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91. 发明申请

WO2010015736A1 CATALYSEUR À BASE DE ZÉOLITHE IZM-2 ET PROCÉDÉ D'HYDROCONVERSION / HYDROCRAQUAGE DE CHARGES HYDROCARBONÉES 审中-公开
标题翻译：基于IZM-2沸石的催化剂和基于烃基进料的氢化/加氢反应的方法
公开(公告)号：WO2010015736A1
公开(公告)日：2010-02-11
申请号：PCT/FR2009/000942
申请日：2009-07-29
申请人： IFP , GUILLON, Emmanuelle , SIMON, Laurent
发明人： GUILLON, Emmanuelle , SIMON, Laurent
IPC分类号： B01J29/035 , B01J29/04 , C01B39/48 , B01J29/70 , C01B39/46 , C10G45/08 , C10G47/20
CPC分类号： B01J29/76 , B01J21/04 , B01J21/12 , B01J29/78 , B01J37/0009 , B01J37/20 , B01J2229/20 , B01J2229/42 , C01B39/48 , C10G47/16 , C10G47/20 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/4018
摘要： La présente invention concerne un catalyseur comprenant au moins une zéolithe IZM-2, au moins une matrice amorphe, au moins un élément hydro-déshydrogénant choisi dans le groupe formé par les éléments du groupe VIB et du groupe VIII de la classification périodique en excluant le platine et le palladium. Le catalyseur renferme également éventuellement au moins un élément dopant en quantité contrôlée choisi parmi le phosphore, le bore et le silicium, éventuellement au moins un élément du groupe VB de la classification périodique des éléments, et éventuellement un élément du groupe VIIA. L'invention concerne également les procédés d'hydrocraquage et d'hydrotraitement mettant en œuvre ce catalyseur.
摘要翻译：本发明涉及包含至少一种IZM-2沸石，至少一种无定形基质，至少一种加氢脱氢元素的催化剂，所述至少一种加氢脱氢元件选自由VIB族元素和元素周期表第VIII族除铂之外形成的基团和钯。催化剂还含有至少一种选自磷，硼和硅的受控量的至少一种掺杂元素，任选地，元素周期表第VB族元素中的至少一种元素，以及任选的来自VIIA族的元素。本发明还涉及使用该催化剂的加氢裂化和加氢处理方法。

92. 发明申请

WO2006079028A8 HYDROCRACKING OF HEAVY FEEDSTOCKS WITH IMPROVED HYDROGEN MANAGEMENT 审中-公开
标题翻译：改进氢气管理的重质原油加氢裂化
公开(公告)号：WO2006079028A8
公开(公告)日：2006-12-14
申请号：PCT/US2006002296
申请日：2006-01-23
申请人： EXXONMOBIL RES & ENG CO , VIETS JOHN W , SUNDARAM NARASIMHAN , KAUL BAL K , STERN DAVID L
发明人： VIETS JOHN W , SUNDARAM NARASIMHAN , KAUL BAL K , STERN DAVID L
IPC分类号： B01D53/047 , B01D53/22 , C10G47/00 , C10G47/02 , C10G47/18 , C10G47/20
CPC分类号： B01D53/0473 , B01D2253/10 , B01D2253/104 , B01D2253/106 , B01D2253/108 , B01D2256/16 , B01D2256/24 , B01D2257/304 , B01D2257/406 , B01D2257/504 , B01D2257/702 , B01D2257/80 , C01B3/56 , C01B2203/042 , C01B2203/048 , C10G45/58 , C10G47/00 , C10G47/02 , C10G47/18 , C10G47/20 , C10G49/007 , C10G2400/10 , Y02C10/08 , Y02P20/152
摘要： An improved process for hydrocracking heavy petroleum feedstocks wherein hydrogen-containing streams associated with a hydrocracker are subjected to rapid cycle pressure swing adsorption having a cycle time of less than 30 S.
摘要翻译：一种改进的加氢裂化重质石油原料的方法，其中与加氢裂化器有关的含氢物流经受循环时间小于30S的快速循环变压吸附。

93. 发明申请

WO2006071963A1 HYDROCRACKING CATALYSTS FOR VACUUM GAS OIL & DE-METALIZED BLEND 审中-公开
标题翻译：用于真空气体和非金属混合物的水解催化剂
公开(公告)号：WO2006071963A1
公开(公告)日：2006-07-06
申请号：PCT/US2005/047341
申请日：2005-12-29
申请人： SAUDI ARABIAN OIL COMPANY , ARAMCO SERVICES COMPANY , AL-NAEEM, Walid, A. , AHMED, Shakeel
发明人： AL-NAEEM, Walid, A. , AHMED, Shakeel
IPC分类号： B01J29/03 , B01J23/883 , C10G45/08 , C10G47/20
CPC分类号： C10G47/16 , B01J21/12 , B01J23/85 , B01J23/883 , B01J29/005 , B01J29/0308 , B01J29/041 , B01J29/044 , B01J29/045 , B01J29/084 , B01J29/166 , B01J29/7007 , B01J35/002 , B01J35/1019 , B01J35/1038 , B01J37/20 , B01J2229/20 , C10G45/08 , C10G45/12 , C10G47/12 , C10G47/20 , C10G65/12
摘要： This invention relates to a catalyst and a process for treating heavy hydrocarbons using the catalyst. The catalyst is useful for treating heavy hydrocarbons, de-metallize oil (DMO) and is particularly useful in VGO/DMO hydrocarbon blend. It is also useful for DAO. The catalyst acts to catalytically convert the VGO/DMO blend to shorter-chain valuable hydrocarbon products. The catalyst includes a catalytic support material, a catalytic metal impregnated upon the catalytic support material, and a promoter metal on the catalytic support material to enhance catalytic conversion. The combination of the catalytic support material with catalytic metal and promoter metal is operable to catalytically convert VGO/DMO into hydrocarbon products having shorter carbon chains.
摘要翻译：本发明涉及使用该催化剂处理重质烃的催化剂和方法。该催化剂可用于处理重质烃，脱金属油（DMO），并且特别适用于VGO / DMO烃共混物。它也对DAO有用。催化剂用于将VGO / DMO共混物催化转化为短链有价烃产物。催化剂包括催化载体材料，浸渍在催化载体材料上的催化金属和催化载体材料上的促进剂金属以增强催化转化。催化载体材料与催化金属和促进剂金属的组合可操作以将VGO / DMO催化转化成具有较短碳链的烃产物。

94. 发明申请

WO2004009736A1 CATALIZADOR DE HIDROCRAQUEO QUE COMPRENDE UN MATERIAL SÓLIDO CRISTALINO MICROPOROSO 审中-公开
标题翻译：包含微晶结晶固体材料的水解催化剂
公开(公告)号：WO2004009736A1
公开(公告)日：2004-01-29
申请号：PCT/ES2003/000367
申请日：2003-07-15
申请人： CONSEJO SUPERIOR DE INVESTIGACIONES CIENTIFICAS , UNIVERSIDAD POLITECNICA DE VALENCIA , CORMA CANOS, AVELINO , MARTINEZ FELIU, Agustin , REY GARCIA, Fernando , DIAZ CABANAS, Maria, José , LÓPEZ CRUZ, Carlos
发明人： CORMA CANOS, AVELINO , MARTINEZ FELIU, Agustin , REY GARCIA, Fernando , DIAZ CABANAS, Maria, José , LÓPEZ CRUZ, Carlos
IPC分类号： C10G47/20
CPC分类号： C10G47/18 , B01J23/24 , B01J23/74 , B01J23/85 , B01J29/04 , B01J35/0006 , B01J37/20 , B01J2229/20 , B01J2229/42 , C10G47/04 , C10G47/14 , C10G47/16 , C10G47/20
摘要： La presente invención se refiere a un catalizador para hidrocraqueo que comprende: - un componente hidrogenante seleccionado entre al menos un metal del grupo VIB, al menos un metal del grupo VIII, y combinaciones de ellos, - al menos una matriz que comprende al menos un óxido seleccionado entre un óxido amorfo, un óxido de baja cristalinidad, y mezcla de ambos, y -al menos un material sólido cristalino microporoso que presenta una composición molar en su estado calcinado y anhidro dada por X 2 O 3 : N yo 2 : m ZO 2 , en la que X es Ge, y que en su forma calcinada y anhidra presenta un difractograma de rayos X conteniendo al menos líneas de difracción a valores de d= 13.64, 7.87, 4.82, 4.55, 4.11 y 3.41 Ă, a su procedimiento de preparación y a su uso en procesos de hidrocraqueo de hidrocarburos.
摘要翻译：本发明涉及加氢裂化催化剂，其包含：选自至少一种VIB族金属，至少一种VIII族金属及其组合的加氢组分; 至少一种包含至少一种选自无定形氧化物，低结晶度氧化物和二者的混合物的氧化物的基体; 和至少一种微孔结晶固体材料，其在煅烧和无水状态下具有摩尔组成X 2 O 3 :N YO 2 :M ZO 2，其中X是三价元素，Y是至少一种不同于Ge的四价元素，Z是 Ge，并且其在煅烧和无水状态下具有至少包含D值= 13.64,7.87,4.82,4.55,4.11和3.41的衍射线的X射线衍射图。本发明还涉及制备本发明催化剂的方法及其在烃加氢裂化方法中的用途。

95. 发明申请

WO0069993A9 DUAL CATALYST SYSTEM 审中-公开
标题翻译：双催化剂体系
公开(公告)号：WO0069993A9
公开(公告)日：2002-07-04
申请号：PCT/US0013060
申请日：2000-05-12
申请人： MOBIL OIL CORP
发明人： ROSE BRENDA H , KILIANY THOMAS R
IPC分类号： B01J29/74 , C10G45/52 , C10G47/20 , C10G65/08 , C10G65/12
CPC分类号： C10G65/12
摘要： This application is related to a process for hydrocracking of heavy naphtha feeds. An improvement in the selectivity of the hydrocracking process was observed by decoupling aromatics saturation and hydrocracking reactions. This benefit has been observed for hydrocracking with either noble metal or base metal catalysts. The improved selectivity was observed in a low pressure as well as standard pressure operation. A decrease in the amount of light gas (C1-C4) and an increase in the amount of liquid product produced was observed. Decoupling the aromatic saturation and hydrocracking reactions also resulted in a significant improvement in process operability (i.e., decreased runaway tendency) and controllability and a reduction in catalyst deactivation rate.
摘要翻译：本申请涉及重质石脑油原料加氢裂化工艺。通过解离芳烃饱和度和加氢裂化反应观察到加氢裂化过程的选择性的改善。已经观察到用贵金属或贱金属催化剂进行加氢裂化的这个益处。在低压以及标准压力操作中观察到改进的选择性。观察到轻质气体（C1-C4）的量减少和产生的液体产物量的增加。芳族饱和和加氢裂化反应的去偶合也导致了工艺操作性（即失控趋势减少）和可控性的显着改善以及催化剂失活速率的降低。

96. 发明申请

WO02050213A2 PROCESS TO PREPARE A SPINDLE OIL, LIGHT MACHINE OIL AND A MEDIUM MACHINE OIL BASE OIL GRADE FROM THE BOTTOMS FRACTION OF A FUELS HYDROCRACKING PROCESS 审中-公开
标题翻译：从燃料加氢过程的底部分段制备主轴油，光机油和介质机油基油分级的方法
公开(公告)号：WO02050213A2
公开(公告)日：2002-06-27
申请号：PCT/EP2001/015134
申请日：2001-12-18
IPC分类号： C10G45/08 , C10G45/50 , C10G45/64 , C10G47/20 , C10G65/12 , C10M101/02 , C10M171/02
CPC分类号： C10M171/02 , C10G65/12 , C10G2400/10 , C10M101/02
摘要： Process to prepare a spindle oil, light machine oil and a medium machine oil base oil grade by (a) performing a separate catalytic dewaxing on a spindle oil fraction, a light machine oil fraction and a medium machine oil fraction as obtained in a vacuum distillation of a bottoms fraction of a fuels hydrocracking process; (b) performing a separate hydrofinishing of the light and medium machine oil fractions obtained in step (a); (c) separating the low boiling compounds from the spindle oil, light machine oil and medium machine oil fractions as obtained in step (a) and (b) and obtaining the spindle oil, light machine oil and medium machine oil base oil grade; (e) wherein the vacuum distillation is performed by alternatingly performing the distillation in two modes wherein the first mode (d1) the bottoms fraction is separated into a gas oil fraction, a spindle oil fraction, a medium machine oil fraction and a first rest fraction boiling between said spindle oil and medium machine oil fraction and in the second mode (d2) the bottoms fraction is separated into a gas oil fraction, a spindle oil fraction, a light machine oil fraction and a second rest fraction boiling above the light machine oil fraction.
摘要翻译：通过（a）在真空蒸馏中获得的主轴油馏分，轻质机油馏分和中等机油馏分上进行单独的催化脱蜡来制备主轴油，轻油机油和中等机油基油级的方法的燃料加氢裂化过程的底部馏分; （b）对步骤（a）中获得的轻和中间机油馏分进行单独的加氢精制; （c）从步骤（a）和（b）中获得的主轴油，轻油机油和中等机油馏分中分离低沸点化合物，得到主轴油，轻机油和中机油基油级; （e）其中通过以两种模式交替进行蒸馏来进行真空蒸馏，其中第一模式（d1）将塔底馏分分离成粗柴油馏分，锭子油馏分，中间机油馏分和第一剩余馏分在所述主轴油和中间机油部分之间沸腾，并且在第二模式（d2）中，塔底部分被分离为粗柴油馏分，主轴油馏分，轻机油馏分和在轻机油上方沸腾的第二剩余馏分分数。

97. 发明申请

WO01098436A1 CATALYTIC HYDROGENATION PROCESS UTILIZING MULTI-STAGE EBULLATED BED REACTORS 审中-公开
标题翻译：催化加氢方法利用多级EBULLED BED反应器
公开(公告)号：WO01098436A1
公开(公告)日：2001-12-27
申请号：PCT/EP2000/005628
申请日：2000-06-19
IPC分类号： B01J23/88 , B01J35/10 , C10G45/08 , C10G47/20 , C10G47/26 , C10G65/10 , C10G65/12
CPC分类号： C10G65/10
摘要： A process for catalytic multi-stage hydrogenation of heavy hydrocarbonaceous feedstocks using catalytic ebullated bed reactors, operated at generally the same reaction conditions. In the process, the feedstock is reacted with hydrogen in a first stage catalytic ebullated bed reactor at operating conditions of 700-850 DEG F temperature, 800-3000 psi hydrogen partial pressure at the reactor outlet, 0.2-2.0 V,/hr/V, liquid hourly space velocity, catalyst space velocity of 0.03-0.33 bbl/day per pound of fresh catalyst and at reduced superficial gas velocity of 0.02-0.3 ft/sec in each reactor, so as to provide increased percentage liquid volume and reduced gas hold-up in each reactor. The first stage reactor effluent liquid portion is fed into the second stage reactor. The second stage reactor effluent is phase separated and fractionated to produce lower boiling liquid products. A vacuum bottoms fraction normally boiling above about 650 DEG F and preferably above 900 DEG F is recycled back to the first stage reactor.
摘要翻译：使用在通常相同的反应条件下操作的催化沸腾床反应器对重质烃原料进行催化多级氢化的方法。在此过程中，原料与第一级催化沸腾床反应器中的反应器在700-850°F温度，反应器出口处的800-3000 psi氢分压，0.2-2.0 V / hr / V ，每小时新鲜催化剂的液时空速，催化剂空速为0.03-0.33桶/天，每个反应器中的表面气速为0.02-0.3ft / sec，以提供增加的液体体积百分比和减少的气体保持在每个反应堆中。将第一级反应器流出液部分进料到第二级反应器中。将第二级反应器流出物相分离并分级以产生较低沸点的液体产物。通常沸点高于约650°F，优选高于900°F的真空塔底馏分被再循环回到第一级反应器。

98. 发明申请

WO01000753A1 ZEOLITE CATALYST AND ITS USE IN HYDROREFINING AND HYDROCRACKING 审中-公开
标题翻译：沸石催化剂及其在水解和水解中的应用
公开(公告)号：WO01000753A1
公开(公告)日：2001-01-04
申请号：PCT/FR2000/001733
申请日：2000-06-22
IPC分类号： B01J29/076 , C10G47/20
CPC分类号： C10G47/20 , B01J29/076
摘要： The invention concerns a catalyst containing at least a matrix, at least a zeolite and at least a hydro-dehydrogenating element located in the matrix (deposited on the catalyst or contained in the matrix), wherein the zeolite contains in its porous system at least an element of group VIB and/or of group VIII. Said hydro-dehydrogenating element preferably belongs to group VIB and/or group VIII of the periodic table of elements. The catalyst contains at least a promoter element (phosphorus, boron, silicon). The invention also concerns the use of said catalyst for transforming hydrocarbon cuts, in particular hydrorefining and hydrocracking.
摘要翻译：本发明涉及至少含有一种基质，至少一种沸石和至少一种位于该基质中的加氢脱氢元素（沉积在该催化剂上或包含在该基质中）的催化剂，其中该沸石在其多孔体系中含有至少一种 VIB组和/或VIII组的元件。所述加氢脱氢元件优选属于元素周期表VIB族和/或VIII族。催化剂至少含有助催化剂元素（磷，硼，硅）。本发明还涉及所述催化剂用于转化烃馏分，特别是加氢精制和加氢裂化的用途。

99. 发明申请

WO99029810A1 DEWAXING PROCESS 审中-公开
标题翻译：脱蜡工艺
公开(公告)号：WO99029810A1
公开(公告)日：1999-06-17
申请号：PCT/US1998/026112
申请日：1998-12-09
IPC分类号： C10G47/12 , C10G45/64 , C10G47/16 , C10G47/20
CPC分类号： C10G47/16 , C10G45/64
摘要： The process of the invention for converting a hydrocarbon oil includes the following steps: (1) contacting a hydrocarbon oil feedstock in the presence of added hydrogen gas with a catalyst selected from the group consisting of a SAPO-11, SAPO-31 or SAPO-41 intermediate pore size silicoaluminophosphate molecular sieve and a hydrogenation component, and mixtures thereof, wherein at least a portion of the feedstock is converted; and (2) passing at least a portion of the converted feedstock to a fractionator, wherein at least a portion of the converted feedstock is fractionated, thereby producing at least one overhead fraction and one bottoms fraction; and (3) mixing at least a portion of the bottoms fraction with the hydrocarbon oil feedstock in step (1).
摘要翻译：本发明用于转化烃油的方法包括以下步骤：（1）在加入的氢气存在下使烃油原料与选自SAPO-11，SAPO-31或SAPO-31的催化剂接触， 41中等孔径硅铝磷酸盐分子筛和氢化组分及其混合物，其中原料的至少一部分被转化; 和（2）将至少一部分转化的原料通入分馏塔，其中将至少一部分转化的原料分馏，从而产生至少一种塔顶馏分和一种塔底馏分; 和（3）在步骤（1）中将至少一部分塔底馏分与烃油原料混合。

100. 发明申请

WO9820970A8 CATALYST FOR HYDROCRACKING AND A METHOD FOR PRODUCING GAS OIL WITH LOW POUR POINT 审中-公开
标题翻译：用于水解的催化剂和用于生产具有低点的气体的方法
公开(公告)号：WO9820970A8
公开(公告)日：1999-05-20
申请号：PCT/HU9600077
申请日：1996-12-16
申请人： MOL MAGYAR OLAJ & GAZIPARI RT , BALAI MARIA , BEYER HERMANN , BORBELY GABRIELLA , CZAGLER ISTVAN , FEHER PAL , FORSTNER JANOS , GEORGIADES GABOR , GERGELY JANOS , HORVATH JOZSEF , JOVER BELA , KANTOR LASZLO , KOVACS IMRE , LENCSE ISTVAN , PERGER JOZSEF , PETRO JOZSEF , RATOSI ERNO , SZALMASNE PECSVARI GABRIELLA , SZIRMAI LASZLO , SZOLLOSI JOZSEF , ZSIDA LASZLO
发明人： BALAI MARIA , BEYER HERMANN , BORBELY GABRIELLA , CZAGLER ISTVAN , FEHER PAL , FORSTNER JANOS , GEORGIADES GABOR , GERGELY JANOS , HORVATH JOZSEF , JOVER BELA , KANTOR LASZLO , KOVACS IMRE , LENCSE ISTVAN , PERGER JOZSEF , PETRO JOZSEF , RATOSI ERNO , SZALMASNE PECSVARI GABRIELLA , SZIRMAI LASZLO , SZOLLOSI JOZSEF , ZSIDA LASZLO
IPC分类号： B01J29/42 , B01J29/46 , C10G45/64 , C10G47/16 , C10G47/20 , B01J29/34
CPC分类号： C10G47/16 , B01J29/46 , B01J2229/26 , B01J2229/42 , C10G45/64
摘要： The invention relates to a new catalyst applicable in hydrocracking of hydrocarbons. The catalyst according to the invention contains as catalytically active components: a) a ZSM-5 zeolite wherein 10-100 % of the exchangeable hydrogen ions have been replaced by nickel ions, and b) 0.3-3 parts by weight of magadiite in hydrogen form for 1 part by weight of component (a). The catalyst according to the invention can be applied to particular advantage in hydrodewaxing of gas oil, and enables one to produce gas oil with extremely low pour point.
摘要翻译：本发明涉及适用于加氢裂化烃的新型催化剂。根据本发明的催化剂包含作为催化活性组分：a）ZSM-5沸石，其中10-100％的可交换氢离子已经被镍离子代替，以及b）0.3-3重量份的氢化镁土矿对于1重量份的组分（a）。根据本发明的催化剂可以在瓦斯油的加氢脱蜡中具有特别的优点，并且能够生产具有极低倾点的瓦斯油。

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