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1. 发明申请

WO2003000755A3 OLEFIN POLYMERISATION CATALYST AND METHODS FOR PREPARING THE SAME 审中-公开
公开(公告)号：WO2003000755A3
公开(公告)日：2003-01-03
申请号：PCT/EP2002/006716
申请日：2002-06-18
申请人： BOREALIS POLYMERS OY , DENIFL, Peter , LEINONEN, Timo , VAN PRAET, Erik , GAROFF, Thomas , PESONEN, Kari
发明人： DENIFL, Peter , LEINONEN, Timo , VAN PRAET, Erik , GAROFF, Thomas , PESONEN, Kari
IPC分类号： C08F4/654
摘要： The present invention relates to an olefin polymerisation catalyst comprising a catalyst component in the form of particles having a predetermined size range and a low surface area, but high activity, said catalyst being suitable for use in olefin polymerisation, to the process for preparing the catalysts as such and to their use in polymerisation olefins. Is claimed a Ziegler-Natta catalyst for olefin polymerisation in the form of solidified particles according to claim 1 wherein said distribution of active sites is being effected during the solidification step to form said particles.

2. 发明申请

WO2003000755A2 OLEFIN POLYMERISATION CATALYST AND METHODS FOR PREPARING THE SAME 审中-公开
标题翻译：烯烃聚合催化剂及其制备方法
公开(公告)号：WO2003000755A2
公开(公告)日：2003-01-03
申请号：PCT/EP2002/006716
申请日：2002-06-18
申请人： BOREALIS POLYMERS OY , DENIFL, Peter , LEINONEN, Timo , VAN PRAET, Erik , GAROFF, Thomas , PESONEN, Kari
发明人： DENIFL, Peter , LEINONEN, Timo , VAN PRAET, Erik , GAROFF, Thomas , PESONEN, Kari
IPC分类号： C08F10/06
CPC分类号： C08F110/06 , C08F4/6546 , C08F4/651 , C08F2500/12 , C08F2500/18 , C08F2500/24
摘要： The present invention relates to an olefin polymerisation catalyst comprising a catalyst component in the form of particles having a predetermined size range and a low surface area, but high activity, said catalyst being suitable for use in olefin polymerisation, to the process for preparing the catalysts as such and to their use in polymerisation olefins.
摘要翻译：烯烃聚合催化剂本发明涉及一种烯烃聚合催化剂，其包含具有预定尺寸范围和低表面积，但具有高活性的所述催化剂适合用于烯烃聚合的颗粒形式的催化剂组分，用于制备催化剂的方法因此它们在聚合烯烃中的用途。

3. 发明申请

WO2003051934A3 PRODUCTION OF OLEFIN POLYMERISATION CATALYSTS 审中-公开
公开(公告)号：WO2003051934A3
公开(公告)日：2003-06-26
申请号：PCT/EP2002/014461
申请日：2002-12-18
申请人： BOREALIS TECHNOLOGY OY , DENIFL, Peter , VAN PRAET, Erik , BARTKE, Michael , OKSMAN, Marita , MUSTONEN, Marja , GAROFF, Thomas , PESONEN, Kari
发明人： DENIFL, Peter , VAN PRAET, Erik , BARTKE, Michael , OKSMAN, Marita , MUSTONEN, Marja , GAROFF, Thomas , PESONEN, Kari
IPC分类号： C08F10/00
摘要： The invention provides a process for producing an olefin polymerisation catalyst, comprising an organometallic compound of a transition metal or of an actinide or lanthanide, in the form of solid catalyst particles, comprising forming a liquid/liquid emulsion system which comprises a solution of one or more catalyst components dispersed in a solvent immiscible therewith; and solidifying said dispersed phase to convert said droplets to solid particles comprising the catalyst and optionally recovering said particles.

4. 发明申请

WO2003106508A1 METHOD FOR THE PREPARATION OF OLEFIN POLYMERISATION CATALYSTS 审中-公开
标题翻译：烯烃聚合催化剂的制备方法
公开(公告)号：WO2003106508A1
公开(公告)日：2003-12-24
申请号：PCT/EP2003/006524
申请日：2003-06-18
申请人： BOREALIS POLYMERS OY , GAROFF, Thomas , PESONEN, Kari , WALDVOGEL, Päivi , LAINE, Timo , DENIFL, Peter
发明人： GAROFF, Thomas , PESONEN, Kari , WALDVOGEL, Päivi , LAINE, Timo , DENIFL, Peter
IPC分类号： C08F4/655
CPC分类号： C08F10/00 , C08F4/651 , C08F4/6546 , C08F4/6555
摘要： The present invention relates to a process for the production of catalysts, particularly of Ziegler-Natta type of catalysts for olefin polymerisation, to the catalysts as such, and to their use in polymerising olefins.
摘要翻译：本发明涉及一种用于生产催化剂，特别是用于烯烃聚合的齐格勒 - 纳塔型催化剂催化剂的方法，以及它们在烯烃聚合中的用途。

5. 发明申请

WO2003106510A1 METHOD FOR THE PREPARATION OF OLEFIN POLYMERISATION CATALYSTS 审中-公开
标题翻译：制备烯烃聚合催化剂的方法
公开(公告)号：WO2003106510A1
公开(公告)日：2003-12-24
申请号：PCT/EP2002/014462
申请日：2002-12-18
申请人： BOREALIS POLYMERS OY , GAROFF, Thomas , PERSONEN, Kari , WALDVOGEL, Päivi , LAINE, Timo, V. , DENIFL, Peter , LINDROOS, Jarmo
发明人： GAROFF, Thomas , PERSONEN, Kari , WALDVOGEL, Päivi , LAINE, Timo, V. , DENIFL, Peter , LINDROOS, Jarmo
IPC分类号： C08F10/00
CPC分类号： C08F10/00 , C08F4/651 , C08F4/6546 , C08F4/6555
摘要： The present invention relates to a process for the production of catalysts, particularly of Ziegler-Natta type of catalysts for olefin polymerisation, to the catalysts as such, and to their use in polymerising olefins.
摘要翻译：本发明涉及生产催化剂，特别是用于烯烃聚合的齐格勒 - 纳塔型催化剂的催化剂的制备方法，催化剂本身以及它们在聚合烯烃中的用途。 >

6. 发明申请

WO2004055069A1 METHOD FOR THE PREPARATION OF OLEFIN POLYMERISATION CATALYST SUPPORT AND AN OLEFIN POLYMERISATION CATALYST 审中-公开
标题翻译：烯烃聚合催化剂支持和烯烃聚合催化剂的制备方法
公开(公告)号：WO2004055069A1
公开(公告)日：2004-07-01
申请号：PCT/FI2003/000687
申请日：2003-09-19
申请人： BOREALIS TECHNOLOGY OY , GAROFF, Thomas , WALDVOGEL, Päivi , PESONEN, Kari
发明人： GAROFF, Thomas , WALDVOGEL, Päivi , PESONEN, Kari
IPC分类号： C08F110/02
CPC分类号： C08F10/00 , B01J31/0212 , B01J2231/122 , B01J2531/22 , C08F110/02 , C08F210/16 , C08F4/6548 , C08F4/6555 , C08F4/6546 , C08F2500/24 , C08F2500/18 , C08F2500/12 , C08F2500/04 , C08F210/14
摘要： The invention is directed to a process for producing a particulate support for an olefin polymerisation catalyst wherein a solution of a magnesium compound is contacted with a solution of an element of Group 13 or 14 of the Periodic Table (IUPAC) to obtain a solid reaction product. In the process of the invention the solid reaction product is formed by (i) contacting (a) a solution of a magnesium hydrocarbyloxy compound with (b) a solution of a halogencontaining compound of an element of Group 13 or 14 of the Periodic Table (IUPAC) at an elevated temperature; and (ii) recovering the solidified reaction product from the reaction mixture.
摘要翻译：本发明涉及一种用于生产烯烃聚合催化剂的颗粒载体的方法，其中将镁化合物的溶液与元素周期表（IUPAC）的第13或14族元素的溶液接触以获得固体反应产物。在本发明的方法中，固体反应产物通过以下步骤形成：（a）将（a）镁烃氧基化合物的溶液与（b）元素周期表第13或14族元素的含卤素化合物 IUPAC）; 和（ii）从反应混合物中回收固化的反应产物。

7. 发明申请

WO2004055068A1 METHOD FOR THE PREPARATION OF OLEFIN POLYMERISATION CATALYST SUPPORT AND AN OLEFIN POLYMERISATION CATALYST 审中-公开
标题翻译：烯烃聚合催化剂支持和烯烃聚合催化剂的制备方法
公开(公告)号：WO2004055068A1
公开(公告)日：2004-07-01
申请号：PCT/EP2002/014463
申请日：2002-12-18
申请人： BOREALIS TECHNOLOGY OY , GAROFF, Thomas , WALDVOGEL, Päivi , PESONEN, Kari
发明人： GAROFF, Thomas , WALDVOGEL, Päivi , PESONEN, Kari
IPC分类号： C08F110/02
CPC分类号： C08F10/00 , B01J31/0212 , B01J2231/122 , B01J2531/22 , C08F110/02 , C08F210/16 , C08F4/6548 , C08F4/6555 , C08F4/6546 , C08F2500/24 , C08F2500/18 , C08F2500/12 , C08F2500/04 , C08F210/14
摘要： The invention is directed to a process for producing a particulate support for an olefin polymerisation catalyst wherein a solution of a magnesium compound is contacted with a solution of an element of Group (13 or 14) of the Periodic Table (IUPAC) to obtain a solid reaction product. In the process of the invention the solid reaction product is formed by: i) contacting (a) a solution of a magnesium hydrocarbyloxy compound with (b) a solution of a halogen-containing compound of an element of Group (13 or 14) of the Periodic Table (IUPAC); and ii) recovering the solidified reaction product from the reaction mixture.
摘要翻译：本发明涉及一种用于生产烯烃聚合催化剂的颗粒载体的方法，其中将镁化合物的溶液与元素周期表（IUPAC）的第（13或14）族元素的溶液接触以获得固体反应产物。在本发明的方法中，固体反应产物通过以下步骤形成：i）使（a）镁烃氧基化合物的溶液与（b）（13）或（14）的元素的含卤化合物的溶液周期表（IUPAC）; 和ii）从反应混合物中回收固化的反应产物。

8. 发明申请

WO2004050722A1 ZIEGLER NATTA CATALYST SYSTEM AND POLYMERISATION PROCESS USING SAID ZN CATALYST SYSTEM FOR PRODUCING ETHYLENE COPOLYMERS HAVING A BROAD MOLECULAR WEIGHT DISTRIBUTION 审中-公开
标题翻译： ZIEGLER NATTA催化剂体系和聚合工艺使用ZNA催化剂系统生产具有宽带分子量分布的乙烯共聚物
公开(公告)号：WO2004050722A1
公开(公告)日：2004-06-17
申请号：PCT/EP2002/013505
申请日：2002-11-29
申请人： BOREALIS TECHNOLOGY OY , CHU, Kyung-Jun , GAROFF, Thomas , WALDVOGEL, Päivi
发明人： CHU, Kyung-Jun , GAROFF, Thomas , WALDVOGEL, Päivi
IPC分类号： C08F10/00
CPC分类号： C08F10/02 , C08F110/02 , C08F4/642 , C08F4/6567 , C08F4/6555 , C08F2/001 , C08F2500/12 , C08F2500/19
摘要： The application relates to a catalyst system for the polymerisation of ethylene with C 3 -C 10 olefins and to a polymerisation process making use of said catalyst system for producing ethylene polymers having a broad molecular weight distribution as well as to the polymers obtained by such process.
摘要翻译：本申请涉及乙烯与C 3 -C 10烯烃聚合的催化剂体系，以及利用所述催化剂体系生产具有宽分子量分布的乙烯聚合物的聚合方法以及通过这种方法得到的聚合物。

9. 发明申请

WO2011149656A2 ETHYLENE POLYMERIZATION CATALYSTS 审中-公开
标题翻译：乙烯聚合催化剂
公开(公告)号：WO2011149656A2
公开(公告)日：2011-12-01
申请号：PCT/US2011/035900
申请日：2011-05-10
申请人： BASF CORPORATION , CHANG, Main , GAROFF, Thomas
发明人： CHANG, Main , GAROFF, Thomas
IPC分类号： C08F4/652 , C08F4/654 , C08F4/655 , C08F4/656 , C08F10/02
CPC分类号： C08F110/02 , C08F2500/12 , C08F4/651 , C08F4/6565
摘要： The present invention relates to solid catalyst components comprising a reaction product of a titanium compound, a magnesium compound, an alcohol, an aluminum alkoxide, a siloxane mixture, and a maleate derivative; and catalyst systems comprising the solid catalyst components and organo aluminum compounds. The present invention also relates to methods of making the solid catalyst components and the catalyst systems, and methods of polymerizing or copolymerizing ethylene using the catalyst systems.
摘要翻译：本发明涉及包含钛化合物，镁化合物，醇，醇铝，硅氧烷混合物和马来酸衍生物的反应产物的固体催化剂组分; 和包含固体催化剂组分和有机铝化合物的催化剂体系。本发明还涉及制备固体催化剂组分和催化剂体系的方法，以及使用催化剂体系聚合或共聚乙烯的方法。

10. 发明申请

WO2010125022A1 LINEAR LOW DENSITY POLYETHYLENE WITH UNIFORM OR REVERSED COMONOMER COMPOSITION DISTRIBUTION 审中-公开
标题翻译：线性低密度聚乙烯具有均匀或反转的人气组合物分布
公开(公告)号：WO2010125022A1
公开(公告)日：2010-11-04
申请号：PCT/EP2010/055519
申请日：2010-04-26
申请人： BOREALIS AG , GAROFF, Thomas , WALDVOGEL, Päivi , KALLIO, Kalle , ERIKSSON, Virginie , AITTOLA, Aki , KOKKO, Esa
发明人： GAROFF, Thomas , WALDVOGEL, Päivi , KALLIO, Kalle , ERIKSSON, Virginie , AITTOLA, Aki , KOKKO, Esa
IPC分类号： C08F10/00 , C08F210/02 , C08L23/08
CPC分类号： C08F210/16 , C08L2314/02 , C08F210/08 , C08F2500/12 , C08F2500/18 , C08F2500/08 , C08F2500/10
摘要： Ziegler-Natta catalyzed linear low density polyethylene which satisfies the following conditions: a) a density, according to ISO 1183, of from 900 to 925 kg/m 3 , b) a C 4 -C 10 -comonomer content, determined by Fourier transform infrared spectroscopy, of 1 to 16 wt% c) a weight average molecular weight Mw, determined by gel permeation chromatography, of at least 200 000, d) wherein the linear low density polyethylene comprises, by Crystallisation Analysis Fractionation (CRYSTAF) an amorphous fraction soluble at a temperature below 30°C of at most 10 wt% and a fraction crystallising between 60 to 75°C of at least 35 wt% and e) by temperature rising elution fractionation (TREF) analysis, at least 70 wt% of a crystallising polymer component having an elution temperature range from 60°C to 94°C and less than 10 wt% of a crystallising polymer component having an elution temperature range from 30°C to 60° and, f) by Gel Permeation chromatography using an Fourier transform infrared spectroscopy detector (GPC-FTIR), a substantially constant short chain branching profile across the molecular weight distribution (MWD) or g) by Gel Permeation chromatography coupled with Fourier transform infrared spectroscopy instruments (GPC-FTIR), a revers short chain branching profile across the molecular weight distribution (MWD), the linear low density polyethylene being produced in the presence of a special Ziegler- Natta procatalyst and a halogenated aluminium alkyl cocatalyst of the formula (IV) (C 1 -C 4 - alkyl) m -AI-X 3-m1 , wherein X is chlorine, bromine, iodine or fluorine and m is 1 or 2.
摘要翻译：齐格勒 - 纳塔催化的线性低密度聚乙烯，其满足以下条件：a）根据ISO 1183的密度为900至925kg / m 3，b）通过傅立叶变换红外光谱测定的C 4 -C 10共聚单体含量， c）通过凝胶渗透色谱测定的至少200000重量平均分子量Mw，d）其中线性低密度聚乙烯通过结晶分析分馏（CRYSTAF）包含在温度低于30℃至多10重量％，并且在60至75℃之间结晶至少35重量％的馏分和e）通过升温洗脱分馏（TREF）分析，至少70重量％的结晶聚合物组分具有洗脱温度范围为60℃至94℃且小于10重量％的洗脱温度范围为30℃至60℃的结晶聚合物组分，f）通过使用傅里叶变换红外光谱的凝胶渗透色谱法（GPC-FTIR），通过凝胶渗透色谱与傅立叶变换红外光谱仪（GPC-FTIR）结合，分子量分布（MWD）基本恒定的短链支化谱，或g），反向短链支化谱分子量分布（MWD），线性低密度聚乙烯是在特殊的齐格勒 - 纳塔前催化剂和式（Ⅳ）的卤化烷基铝助催化剂（C1-C4烷基）m-AI-X3- m1，其中X是氯，溴，碘或氟，m是1或2。

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