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1. 发明申请

WO2012065981A1 COMPOUND OR MIXTURE OF PHOTOLUMINESCENT COMPOUNDS 审中-公开
标题翻译：化合物或化合物的混合物
公开(公告)号：WO2012065981A1
公开(公告)日：2012-05-24
申请号：PCT/EP2011/070129
申请日：2011-11-15
申请人： Eni S.p.A. , BIAGINI, Paolo , MELCHIORRE, Fabio , ALESSI, Andrea , FUSCO, Roberto
发明人： BIAGINI, Paolo , MELCHIORRE, Fabio , ALESSI, Andrea , FUSCO, Roberto
IPC分类号： C09K11/06
CPC分类号： C09K11/06 , C09K2211/182
摘要： Compound comprising a metal belonging to the family of lanthanides or mixture of compounds comprising a metal belonging to the family of lanthanides. Both said compound and said mixture of compounds,can be advantageously used in the construction of spectrum converters capable of enhancing the performances of solar devices (i.e. devices for the utilizationof solar energy) such as, for example, photovoltaic cells, photoelectrolytic cells.
摘要翻译：包含属于镧系元素的金属或包含属于镧系元素的金属的化合物的混合物的化合物。所述化合物和所述化合物混合物都可以有利地用于能够增强太阳能装置（即太阳能利用装置）的光谱转换器的构造，例如光伏电池，光电解池。

2. 发明申请

WO2011048458A8 PHOTOLUMINISCENT COMPOSITIONS FOR SPECTRUM CONVERTERS WITH ENHANCED EFFICIENCY 审中-公开
公开(公告)号：WO2011048458A8
公开(公告)日：2011-04-28
申请号：PCT/IB2010/002639
申请日：2010-10-14
申请人： ENI S.P.A. , ALESSI, Andrea , FUSCO, Roberto , PROTO, Antonio, Alfonso , SCHIMPERNA, Giuliana , SCUDO, Petra
发明人： ALESSI, Andrea , FUSCO, Roberto , PROTO, Antonio, Alfonso , SCHIMPERNA, Giuliana , SCUDO, Petra
IPC分类号： C09K11/06 , H01L31/00
摘要： The present invention relates to a photoluminescent composition comprising an acene compound having general formula (I) or (Ia) and a benzothiadiazole compound having general formula (II), and the relative use as photoluminescent composition in a spectrum converter. A spectrum converter comprising the photoluminescent composition defined above, comprising the above compounds having general formula (I) or (Ia) and (II) and a solar device comprising said spectrum converter, are also described.

3. 发明申请

WO2013005177A3 LUMINESCENT SOLAR CONCENTRATOR COMPRISING DISUBSTITUTED BENZOSELENADIAZOLE COMPOUNDS 审中-公开
公开(公告)号：WO2013005177A3
公开(公告)日：2013-01-10
申请号：PCT/IB2012/053432
申请日：2012-07-05
申请人： ENI S.P.A. , SANTARELLI, Samuele , FUSCO, Roberto , PROTO, Antonio , CACCIANOTTI, Luciano
发明人： SANTARELLI, Samuele , FUSCO, Roberto , PROTO, Antonio , CACCIANOTTI, Luciano
IPC分类号： C09B57/00 , H01L31/055
摘要： Luminescent solar concentrator (LSC) comprising at least one disubstituted benzoselenadiazole compound having general formula (I): R 1 , R 2 , R 3 , R 4 and R 5 , equal to or different from each other, represent a hydrogen atom; or they are selected from linear or branched C 1 -C 20 , preferably C 1 -C 10 , alkyl groups, cycloalkyl groups optionally substituted, aryl groups optionally substituted, linear or branched C 1 -C 20 , preferably C 1 -C 10 , alkoxyl groups, optionally substituted; or R 1 and R 2 , can be possibly bound to each other so as to form, together with the carbon atoms to which they are bound, a cycle or a polycyclic system containing from 3 to 14 carbon atoms, preferably from 4 to 6 carbon atoms, saturated, unsaturated, or aromatic, possibly containing one or more heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorous, selenium; or R 3 and R 4 , can be possibly bound to each other so as to form, together with the carbon atoms to which they are bound, a cycle or a polycyclic system containing from 3 to 14 carbon atoms, preferably from 4 to 6 carbon atoms, saturated, unsaturated, or aromatic, possibly containing one or more heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorous, selenium; or R 4 and R 5 , can be possibly bound to each other so as to form, together with the carbon atoms to which they are bound, a cycle or a polycyclic system containing from 3 to 14 carbon atoms, preferably from 4 to 6 carbon atoms, saturated, unsaturated, or aromatic, possibly containing one or more heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorous, selenium.

4. 发明申请

WO2012007834A1 PROCESS FOR THE SYNTHESIS OF BENZOTHIADIAZOLE COMPOUNDS 审中-公开
标题翻译：苯并噻唑化合物合成方法
公开(公告)号：WO2012007834A1
公开(公告)日：2012-01-19
申请号：PCT/IB2011/001650
申请日：2011-07-13
申请人： ENI S.P.A. , SANTARELLI, Samuele , RICCI, Marco , FUSCO, Roberto
发明人： SANTARELLI, Samuele , RICCI, Marco , FUSCO, Roberto
IPC分类号： C07D417/14
CPC分类号： C07D417/14 , C07D285/14
摘要： The invention relates to a significantly improved process for the preparation of benzothiadxazole compounds which can be used in the production of Luminescent Solar Concentrators, (LSC). In particular, the synthesis process of the present invention is oriented towards the preparation of 4, -di-2-thienyl- 2,1,3-benzo-thiadiazole.
摘要翻译：本发明涉及可用于生产发光太阳能集中器（LSC）的苯并噻唑化合物的制备方法。特别地，本发明的合成方法定向为制备4'-二-2-噻吩基-2,1,3-苯并噻二唑。

5. 发明申请

WO2012052947A1 WAVELENGTH CONVERTER 审中-公开
标题翻译：波长转换器
公开(公告)号：WO2012052947A1
公开(公告)日：2012-04-26
申请号：PCT/IB2011/054673
申请日：2011-10-19
申请人： ENI S.P.A. , BELLUSSI, Giuseppe , BONOLDI, Lucia , CARATI, Angela , MONTANARI, Luciano , RIZZO, Caterina , ZANARDI, Stefano , FUSCO, Roberto
发明人： BELLUSSI, Giuseppe , BONOLDI, Lucia , CARATI, Angela , MONTANARI, Luciano , RIZZO, Caterina , ZANARDI, Stefano , FUSCO, Roberto
IPC分类号： C01B33/44 , C01B37/00 , C01B37/02
CPC分类号： C01B37/00 , C01B33/44 , C01B37/02 , C07F7/1836
摘要： The invention relates to a spectrum converter, capable of absorbing at least part of an incident radiation and re-emitting it to a longer wavelength, wherein said converter contains particular hybrid organic-inorganic silicates or metal-silicates. Said converter is particularly useful for transforming light with a higher energy of the solar spectrum into light with a lower energy for use in solar devices: its use coupled with a photovoltaic cell optimizes the portion of solar spectrum which can be used by the cell for conversion to electric current, and also avoids that light with an excessively high energy causes damaging the cell itself.
摘要翻译：本发明涉及能够吸收入射辐射的至少一部分并将其再发射到更长波长的光谱转换器，其中所述转换器包含特定的杂化有机 - 无机硅酸盐或金属硅酸盐。所述转换器特别适用于将具有较高能量的太阳光谱的光转换为具有较低能量的光用于太阳能装置：其与光伏电池耦合的使用优化了可被电池用于转换的部分太阳光谱并且也避免了具有过高能量的光会导致电池本身的损坏。

6. 发明申请

WO2010078933A1 IMIDIZED POLYMERS CONTAINING LUMINESCENT GROUPS AND METHOD FOR OBTAINING THEM 审中-公开
标题翻译：含有发光体的聚合物和用于获得它们的方法
公开(公告)号：WO2010078933A1
公开(公告)日：2010-07-15
申请号：PCT/EP2009/009111
申请日：2009-12-17
申请人： ENI S.p.A. , PROTO, Antonio Alfonso , FUSCO, Roberto , SALVALAGGIO, Mario , OTTIMOFIORE, Giacomo
发明人： PROTO, Antonio Alfonso , FUSCO, Roberto , SALVALAGGIO, Mario , OTTIMOFIORE, Giacomo
IPC分类号： C08F8/48 , C08F8/32 , C08F8/30 , C08F20/12 , C08F22/40 , C09K11/06 , H01L31/04 , H01L31/055 , C08F220/14 , C08F212/08
CPC分类号： C08F8/30 , C08F8/32 , C08F8/48 , C09K11/06 , C09K2211/14 , C09K2211/1416 , C09K2211/145 , C09K2211/1466 , H01L31/02167 , H01L31/02168 , H01L31/055 , Y02E10/52 , C08F20/12 , C08F220/14 , C08F212/08
摘要： The present invention relates to photoactive polymers and copolymers of acrylic monomers comprising cycloimide units functionalised with at least one luminescent chromophore group, preferably photoluminescent. The present invention also relates to spectrum converters comprising the above photoactive polymers and copolymers and solar devices comprising said converters.
摘要翻译：本发明涉及包含与至少一个发光发生基团官能化的环酰亚胺单元的丙烯酸单体的光聚合物和共聚物，优选光致发光。本发明还涉及包含上述光活性聚合物和共聚物的光谱转换器以及包括所述转换器的太阳能装置。

7. 发明申请

WO2011060958A1 CATALYSTS OF THE ZIEGLER-NATTA TYPE FOR THE (CO)POLYMERIZATION OF OLEFINS WITH A HIGH PRODUCTIVITY 审中-公开
标题翻译： ZIEGLER-NATTA类型用于（CO）高生产率烯烃聚合的催化剂
公开(公告)号：WO2011060958A1
公开(公告)日：2011-05-26
申请号：PCT/EP2010/007067
申请日：2010-11-18
申请人： POLIMERI EUROPA S.P.A. , MASI, Francesco , POLESELLO, Mario , FUSCO, Roberto , SOMMAZZI, Anna , PROTO, Antonio Alfonso , MEDA, Laura , CONTI, Giuseppe , MENCONI, Francesco , FRIGERIO, Elena Maria , PENNATI, Alessandro
发明人： MASI, Francesco , POLESELLO, Mario , FUSCO, Roberto , SOMMAZZI, Anna , PROTO, Antonio Alfonso , MEDA, Laura , CONTI, Giuseppe , MENCONI, Francesco
IPC分类号： C08F4/655 , C08F10/00
CPC分类号： C08F10/00 , C08F210/16 , C08F2410/03 , C08F4/6557 , C08F210/14 , C08F2500/12
摘要： Solid catalyst with a high thermal stability for the (co) polymerization of α-olefins, comprising titanium, magnesium, at least one metal selected from hafnium and zirconium, aluminum and chlorine, wherein at least 60% of the titanium is in oxidation state +3, and, when examined by means of XPS spectroscopy, has an absorption band characteristic of a binding energy ranging from 455 to 458 eV. Said catalyst, used in combination with a suitable co-catalyst in (co) polymerization processes of α-olefins at a high temperature, shows an improved productivity, a high incorporation of co-monomers in the copolymerization of ethylene and an increased thermal stability with respect to the systems so far in use.
摘要翻译：包含钛，镁，选自铪和锆，铝和氯的至少一种金属的α-烯烃（共）聚合的高热稳定性的固体催化剂，其中至少60％的钛处于氧化态+ 如图3所示，当通过XPS光谱法检查时，具有范围为455至458eV的结合能的吸收带特征。所述催化剂与α-烯烃在高温下的（共）聚合方法中与合适的助催化剂组合使用显示出提高的生产率，共聚单体在乙烯共聚中的高掺入和增加的热稳定性，尊重到目前为止使用的系统。

8. 发明申请

WO2016120264A1 HYBRID CONCENTRATED PHOTOVOLTAIC DEVICE 审中-公开
标题翻译：混合集中的光电器件
公开(公告)号：WO2016120264A1
公开(公告)日：2016-08-04
申请号：PCT/EP2016/051557
申请日：2016-01-26
申请人： ENI S.P.A.
发明人： FUSCO, Roberto , ANDREANI, Lucio , BOZZOLA, Angelo , COMORETTO, Davide , ROBBIANO, Valentina , LAUS, Michele , SPARNACCI, Katia
IPC分类号： H01L31/055 , H01L31/054
CPC分类号： H01L31/055 , H01L31/0543 , Y02B10/10 , Y02E10/52
摘要： Hybrid concentrated photovoltaic device comprising: (i) at least one luminescent solar concentrator (LSC) having the shape of a polygonal, circular,or elliptical plate, comprising at least one photoluminescent compound having a spectral range of absorption and a spectral range of emission; (ii) at least one micrometric or sub-micrometric dielectric photonic structure, optically coupled to said luminescent solar concentrator (LSC),said micrometric or sub-micrometric dielectric photonic structure being able to induce diffusion and/or diffraction of sunlight,preferably diffraction,within said luminescent solar concentrator (LSC),in a spectral range where there is no absorption of said photoluminescent compound; (iii) at least one photovoltaic cell positioned on the outside of at least one side of said luminescent solar concentrator (LSC). The aforementioned hybrid concentrated photovoltaic device may advantageously be incorporated in buildings and dwellings (for example, in photovoltaic glass doors, in photovoltaic skylights, in photovoltaic windows, both indoor and outdoor). Moreover, said hybrid concentrated photovoltaic device may also be used advantageously as a functional element in urban and transport contexts (for example, in photovoltaic noise barriers, in photovoltaic windbreaks).
摘要翻译：混合集中光伏器件包括：（i）具有多边形，圆形或椭圆形板形状的至少一种发光太阳能聚光器（LSC），包括至少一种具有吸收光谱范围和发射光谱范围的光致发光化合物; （ii）光学耦合到所述发光太阳能聚光器（LSC）的至少一个微米或亚微米级介电光子结构，所述微米或亚微米级介电光子结构能够诱导太阳光的扩散和/或衍射，优选衍射，在所述发光太阳能集中器（LSC）内，在不存在所述光致发光化合物的吸收的光谱范围内; （iii）位于所述发光太阳能集中器（LSC）的至少一侧的外侧的至少一个光伏电池。上述混合集中光伏器件可以有利地结合在建筑物和住宅（例如，在光伏玻璃门，在光伏天窗中，在光伏窗户中，室内和室外）。此外，所述混合集中光伏器件还可以有利地用作城市和传输环境中的功能元件（例如，在光伏防风林中的光伏隔离屏障中）。

9. 发明申请

WO2020035799A1 PHOTOVOLTAIC DEVICES COMPRISING LUMINESCENT SOLAR CONCENTRATORS AND PEROVSKITE-BASED PHOTOVOLTAIC CELLS 审中-公开
公开(公告)号：WO2020035799A1
公开(公告)日：2020-02-20
申请号：PCT/IB2019/056892
申请日：2019-08-14
申请人： ENI S.P.A.
发明人： FUSCO, Roberto , TOZZOLA, Gabriella
IPC分类号： H01L51/44
摘要： Photovoltaic device (or solar device) comprising: at least one luminescent solar concentrator (LSC) having an upper surface, a lower surface and one or more external sides; at least one perovskite-based photovoltaic cell (or solar cell) positioned on the outside of at least one of the external sides of said luminescent solar concentrator (LSC), said perovskite being selected from organometal trihalides. Said photovoltaic device (or solar device) may be used advantageously in various applications necessitating the production of electrical energy by utilising light energy, in particular solar radiation energy such as, for example: building integrated photovoltaic (BIPV) systems, photovoltaic window's, greenhouses, photobioreactors, noise barriers, lighting equipment, design, advertising, automotive industry. Moreover, said photovoltaic device (or solar device) can be used both in stand-alone mode and in modular systems.

10. 发明申请

WO2014102742A1 LUMINESCENT SOLAR CONCENTRATOR 审中-公开
标题翻译：发光太阳能集中器
公开(公告)号：WO2014102742A1
公开(公告)日：2014-07-03
申请号：PCT/IB2013/061367
申请日：2013-12-27
申请人： ENI S.P.A.
发明人： GILA, Liliana , FUSCO, Roberto , LUCCHELLI, Emilio
IPC分类号： H01L31/052
CPC分类号： H01L31/02327 , C09K11/02 , C09K11/025 , C09K11/06 , C09K2211/1011 , C09K2211/1051 , C09K2211/1416 , C09K2211/1483 , H01L31/055 , Y02E10/52
摘要： Luminescent solar concentrator (LSC) comprising an aqueous microemulsion including at least one photoluminescent compound. Said luminescent solar concentrator (LSC) can be advantageously used in solar devices (i.e. devices for exploiting solar energy) such as, for example, photovoltaic cells (or solar cells), photoelectrolytic cells. Said luminescent solar concentrator (LSC) can also be advantageously used in photovoltaic windows.
摘要翻译：发光太阳能集中器（LSC）包括含有至少一种光致发光化合物的水性微乳液。所述发光太阳能集中器（LSC）可以有利地用于太阳能装置（即，用于开发太阳能的装置），例如光伏电池（或太阳能电池），光电解池。所述发光太阳能聚光器（LSC）也可有利地用于光伏窗。

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