. in the range of 0.1 psia to less than 10 psia.
摘要翻译：使用催化蒸馏来利用蒸馏塔反应器的蒸馏反应区内的冷凝馏出物的脂肪族烷烃衍生物（单醇和多元醇）的胺化方法。蒸馏塔反应器的操作导致蒸馏反应区内的液相和气相。催化剂以蒸馏结构的形式制备。反应在蒸馏塔反应器中在低氢分压下进行，例如，在0.1psia至小于10psia的范围内。

18. 发明申请

WO1997035823A1 METHOD FOR THE PREPARATION OF DIALKYL ETHERS 审中-公开
标题翻译：制备二烷基醚的方法
公开(公告)号：WO1997035823A1
公开(公告)日：1997-10-02
申请号：PCT/US1997002768
申请日：1997-02-25
申请人： CHEMICAL RESEARCH & LICENSING COMPANY
发明人： CHEMICAL RESEARCH & LICENSING COMPANY , NEMPHOS, Speros, Peter , HEARN, Dennis
IPC分类号： C07C41/00
CPC分类号： C07C41/42 , B01D3/009 , C07C41/09 , Y02P20/127 , C07C43/043 , C07C43/04
摘要： A method for producing dialkyl ethers comprising feeding a stream containing a C1 to C4 alcohol to a distillation column reactor into a feed zone, contacting the stream with a fixed bed zeolite prepared as a distillation structure to form the corresponding dialkyl ether and water, and concurrently fractionating the ether product from the water and unreacted materials, wherein the improvement is the addition of a small amount of hydrogen to the reaction zone to inhibit catalyst fouling and substantially increasing the catalyst life and activity.
摘要翻译：一种制备二烷基醚的方法，包括将含有C1至C4醇的物流进料到进料区，将该料流与作为蒸馏结构制备的固定床沸石接触以形成相应的二烷基醚和水，同时从水和未反应的物质中分离出醚产物，其中改进是向反应区加入少量的氢以抑制催化剂污染并显着增加催化剂的寿命和活性。

19. 发明申请

WO1997008272A1 GASOLINE DESULFURIZATION PROCESS 审中-公开
标题翻译：汽油脱硫方法
公开(公告)号：WO1997008272A1
公开(公告)日：1997-03-06
申请号：PCT/US1996011645
申请日：1996-07-12
申请人： CHEMICAL RESEARCH & LICENSING COMPANY
发明人： CHEMICAL RESEARCH & LICENSING COMPANY , HEARN, Dennis , HICKEY, Thomas, P.
IPC分类号： C10G45/00
CPC分类号： C10G65/06 , C10G2300/4087 , C10G2400/02 , Y02P20/127
摘要： A catalytic cracked naphtha is desulfurized with minimum loss of olefins and octane. The naphtha is fed to a first distillation column reactor (10) which acts as a depentanizer or dehexanizer with the lighter material containing most of the olefins and mercaptans being boiled up into a first distillation reaction zone (11) where the mercaptans are reacted with diolefins to form sulfides which are removed in the bottoms along with any higher boiling sulfur compounds. The bottoms are subjected to hydrodesulfurization in a second distillation column reactor (20) where the sulfur compounds are converted to H2S and removed. The lighter fraction containing most of the olefins is thus not subjected to the more harsh hydrogenation conditions of the second reactor (20).
摘要翻译：催化裂化石脑油以最少的烯烃和辛烷值的损失脱硫。将石脑油加入到第一蒸馏塔反应器（10）中，该反应器（10）充当脱苯胺或脱脂装置，其中较轻的材料含有大部分烯烃和硫醇被煮沸成第一蒸馏反应区（11），其中硫醇与二烯烃以形成硫化物，其随着任何更高沸点的硫化合物在塔底中除去。将塔底物在第二蒸馏塔反应器（20）中进行加氢脱硫，其中硫化合物转化为H 2 S并除去。因此，含有大部分烯烃的轻馏分不会受到第二反应器（20）的更苛刻的氢化条件的影响。

20. 发明申请

WO1997003148A1 IMPROVED PROCESS FOR SELECTIVE HYDROGENATION OF HIGHLY UNSATURATED COMPOUNDS AND ISOMERIZATION OF OLEFINS IN HYDROCARBON STREAMS 审中-公开
标题翻译：高度不饱和化合物的选择性加氢改进方法和油气中烯烃的异构化
公开(公告)号：WO1997003148A1
公开(公告)日：1997-01-30
申请号：PCT/US1996010885
申请日：1996-06-27
申请人： CHEMICAL RESEARCH & LICENSING COMPANY
发明人： CHEMICAL RESEARCH & LICENSING COMPANY , HEARN, Dennis , GILDERT, Gary, R. , PUTMAN, Hugh, M.
IPC分类号： C10G45/00
CPC分类号： C07C7/167 , B01D3/009 , B01J8/0453 , C07C7/163 , C07C2523/44 , C07C2523/755 , C10G2300/4087 , C10G2400/02 , Y02P20/127 , Y10S203/06
摘要： A process for treating C3 to C12 petroleum fractions, such as a light cracked naphtha to be used as an etherification feed stock in which H2S is removed by distillation of at least the C3 fraction and mercaptans and diolefins are removed simultaneously in a distillation column reactor (20) using a dual catalyst bed (22, 24). The mercaptans and H2S are reacted with the diolefins in the presence of a reduced nickel catalyst (22) to form sulfides which are higher boiling than the portion of the feed which is fractionated to an upper hydrogenation catalyst bed of palladium (24) for hydrogenating diolefins and acetylenes. The higher boiling sulfides are removed as bottoms (110) along with heavier materials. Any diolefins not converted to sulfides and acetylenes are selectively hydrogenated to mono-olefins in the presence of a palladium oxide catalyst in an upper bed (24), producing overheads (116), substantially free of sulfur compounds, diolefins and acetylenes.
摘要翻译：一种用于处理C3至C12石油馏分的方法，例如用作通过蒸馏至少C3馏分和硫醇和二烯烃除去H 2 S的醚化原料的轻质裂化石脑油在蒸馏塔反应器中同时除去 20）使用双催化剂床（22,24）。在还原的镍催化剂（22）的存在下，硫醇和H 2 S与二烯烃反应形成沸点高于进料的部分沸点的硫化物，该硫化物被分馏到钯（24）的上氢化催化剂床用于氢化二烯烃和炔类。较高沸点的硫化物与较重的材料一起作为底部（110）除去。任何未转化成硫化物和炔烃的二烯烃在上床（24）中在氧化钯催化剂存在下选择性氢化成单烯烃，产生基本上不含硫化合物，二烯烃和乙炔的塔顶馏出物（116）。

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