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91. 发明申请

WO1993015510A1 COLORED ELECTRICALLY CONDUCTIVE POLYANILINE COMPOUNDS 审中-公开
标题翻译：彩色电导电聚苯胺化合物
公开(公告)号：WO1993015510A1
公开(公告)日：1993-08-05
申请号：PCT/FI1993000032
申请日：1993-02-03
申请人： NESTE OY , CAO, Young , SMITH, Paul
发明人： NESTE OY
IPC分类号： H01B01/12
CPC分类号： H01B1/128 , C08G73/0266 , C08K5/0041 , Y10S428/913 , C08L79/02
摘要： Colored, electrically conductive compositions comprising substituted and unsubstituted polyanilines and functionalized protonic acids and blends with insulating and semiconducting substrate polymers or polymers plus solvents are disclosed as are methods of forming colored electrically conductive articles of polyaniline/substrate/acid mixtures.
摘要翻译：公开了包含取代和未取代的聚苯胺和官能化质子酸和与绝缘和半导体底物聚合物或聚合物加溶剂的共混物的着色的导电组合物，是形成聚苯胺/底物/酸混合物的有色导电制品的方法。

92. 发明申请

WO1993013141A1 PROCATALYST COMPOSITION FOR HOMO- AND COPOLYMERIZATION OF ALPHA OLEFINS, ITS PREPARATION AND ITS USE 审中-公开
标题翻译： ALPHA烯烃的共聚合和其共聚物的制备及其使用的方法
公开(公告)号：WO1993013141A1
公开(公告)日：1993-07-08
申请号：PCT/FI1992000362
申请日：1992-12-23
申请人： NESTE OY , ALA-HUIKKU, Sirpa , LOMMI, Marjaana
发明人： NESTE OY
IPC分类号： C08F04/654
CPC分类号： C08F10/00 , C08F4/6546 , C08F4/6555
摘要： A procatalyst composition which is suitable for the homo- and copolymerization of alpha olefins together with an organometallic cocatalyst compound and which is prepared by treating an inorganic carrier with a component system containing a complex of a magnesium halide and a tetraalkyl titanate, and a chlorinating compound which does not contain a transition metal compound. In order to raise the Mg:Ti ratio, the component system additionally contains an organomagnesium compound.
摘要翻译：一种适用于α-烯烃与有机金属助催化剂化合物同时和共聚合的主催化剂组合物，其通过用含有卤化镁和钛酸四烷基酯的络合物的组分体系和氯化化合物处理无机载体而制备其不含过渡金属化合物。为了提高Mg:Ti比，组分体系另外含有有机镁化合物。

93. 发明申请

WO1993012106A1 PROCESS FOR THE PREPARATION OF 3-SUBSTITUTED THIOPHENES 审中-公开
标题翻译：制备三取代噻吩的方法
公开(公告)号：WO1993012106A1
公开(公告)日：1993-06-24
申请号：PCT/FI1992000333
申请日：1992-12-08
申请人： NESTE OY , JÄRVINEN, Hannele , LAHTINEN, Leila , HORMI, Osmo , NÄSMAN, Jan , TAMMI, Anna-Liisa
发明人： NESTE OY
IPC分类号： C07D333/08
CPC分类号： C07D333/08
摘要： The invention relates to a process for the preparation of 3-substituted thiophenes in which the substituent is a C4-C18-alkyl group. According to the invention, the preparation is carried out by allowing an alkali metal salt of a C4-C18-alkyl-succinic acid to react with a compound of sulfur and phosphorus, e.g. tetraphosphorus decasulfide, in an organic solvent at a temperature of 100-180 DEG C, the product obtained being 3-(C4-C18-alkyl)thiophene. The said reaction may be the last step in a process in which the initial material is maleic acid anhydride with which alpha -C4-C18-alkene is combined so that C4-C18-alkenylsuccinic acid anhydride is obtained, whereafter this is hydrogenated catalytically to produce C4-C18-alkylsuccinic acid anhydride. This is thereafter reacted with an alkali metal hydroxide so that an alkali salt of the C4-C18-alkylsuccinic acid is obtained, which salt is reacted with a compound of sulfur and phosphorus to produce 3-(C4-C18-alkyl)thiophene, which constitutes the final product.
摘要翻译：本发明涉及一种制备其中取代基为C 4 -C 18 - 烷基的3-取代噻吩的方法。根据本发明，通过使C4-C18-烷基 - 琥珀酸的碱金属盐与硫和磷的化合物反应来进行制备。十四烷基四硫化物，在有机溶剂中，温度为100-180℃，所得产物为3-（C 4 -C 18 - 烷基）噻吩。所述反应可以是其中初始材料是马来酸酐与其中α-C 4 -C 18 - 烯烃组合使得得到C 4 -C 18 - 烯基琥珀酸酐的方法中的最后一个步骤，然后将其氢化催化以产生 C4-C18-烷基琥珀酸酐。然后与碱金属氢氧化物反应，得到C4-C18-烷基琥珀酸的碱金属盐，该盐与硫和磷的化合物反应生成3-（C 4 -C 18烷基）噻吩，其中构成最终产品。

94. 发明申请

WO1992019659A1 A LARGE-PORE POLYOLEFIN, A METHOD FOR ITS PRODUCTION AND A PROCATALYST CONTAINING A TRANSESTERIFICATION PRODUCT OF A LOWER ALCOHOL AND A PHTHALIC ACID ESTER 审中-公开
标题翻译：大孔聚烯烃，其生产方法和含有低级醇和酸式酯的转化产物的方法
公开(公告)号：WO1992019659A1
公开(公告)日：1992-11-12
申请号：PCT/FI1992000083
申请日：1992-03-23
申请人： NESTE OY , GAROFF, Thomas , LEINONEN, Timo , LISKOLA, Eero
发明人： NESTE OY
IPC分类号： C08F10/00
CPC分类号： C08F110/06 , C08F10/00 , C08F4/6543 , C08F2500/18 , C08F2500/15
摘要： The invention relates to a method for the preparation of polyolefins by polymerizing olefin by using a procatalyst composition prepared by bringing together magnesium chloride, a lower alcohol, a titanium compound, and phthalic acid ester. The invention also relates to the said procatalyst composition. The invention has succeeded in lowering the concentrations of titanium and phthalic acid ester in the catalyst, and thereby also in the polyolefin, and at the same time in preparing large-pore polyolefin, which is important for certain purposes. These properties have been obtained by using a procatalyst of the said type, in the preparation of which a transesterification has been performed between the lower alcohol and the phthalic acid ester, and the phthalic acid ester selected for the transesterification is one the alkoxy group of which has at minimum 10 carbon atoms.
摘要翻译：本发明涉及通过使用通过将氯化镁，低级醇，钛化合物和邻苯二甲酸酯聚合而制备的前催化剂组合物聚合烯烃来制备聚烯烃的方法。本发明还涉及所述前催化剂组合物。本发明成功地降低了催化剂中钛和邻苯二甲酸酯的浓度，从而降低了聚烯烃中的浓度，同时在制备大孔聚烯烃的同时，这对于某些目的是重要的。这些性质是通过使用所述类型的前催化剂制备的，其中在低级醇和邻苯二甲酸酯之间已经进行了酯交换反应，而选择用于酯交换反应的邻苯二甲酸酯是其烷氧基具有至少10个碳原子。

95. 发明申请

WO1992017465A1 METHOD OF PREPARING 3-SUBSTITUTED THIOPHENE 审中-公开
标题翻译：制备三取代噻吩的方法
公开(公告)号：WO1992017465A1
公开(公告)日：1992-10-15
申请号：PCT/FI1992000090
申请日：1992-03-26
申请人： NESTE OY , NÄSMAN, Jan , HORMI, Osmo , TAMMI, Anna-Liisa
发明人： NESTE OY
IPC分类号： C07D333/08
CPC分类号： C07D333/08
摘要： Method of preparing 3-substituted thiophene with formula (I) in which formula R is alkyl, by treating N-alkyl-3-alkyl-2-thiophene amide with a strong acid to loose the amide group and thus to get the compound of formula (I).
摘要翻译：通过用强酸处理N-烷基-3-烷基-2-噻吩酰胺来制备式（I）的3-取代噻吩的方法，其中式R 1是烷基，以松散酰胺基，从而得到式（I）化合物。

96. 发明申请

WO1992014724A1 PROCESS FOR PREPARING THIOPHENE AND ITS DERIVATIVES 审中-公开
标题翻译：制备噻吩及其衍生物的方法
公开(公告)号：WO1992014724A1
公开(公告)日：1992-09-03
申请号：PCT/FI1992000046
申请日：1992-02-20
申请人： NESTE OY , HEINOLA, Kalevi , HORMI, Osmo , NYHOLM, Per , NÄSMAN, Jan , TAMMI, Anna-Liisa , KOSKIMIES, Salme , TUOMINEN, Simo , LAHTINEN, Leila , KARJALAINEN, Sari , MONONEN, Pirjo , PARKKINEN, Lea
发明人： NESTE OY
IPC分类号： C07D333/08
CPC分类号： C07D333/08
摘要： In the process according to the invention for the preparation of thiophene and particularly a thiophene, the non-sulphur bound carbon of which is substituted, the product is produced by treating succinic anhydride or especially substituted succinic anhydride with a sulphur compound. The sulphur compound is preferably a sulphur compound, which contains phosphorus, such as phosphorus pentasulphide. The stated treatment with a sulphur compound forms according to one embodiment the end stage of the process, in which 1-alkene is attached to maleic anhydride to give an 1-alkenyl-succinic anhydride, the 1-alkenylsuccinic anhydride is hydrogenated catalytically to produce an alkylsuccinic anhydride and the alkylsuccinic anhydride is treated with the above-mentioned sulphur compound to give a thiophene, the non-sulphur bound carbon of which, e.g. 3-carbon, is substituted.
摘要翻译：在根据本发明的用于制备噻吩，特别是噻吩的方法中，其非硫结合的碳被取代，该产物通过用硫化合物处理琥珀酸酐或特别是取代的琥珀酸酐来制备。硫化合物优选为含有磷的硫化合物，例如五硫化二磷。根据一个实施方案，根据一个实施方案，所述的硫化合物的处理形成了该方法的最终阶段，其中1-烯烃连接到马来酸酐以得到1-烯基 - 琥珀酸酐，1-烯基琥珀酸酐被氢化为催化剂，以产生烷基琥珀酸酐和烷基琥珀酸酐用上述硫化合物处理，得到噻吩，其非硫结合的碳例如 3-碳，被取代。

97. 发明申请

WO1992010535A1 METHOD OF REGENERATION OF A HYDROCARBON BASED LIQUID THAT CONTAINS TITANIUM AND/OR CHLORINE COMPOUNDS 审中-公开
标题翻译：含有钛和/或氯化合物的基于烃类液体的再生方法
公开(公告)号：WO1992010535A1
公开(公告)日：1992-06-25
申请号：PCT/FI1991000376
申请日：1991-12-05
申请人： NESTE OY , GAROFF, Thomas , GUSTAFSSON, Bill
发明人： NESTE OY
IPC分类号： C08J11/02
CPC分类号： C08J11/02 , C07C7/14858
摘要： The invention is concerned with a method of regeneration of a hydrocarbon based washing liquid that contains titanium and chlorine compounds. The titanium and chlorine compounds in the hydrocarbon based solution is removed so that the hydrocarbon solution is brought into contact with a silica that contains hydroxylic groups after which the silica is regenerated by means of water, for recovery.
摘要翻译：本发明涉及含有钛和氯化合物的烃类洗涤液的再生方法。除去烃基溶液中的钛和氯化合物，使得烃溶液与含有羟基的二氧化硅接触，之后通过水再生二氧化硅用于回收。

98. 发明申请

WO1992010351A1 A METHOD FOR PREPARING A CONDUCTIVE PLASTIC PRODUCT AND A MOULD FOR PERFORMING THE METHOD 审中-公开
标题翻译：制备导电塑料制品的方法和用于实施该方法的模具
公开(公告)号：WO1992010351A1
公开(公告)日：1992-06-25
申请号：PCT/FI1991000385
申请日：1991-12-13
申请人： NESTE OY , KOKKONEN, Timo , KÄRNÄ, Toivo , LAAKSO, Jukka , SAVOLAINEN, Esko
发明人： NESTE OY
IPC分类号： B29C45/00
CPC分类号： C08G61/126 , B29C45/0013 , B29C70/885 , B29K2995/0005 , H01B1/127
摘要： A method for preparing a conductive plastic product, in which method a conductor polymer (1) to be doped or a mixture of such a polymer and a matrix plastic (2) is led in a molten state into a mould (9). A doping agent (3) is added to the molten dopable conductor polymer (1) in the mould (9).
摘要翻译：一种制备导电塑料制品的方法，其中待掺杂的导体聚合物（1）或这种聚合物和基质塑料（2）的混合物以熔融状态引入模具（9）中。将掺杂剂（3）加入到模具（9）中的熔融可掺杂导体聚合物（1）中。

99. 发明申请

WO1992001231A1 AN INDIRECT CURRENT MEASURING CIRCUIT 审中-公开
标题翻译：一种间接电流测量电路
公开(公告)号：WO1992001231A1
公开(公告)日：1992-01-23
申请号：PCT/FI1991000207
申请日：1991-07-01
申请人： NESTE OY , OLLILA, Jaakko
发明人： NESTE OY
IPC分类号： G01R19/00
CPC分类号： G01R19/16542
摘要： The invention relates to an indirect current measuring circuit. The current measuring circuit is comprised of a switch (S1) of the main circuit, a diode (D) and an inductance (L). The measured instantaneous value (u1) of the current of the switch (S1) is proportional to the current (iS) passing through the switch (S1), and when the switch (S1) is conducting, also to the load current (iL). A comparator (COMP1) is fitted to act as an indicator of the current of the diode (D), based on the examination of the polarity of the voltage prevailing over the diode (D), whereby the signal to be obtained from the comparator (COMP1) is (u9 = identically ''1'') when the diode (D) is conducting, whereby a control signal (u8) of the switch (S1) directly indicates the current passing through the switch. The output voltage (u10) of the OR-element (OR1) is during the time (0
摘要翻译：本发明涉及一种间接电流测量电路。电流测量电路包括主电路的开关（S1），二极管（D）和电感（L）。开关（S1）的电流的测量瞬时值（u1）与通过开关（S1）的电流（iS）成比例，并且当开关（S1）导通时，也与负载电流（iL）成比例，。基于对二极管（D）上存在的电压的极性的检查，比较器（COMP1）被配置为用作二极管（D）的电流的指示符，由此从比较器获得的信号（ COMP1）当二极管（D）导通时为（u9 =相同“1”），由此开关（S1）的控制信号（u8）直接指示通过开关的电流。 OR元件（OR1）的输出电压（u10）在时间（0

100. 发明申请

WO1991018032A1 ETHYLENE VINYL SILANE COPOLYMER AND ITS PREPARATION 审中-公开
标题翻译：乙烯乙烯基硅烷共聚物及其制备
公开(公告)号：WO1991018032A1
公开(公告)日：1991-11-28
申请号：PCT/FI1991000099
申请日：1991-04-05
申请人： NESTE OY , BERGSTRÖM, Christer , PUROPAASI, Markku , VESTBERG, Torvald , LEHTINIEMI, Ismo
发明人： NESTE OY
IPC分类号： C08F255/00
CPC分类号： C08F299/00 , C08F290/12
摘要： For improving the mixability of two usually nonmixable polymers and for preventing a complete phase separation during handling, one polymer can be grafted on the other. In this invention is etherrified an ethylene vinyl silane polymer containing methoxy groups with another polymer containing hydroxy groups or with a monomer containing hydroxy groups. For example by blending the copolymer of styrene and hydroxy ethyl methacrylate with the terpolymer of ethyl butyl acrylate and vinyl trimethoxy silane, the copolymer is grafted with the silane terpolymer via etherification of the hydroxy groups and the methoxy groups. Alternatively, styrene and hydroxy ethyl methacrylate can be blended with a silane terpolymer by first etherifying the hydroxy groups of the methacrylate monomer and the methoxy groups of the terpolymer and by then copolymerizing styrene with hydroxy ethyl metacrylate. The resulting product is very homogenous and it can be used as compatibilizer and an adhesion plastic and as a polymer component in rubber bitumens.
摘要翻译：为了改善两种通常不混合的聚合物的混合性，并且为了防止在处理期间的完全相分离，可以将另一种聚合物接枝。在本发明中，将包含甲氧基的乙烯乙烯基硅烷聚合物与含有羟基的另一种聚合物或含有羟基的单体进行醚化。例如通过将苯乙烯和甲基丙烯酸羟乙酯的共聚物与丙烯酸丁酯和乙烯基三甲氧基硅烷的三元共聚物共混，通过羟基和甲氧基的醚化将共聚物与硅烷三元共聚物接枝。或者，苯乙烯和甲基丙烯酸羟乙酯可以与硅烷三元共聚物共混，首先醚化甲基丙烯酸酯单体的羟基和三元共聚物的甲氧基，然后共聚苯乙烯与甲基丙烯酸羟乙酯。所得产品非常均匀，可用作增容剂和粘合塑料以及作为橡胶沥青中的聚合物组分。

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