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111. 发明申请

WO1983002278A1 PROCEDURE FOR PRODUCING SOLUBLE CELLULOSE DERIVATIVES 审中-公开
标题翻译：生产可溶性纤维素衍生物的方法
公开(公告)号：WO1983002278A1
公开(公告)日：1983-07-07
申请号：PCT/FI1982000069
申请日：1982-12-30
申请人： NESTE OY , TURUNEN, Olli , MANDELL, Leo , EKLUND, Vidar , EKMAN, Kurt , HUTTUNEN, Jouko, I.
发明人： NESTE OY
IPC分类号： C08B15/06
CPC分类号： F23G5/027 , C08B1/00 , C08B15/06 , F23G2201/303
摘要： Procedure for producing cellulose carbamate from cellulose and urea. To avoid alkali treatment of the cellulose used as starting material with a view to decreasing the degree of polymerisation of the cellulose, the cellulose in web form is exposed to a radiation dose of preferably 0.5 to 10 Mrad from a radiation source, whereafter the cellulose is reacted with urea at elevated temperature.
摘要翻译：从纤维素和尿素生产纤维素氨基甲酸酯的方法。为了避免对用作原料的纤维素进行碱处理以减少纤维素的聚合度，将纤维网形式的纤维素从放射源暴露于优选0.5-10Mrad的辐射剂量，之后纤维素为在高温下与尿素反应。

112. 发明申请

WO1997041088A1 PROCESS FOR PREPARING MONOESTERS OF 1,3-DIOLS 审中-公开
标题翻译：制备1,3-二醇单体的方法
公开(公告)号：WO1997041088A1
公开(公告)日：1997-11-06
申请号：PCT/FI1997000263
申请日：1997-04-29
申请人： NESTE OY , HEINOLA, Kalevi , KARVINEN, Esko , LINDFORS, Lars-Peter , KULMALA, Kari , HAKANPÄÄ-LAITINEN, Hannele , RINTALA, Lea , KUISMA, Eija , PARKKINEN, Lea
发明人： NESTE OY
IPC分类号： C07C67/44
CPC分类号： C07C67/44 , C07C69/003 , C07C69/28
摘要： The invention relates to a process for preparing monoesters of 1,3-diols. The invention relates to a process for preparing in particular 2,2,4-trimethyl-1,3-pentanediol monoisobutyrate, according to which process isobutyraldehyde is brought into contact with an alkalihydroxide catalyst. The alkali hydroxide catalyst used according to the invention is a dilute solution of lithium hydroxide, in which the concentration of lithium hydroxide is about 1 - 12 % by weight. An aqueous solution containing about 2 - 10 % by weight of sodium hydroxide and about 0.1 - 6 % by weight of lithium hydroxide, is used preferably. This enhances selectivity with respect to 1,3-diols, with an increased conversion of the aldehyde into a monoester and a subsequent decrease in recirculation volumes in the preparation process.
摘要翻译：本发明涉及一种制备1,3-二醇单酯的方法。本发明涉及一种制备特别是2,2,4-三甲基-1,3-戊二醇单异丁酸酯的方法，根据该方法使异丁醛与碱金属氢氧化物催化剂接触。根据本发明使用的碱金属氢氧化物催化剂是氢氧化锂的稀释溶液，其中氢氧化锂的浓度为约1至12重量％。优选使用含有约2-10重量％氢氧化钠和约0.1-6重量％氢氧化锂的水溶液。这提高了对1,3-二醇的选择性，醛的转化率增加到单酯中，随后在制备过程中再循环量减少。

113. 发明申请

WO1997032929A1 POLYLACTIDE FILMS 审中-公开
标题翻译：聚酰胺薄膜
公开(公告)号：WO1997032929A1
公开(公告)日：1997-09-12
申请号：PCT/FI1997000143
申请日：1997-03-04
申请人： NESTE OY , HILTUNEN, Elina , SKOG, Maria , SELIN, Johan-Fredrik
发明人： NESTE OY
IPC分类号： C08L67/04
CPC分类号： C08J5/18 , C08J2367/04 , C08K5/103 , C08L67/04 , C08L67/02
摘要： The invention relates to polylactide films the mechanical properties of which, in particular bursting strength, elongation and tearing strength, have been improved by adding to the polymer certain plasticizers. These plasticizers are preferably glycerol esters.
摘要翻译：本发明涉及通过向聚合物中加入某些增塑剂而改善其机械性能，特别是破裂强度，伸长率和撕裂强度的聚丙交酯膜。这些增塑剂优选为甘油酯。

114. 发明申请

WO1997030960A1 PROCESS FOR PREPARING ALKYL ETHERS AND MIXTURES THEREOF 审中-公开
标题翻译：制备烷基醚及其混合物的方法
公开(公告)号：WO1997030960A1
公开(公告)日：1997-08-28
申请号：PCT/FI1997000120
申请日：1997-02-21
申请人： NESTE OY , KOSKINEN, Matti , LINDQVIST, Petri , JÄRVELIN, Harri , AITTAMAA, Juhani
发明人： NESTE OY
IPC分类号： C07C41/06
CPC分类号： C07C41/42 , C07C41/06 , C07C43/046
摘要： The invention concerns a process for preparing a tertiary alkyl ether product. The process comprises reacting the isoolefins of an olefinic hydrocarbon feedstock in a reaction zone (1 - 3) with an alkanol to form a reaction mixture, which is subjected to distillation in a first distillation zone (4). The bottoms product of the first distillation contains the ether(s), whereas the overhead stream contains unreacted alkanol and a mixture of light hydrocarbons. The overhead stream is subjected to a second distillation in a second distillation zone (15). The overhead product of the second distillation mainly contains the lightest hydrocarbons and a small amount of alkanol, and the bottoms product contains an essentially oxygenate-free hydrocarbon stream which can be used as such for alkylation. In order to increase the conversion of the process, a side drawoff is withdrawn from the second distillation zone (15) and recirculated to the reaction zone (1 - 3).
摘要翻译：本发明涉及一种制备叔烷基醚产物的方法。该方法包括使反应区（1-3）中的烯烃原料的异烯烃与烷醇反应以形成反应混合物，其在第一蒸馏区（4）中进行蒸馏。第一次蒸馏的塔底产物含有醚，而顶部物流含有未反应的链烷醇和轻烃的混合物。塔顶流在第二蒸馏区（15）中进行第二次蒸馏。第二次蒸馏的塔顶产物主要含有最轻的烃和少量的链烷醇，底部产物含有基本上不含氧的烃流，可用于烷基化。为了增加该方法的转化率，从第二蒸馏区（15）中取出侧抽出物并再循环至反应区（1-3）。

115. 发明申请

WO1997023438A1 PROCESS FOR PREPARING ALKYL ETHERS AND MIXTURES THEREOF 审中-公开
标题翻译：制备烷基醚及其混合物的方法
公开(公告)号：WO1997023438A1
公开(公告)日：1997-07-03
申请号：PCT/FI1996000678
申请日：1996-12-19
申请人： NESTE OY , TAMMINEN, Esa , LINDQVIST, Petri
发明人： NESTE OY
IPC分类号： C07C43/04
CPC分类号： C07C41/42 , B01D3/009 , C07C41/06 , C10L1/023 , Y02P20/127 , C07C43/046
摘要： The invention relates to a process for preparing tertiary alkyl ethers, in particular MTBE, ETBE or mixtures of these ethers with heavier ethers. According to the process the feedstock containing hydrocarbons is fed to a catalytic distillation reactor system, in which the isoolefines, in particular the C4 to C7 isoolefines, of the feed are reacted with an alkanol in the presence of a cation exchange resin in order to produce tertiary alkyl ether products. The reaction product containing the ethers is removed from the distillation system as the bottoms product and, if necessary, it is subjected to an additional treatment for producing a gasoline component. The unreacted alkanol is removed as the overhead product of the distillation. According to the invention, the distillate withdrawn mainly contains an azeotrope of C3 hydrocarbons and alkanol, the C3 amount of which at least approximately corresponds to the C3 hydrocarbon concentration of the hydrocarbon feed, a substantial amount of the unreacted alkanol being removed in the form of said azeotrope. By means of the invention the need for a separate alkanol washing unit is eliminated in the apparatus which considerably reduces apparatus investment costs.
摘要翻译：本发明涉及一种制备叔烷基醚，特别是MTBE，ETBE或这些醚与较重醚的混合物的方法。根据该方法，将含有烃的原料进料到催化蒸馏反应器系统中，其中进料的异烯烃，特别是C4至C7异烯烃在阳离子交换树脂的存在下与烷醇反应，以产生叔烷基醚产物。含有醚的反应产物作为塔底产物从蒸馏系统中除去，如果需要，将其进行额外处理以生产汽油组分。将未反应的链烷醇作为蒸馏塔顶产物除去。根据本发明，取出的馏出物主要含有C 3烃和链烷醇的共沸物，其C3量至少大约对应于烃进料的C 3烃浓度，大量未反应的链烷醇以说共沸物。通过本发明，在装置中消除了对单独的烷醇洗涤单元的需求，这大大降低了设备的投资成本。

116. 发明申请

WO1997023437A1 PROCESS FOR PREPARING TERTIARY ALKYL ETHERS 审中-公开
标题翻译：制备仲胺醇的方法
公开(公告)号：WO1997023437A1
公开(公告)日：1997-07-03
申请号：PCT/FI1996000677
申请日：1996-12-19
申请人： NESTE OY , LINDQVIST, Petri
发明人： NESTE OY
IPC分类号： C07C43/04
CPC分类号： C07C41/06 , C07C41/42 , C07C43/046
摘要： A process for preparing tertiary alkyl ethers comprises the steps of reacting C4-7 isoolefins of an olefinic hydrocarbon feedstock with an alkanol in the presence of a first catalyst in a reaction zone to form a reaction mixture containing a tertiary alkyl ether or a mixture of tertiary alkyl ethers, feeding the reaction mixture to a distillation column, distilling the reaction mixture and recovering the alkyl ether(s) with the bottoms product of the distillation. An azeotrope formed by unreacted C4 hydrocarbons and the alkanol is withdrawn as an overhead product of the distillation. According to the invention, a part of the liquid flow of the column is withdrawn to form a side drawoff, and the side drawoff is recirculated to the reaction zone. As a result, the conversion of the reactive C6 hydrocarbons is increased and the operating cost of the ethers process is reduced.
摘要翻译：制备叔烷基醚的方法包括以下步骤：在反应区中，在第一催化剂存在下使烯烃原料的C 4-7异烯烃与链烷醇反应，形成含有叔烷基醚或叔烷基醚的混合物的反应混合物将反应混合物进料到蒸馏塔中，蒸馏反应混合物并用蒸馏塔底产物回收烷基醚。由未反应的C 4烃和链烷醇形成的共沸物作为蒸馏塔顶馏出物排出。根据本发明，塔的液体流的一部分被抽出以形成侧抽屉，并且侧抽屉被再循环到反应区。结果，反应性C6烃的转化率增加，并且醚过程的操作成本降低。

117. 发明申请

WO1996033147A1 PROCESS FOR OLIGOMERIZATION OF AROMATIC AND ALICYCLIC HYDROCARBONS HAVING OLEFINIC SIDE GROUP 审中-公开
标题翻译：具有烯烃基团的芳族和碱性烃的低聚方法
公开(公告)号：WO1996033147A1
公开(公告)日：1996-10-24
申请号：PCT/FI1995000105
申请日：1995-02-27
申请人： NESTE OY , KAPANEN, Mika , HALME, Erkki , KOSKIMIES, Salme , KEINÄNEN, Kari
发明人： NESTE OY
IPC分类号： C07C02/04
CPC分类号： C10M143/10 , C07C2/04 , C07C2527/1213 , C08F12/04 , C08L63/10 , C08L67/06 , C10L1/1608 , C10L1/1641 , C10L1/165 , C10L1/1691 , C10L1/18 , C10L1/1817 , C10L1/1955 , C10L1/1963 , C10M143/00 , C10M2205/04 , C10M2205/10 , C08L2666/04
摘要： The application relates to a process for the oligomerization of aromatic or alicyclic hydrocarbons by means of a complex made up of BF3 and a cocatalyst. The aromatic hydrocarbon may preferably be styrene, alpha-methyl styrene, or a mixture thereof, and the alicyclic hydrocarbon may be vinyl cyclohexane, vinyl cyclohexene, allyl cyclohexane, allyl cyclohexene, or a mixture thereof. The cocatalyst is an aliphatic alcohol, carboxylic acid, or inorganic acid. The oligomerization may be performed with or without a medium, at a temperature above 0 DEG C, the pressure being adjusted by means of BF3 to 1 - 10 bar. An oligomer prepared by the process can be used as a solvent or an additive in fuels or lubricants, in surfactants, in white oils and cosmetic oils requiring extra purity, and in PVC and polyolefin plastics. In polyester and vinyl ester resins this oligomer can be used to replace in part a monomer (e.g. styrene), thus reducing the evaporation of monomer, and to inhibit shrinkage at the hardening stage, and it also improves the optical properties of the said resins.
摘要翻译：本申请涉及通过由BF 3和助催化剂组成的络合物使芳族或脂环族烃低聚的方法。芳族烃可以优选为苯乙烯，α-甲基苯乙烯或其混合物，脂环族烃可以是乙烯基环己烷，乙烯基环己烯，烯丙基环己烷，烯丙基环己烯或其混合物。助催化剂是脂族醇，羧酸或无机酸。低聚反应可在有或没有介质的情况下，在高于0℃的温度下进行，压力通过BF 3调节至1-10巴。通过该方法制备的低聚物可用作燃料或润滑剂，表面活性剂，需要额外纯度的白油和化妆油中的溶剂或添加剂，以及PVC和聚烯烃塑料中。在聚酯和乙烯基酯树脂中，这种低聚物可以部分地替代单体（例如苯乙烯），从而减少单体的蒸发，并且抑制在硬化阶段的收缩，并且还改善了所述树脂的光学性能。

118. 发明申请

WO1995034721A1 WALL ELEMENT ARRANGEMENT 审中-公开
标题翻译：墙元素安排
公开(公告)号：WO1995034721A1
公开(公告)日：1995-12-21
申请号：PCT/FI1995000336
申请日：1995-06-09
申请人： NESTE OY , KARIMÄKI, Seppo
发明人： NESTE OY
IPC分类号： E04B01/88
CPC分类号： E04B1/10 , E04C2/205
摘要： Wall element for a wall structure containing thermal insulations (10) and additional insulations (40) in the form of boards as well as carriers consisting of vertical load-bearing studs (20) which can be at least partly embedded into grooves (11) in thermal insulation board (10). The thermal insulation comprises a board (10) of cellular plastic where at least on its one side are formed vertically oriented laterally spaced grooves (11), into which vertical load-bearing studs (20) of the wall element can be mounted by nailing or in some other such way to vertically oriented mounting ribs (30) located at the same point on the opposite side of thermal insulation board (10). The depth of grooves (11) in the surface of thermal insulation board (10) is chosen so that when embedded against bottom (12) of groove (11), the vertical load-bearing stud (20) will protrude from the surface level of thermal insulation board (10) by a distance equal to the thickness of additional insulation layer (40). The vertical sides of thermal insulation board (10) have grooves (14) and corresponding protrusions (15) to join the thermal insulation boards (10) of adjacent elements with a tongue-and-groove joint.
摘要翻译：用于壁结构的壁元件，其包含板状形式的热绝缘（10）和附加绝缘体（40），以及由垂直承载柱（20）组成的载体，所述承载柱可以至少部分地嵌入槽（11）中保温板（10）。隔热层包括多孔塑料的板（10），其中至少在其一侧上形成垂直定向的侧向间隔开的沟槽（11），墙壁元件的垂直承载柱（20）可以通过打钉或以其它一些方式，位于位于隔热板（10）相对侧上相同点处的垂直取向的安装肋（30）。选择绝热板（10）表面中的凹槽（11）的深度，使得当嵌入凹槽（11）的底部（12）时，垂直承载螺柱（20）将从绝热板（10）的距离等于附加绝缘层（40）的厚度。绝热板（10）的垂直侧面具有凹槽（14）和相应的突起（15），以使相邻元件的隔热板（10）与榫槽接头相接合。

119. 发明申请

WO1995026991A1 A METHOD TO OLIGOMERIZE C4 OLEFINS TOGETHER WITH LONG CHAIN OLEFINS 审中-公开
标题翻译： C4链烯醇与长链烯烃低聚的方法
公开(公告)号：WO1995026991A1
公开(公告)日：1995-10-12
申请号：PCT/FI1995000176
申请日：1995-03-31
申请人： NESTE OY , MIKES¿, Frantis¿ek , HALAS¿KA, Vlastimil , PECKA, Jan , MAREK, Miroslav , HALME, Erkki , KOSKIMIES, Salme
发明人： NESTE OY
IPC分类号： C08F210/08
CPC分类号： C07C2/30 , C07C2/22 , C07C2527/11 , C07C2527/126 , C07C2531/02 , C07C2531/14 , C08F10/04 , C08F10/14 , C08F110/04 , C08F110/14 , C08F210/04 , C08F210/14 , C10G50/02 , C08F2500/03 , C08F2500/02 , C08F2500/17
摘要： The invention concerns a process for producing synthetic oils and an olefinic polymer product which is useful as a synthetic oil or a part thereof. According to the process, olefinic hydrocarbons are polymerized in order to form an oil product having a high viscosity index and low pour point. According to the invention, the olefinic hydrocarbons used comprise C8-24 olefins with an internal double bond, which are subjected to a polymerization reaction with lower olefins, in particular 1- and 2-butenes. The reaction is carried out in the presence of an initiator system, which contains a compound of general formula (I) R2AlCl, wherein R represents halogen or an alkyl group containing 1 to 6 carbon atoms, in order to produce a polymerization product, and the polymerization product is separated from the reaction mixture in order to form a synthetic oil.
摘要翻译：本发明涉及可用作合成油或其一部分的合成油和烯烃聚合物产品的生产方法。根据该方法，使烯烃聚合以形成具有高粘度指数和低倾点的油产物。根据本发明，使用的烯烃包含具有内部双键的C8-24烯烃，它们与低级烯烃特别是1-和2-丁烯进行聚合反应。该反应是在引发剂体系存在下进行的，该引发剂体系含有通式（Ⅰ）R2AlCl的化合物，其中R表示卤素或含有1至6个碳原子的烷基，以便产生聚合产物，将聚合产物与反应混合物分离以形成合成油。

120. 发明申请

WO1994015895A1 METHOD FOR OLIGOMERIZATION OF OLEFINS AND OLEFIN MIXTURES 审中-公开
标题翻译：烯烃和烯烃混合物低聚方法
公开(公告)号：WO1994015895A1
公开(公告)日：1994-07-21
申请号：PCT/FI1993000540
申请日：1993-12-15
申请人： NESTE OY , KAPANEN, Mika , HALME, Erkki , KOSKIMIES, Salme
发明人： NESTE OY
IPC分类号： C07C02/20
CPC分类号： C07C2/20 , C07C2527/1213 , C07C2531/02 , C07C2531/04
摘要： The invention relates to the oligomerization of olefins or olefin mixtures, in particular long-chain hydrocarbon mixtures containing 6-20 carbon atoms or butenes, or mixtures of these said olefins, by means of a BF3/cocatalyst complex, the cocatalyst being water, a C2-C10 monoalcohol or a C2-C10 monocarboxylic acid. Examples of especially preferred cocatalysts are pentanol and n-valeric acid. BF3 is fed in gaseous state into the oligomerization reactor, and the reactor is pressurized thereby. In case a monomer mixture is oligomerized, the product is a true co-oligomer and it also contains double bonds which increase product reactivity, needed when the oligomer is used as an intermediate.
摘要翻译：本发明涉及烯烃或烯烃混合物，特别是含有6-20个碳原子或丁烯的长链烃混合物，或这些所述烯烃的混合物，通过BF 3 /助催化剂络合物，助催化剂为水， C2-C10一元醇或C2-C10一元羧酸。特别优选的助催化剂的实例是戊醇和正戊酸。 BF 3以气态进料到低聚反应器中，反应器被加压。在单体混合物低聚的情况下，产物是真正的共低聚物，并且还含有提高产物反应性的双键，当低聚物用作中间体时所需的反应性。

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