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    • 11. 发明申请
    • TWO-STAGE, GAS PHASE PROCESS FOR THE MANUFACTURE OF ALKYLENE GLYCOL
    • 两阶段气相法制备亚乙基二醇
    • WO2010017052A3
    • 2010-05-20
    • PCT/US2009051830
    • 2009-07-27
    • DOW TECHNOLOGY INVESTMENTS LLCNORONHA JOHN CCAMPBELL E JOSEPHKEEN BRIAN TNAGAKI DICK ASOO HWAILISPEARS DAVID ASZUL JOHN F
    • NORONHA JOHN CCAMPBELL E JOSEPHKEEN BRIAN TNAGAKI DICK ASOO HWAILISPEARS DAVID ASZUL JOHN F
    • C07C29/16C07C31/20
    • C07C29/106C07D301/06C07C31/202
    • A two-stage, gas phase process for manufacturing alkylene glycol (e.g., ethylene glycol) from an alkene (e.g., ethylene), oxygen and water, the process comprising the steps of: (A) Contacting under gas phase, oxidation conditions gaseous alkene and oxygen over a heterogeneous oxidation catalyst to produce a gaseous oxidation product comprising alkylene oxide, water and unreacted alkene; (B) Contacting under gas phase, hydrolysis conditions the gaseous oxidation product of (A) with added water over a heterogeneous hydrolysis catalyst to produce a gaseous alkylene glycol and unreacted alkene; and (C) Recycling the unreacted alkene of (B) to (A). The hydrolysis catalyst is selected from the group consisting of hydrotalcites, metal-loaded zeolites, phosphates, and metal-loaded ion-exchanged molecular sieves. The process improves over the conventional two-stage process by the elimination of steps and equipment to recover and refine alkylene oxide, the use of less water in the hydrolysis reaction, and the elimination of the entire evaporation train used in the recovery of alkylene glycol.
    • 用于由烯烃(例如乙烯),氧气和水制造亚烷基二醇(例如乙二醇)的两阶段气相方法,所述方法包括以下步骤:(A)在气相下接触,氧化条件为气态烯烃 和氧在非均相氧化催化剂上反应以产生包含氧化烯,水和未反应的烯烃的气态氧化产物; (B)在气相条件下接触,(A)的气态氧化产物与加入的水在非均相水解催化剂上进行水解以产生气态的亚烷基二醇和未反应的烯烃; (C)将(B)的未反应烯烃再循环至(A)。 水解催化剂选自水滑石,载有金属的沸石,磷酸盐和载有金属的离子交换分子筛。 该方法改进了传统的两步法,其中通过消除用于回收和精炼烯化氧的步骤和设备,在水解反应中使用更少的水以及消除用于回收亚烷基二醇的整个蒸发列。