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    • 15. 发明申请
    • SOLVENT ASSISTED PROCESS FOR RECOVERY OF PHTHALIC ANHYDRIDE IN THE LIQUID PHASE BY DISTILLATION
    • 用于通过蒸馏在液相中回收邻苯二甲酸酐的溶剂辅助方法
    • WO1998023572A1
    • 1998-06-04
    • PCT/US1997022413
    • 1997-11-26
    • EXXON CHEMICAL PATENTS INC.
    • EXXON CHEMICAL PATENTS INC.BAIEL, James, J.JONES, Larry, O.GRAY, Ralph, O., Jr.AGOSTO, Magdiel
    • C07C51/573
    • C07C51/573C07C63/16
    • A process for recovering phthalic anhydride as a liquid from a vapor phase oxidation product which comprises mixing the vapor phase oxidation product having a temperature of about 130 DEG C or greater with a first stream comprising a solvent having a boiling point in the range between about 150 to 350 DEG C and a freezing point of less then 40 DEG C, and, optionally, at least one by-product selected from the group consisting of: maleic anhydride, citraconic anhydride, benzoic acid and phthalic anhydride, in a contacting means such that a substantial portion of the phthalic anhydride contained within the vapor phase oxidation product transfers from the vapor phase to a liquid phase and a substantial portion of the first stream which are more volatile than phthalic anhydride transfer from the liquid phase to the vapor phase and wherein a vapor-to-liquid weight ratio in the range of between about 2 to 20 is exhibited within the contacting means, thereby forming a liquid phase phthalic anhydride product having a phthalic anhydride concentration in the range between about 50-100 wt.%, preferably 90-100 wt.%, without the formation of an intermediate solid phase.
    • 从气相氧化产物中回收邻苯二甲酸酐作为液体的方法,该方法包括将具有约130℃或更高温度的气相氧化产物与包含沸点在约150℃范围内的溶剂的第一流混合 350℃,低于40℃的凝固点,以及任选的至少一种选自马来酸酐,柠康酸酐,苯甲酸和邻苯二甲酸酐的副产物,其接触方式使得 气相氧化产物中所含的邻苯二甲酸酐的相当大部分从汽相转移到液相和大部分第一物流,其比邻苯二甲酸酐从液相转移到汽相更易挥发,其中a 在接触装置内表现出约2-20范围内的气 - 液重量比,从而形成液相邻苯二甲酸 邻苯二甲酸酐浓度在约50-100重量%之间,优选90-100重量%的范围内,而不形成中​​间固相。
    • 16. 发明申请
    • HYDROGENATION PROCESS FOR UNSATURATED HYDROCARBONS
    • 不饱和烃的加氢过程
    • WO1998022214A1
    • 1998-05-28
    • PCT/US1997021129
    • 1997-11-20
    • EXXON CHEMICAL PATENTS INC.
    • EXXON CHEMICAL PATENTS INC.HALUSKA, Jerry, L.PANNELL, Richard, B.
    • B01J35/10
    • C10G45/08B01J23/888B01J35/1019B01J35/1042B01J35/108
    • The invention relates to catalytic hydrogenation processes for hydrocarbon molecules of number-average molecular weight greater than about 180, and to use therein of an inert catalyst support comprising porous refractory substrate particles having: a) a pore volume distribution wherein i) pores having diameters > 150,000 ANGSTROM constitute greater than about 2 % of the total volume, ii) pores having diameters > 20,000 ANGSTROM and 2,000 ANGSTROM and
    • 本发明涉及数均分子量大于约180的烃分子的催化氢化方法,并且在其中使用包含多孔耐火基材颗粒的惰性催化剂载体,其具有:a)孔体积分布,其中i)直径> 15万个角度构成总体积的大约2%; ii)直径≥2000安格姆和<150,000安培的孔隙占总体积的大于约1%; iii)直径大于2,000安培和<20,000安培的孔隙构成更大 约占总量的12%; 和b)总孔体积为基体颗粒总体积的约45%至86%。 使用本发明,在工业操作中可以实现提高150%以上的树脂生产率。 由催化或热聚合的原料流制备并使用具有所述孔径分布的惰性载体氢化的烃树脂表现出至少与以前可获得的树脂相当的颜色和软化点特性。 此外,根据该方法制备的脂族 - 芳族树脂的芳族化度的增加可能导致作为苯乙烯嵌段共聚物,乙烯 - 乙烯基酯共聚物和丙烯酸共聚物粘合剂组合物的增粘剂的特别适合性。