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1. 发明申请

WO2011028827A3 ORGANIC ELECTRONIC DEVICES AND POLYMERS, INCLUDING PHOTOVOLTAIC CELLS AND DIKETONE-BASED POLYMERS 审中-公开
标题翻译：有机电子器件和聚合物，包括光伏电池和基于二酮的聚合物
公开(公告)号：WO2011028827A3
公开(公告)日：2011-05-26
申请号：PCT/US2010047565
申请日：2010-09-01
申请人： PLEXTRONICS INC , SHEINA ELENA E , BROWN CHRISTOPHER T , GRENIER CHRISTOPHE RENE GASTON , LANDIS CHAD
发明人： SHEINA ELENA E , BROWN CHRISTOPHER T , GRENIER CHRISTOPHE RENE GASTON , LANDIS CHAD
IPC分类号： C07D333/00 , C07D333/38 , C07D333/78 , C07D487/04 , C08G61/12 , C08L65/00 , C09D165/00 , H01L51/42
CPC分类号： C08L65/00 , C07D487/04 , C07D495/04 , C07D519/00 , C07F7/0816 , C08G61/12 , C08G61/126 , C08G2261/124 , C08G2261/18 , C08G2261/226 , C08G2261/228 , C08G2261/3223 , C08G2261/334 , C08G2261/344 , C08G2261/364 , C08G2261/414 , C09B57/004 , C09B69/008 , C09B69/109 , C09D165/00 , H01L51/0036 , H01L51/0043 , H01L51/0069 , H01L51/0077 , H01L51/4253 , Y02E10/549 , Y10S428/917
摘要： Polymers which can be used in p-type materials for organic electronic devices and photovoltaic cells. Compounds, monomers, dimers, trimers, and polymers comprising formula (I); Good photovoltaic efficiency and lifetime can be achieved. The R group can provide solubility, environmental stability, and fine tuning of spectroscopic and/or electronic properties. Different polymer microstructures can be prepared which encourage multiple band gaps and broad and strong absorptions. The carbonyl can interact with adjacent thiophene rings to provide backbone with rigidity, induce planarity, and reduce and/or eliminate intramolecular chain twisting defects. Polymers comprising benzodithiophene and/or benzothiadiazole structures can show particularly high performance.
摘要翻译：可用于有机电子器件和光伏电池的p型材料的聚合物。包含式（I）的化合物，单体，二聚体，三聚体和聚合物; 可以实现良好的光伏效率和使用寿命。 R基团可以提供溶解性，环境稳定性和光谱和/或电子性质的微调。可以制备不同的聚合物微结构，其鼓励多重带隙和宽而强的吸收。羰基可以与邻近的噻吩环相互作用以提供具有刚性的主链，引起平面性，并减少和/或消除分子内链扭曲缺陷。包含苯并二噻吩和/或苯并噻二唑结构的聚合物可以显示出特别高的性能。

2. 发明申请

WO2010144472A2 PORPHYRIN AND CONDUCTIVE POLYMER COMPOSITIONS FOR USE IN SOLID-STATE ELECTRONIC DEVICES 审中-公开
标题翻译：固体电子器件中使用的吡啶和导电聚合物组合物
公开(公告)号：WO2010144472A2
公开(公告)日：2010-12-16
申请号：PCT/US2010037805
申请日：2010-06-08
申请人： PLEXTRONICS INC , BROWN CHRISTOPHER T , SHEINA ELENA E
发明人： BROWN CHRISTOPHER T , SHEINA ELENA E
IPC分类号： C08L65/00
CPC分类号： C08L83/16 , C08G61/12 , C08G61/123 , C08G61/126 , C08G77/60 , C08G2261/3162 , C08G2261/3243 , C08G2261/3246 , C08G2261/3247 , C08G2261/344 , C08G2261/91 , C09B69/108 , C09B69/109 , C09D11/52 , H01L51/0036 , H01L51/0037 , H01L51/0043 , H01L51/009 , H01L51/4253 , H01L2251/308 , Y02E10/549
摘要： Compositions comprising porphyrinic macrocycles and conjugated polymers for use in organic electronic devices including solar cells are presented. Covalent linkage of a porphyrinic macrocycle to a polymer or incorporation of a pophyrinic macrocycle into a polymer allows tuning of electronic and spectroscopic properties of conjugated polymers and can improve the heat stability of the system relative to a blended comparison. Compositions, devices, and methods are presented.
摘要翻译：提出了包含卟啉大环化合物和用于包括太阳能电池的有机电子器件的共轭聚合物的组合物。卟啉大环与聚合物的共价连接或将卟啉大环加入到聚合物中可以调节共轭聚合物的电子和光谱性质，并可以相对于混合比较提高系统的热稳定性。介绍了组合，设备和方法。

3. 发明申请

WO2006036756A2 HETEROATOMIC REGIOREGULAR POLY(3-SUBSTITUTEDTHIOPHENES) IN PHOTOVOLTAIC CELLS 审中-公开
标题翻译：异位原子取代聚（3-取代噻吩）在光伏细胞中的应用
公开(公告)号：WO2006036756A2
公开(公告)日：2006-04-06
申请号：PCT/US2005034043
申请日：2005-09-26
申请人： PLEXTRONICS INC , HAMMOND TROY D , LAIRD DARIN W , WILLIAMS SHAWN P , HANNAH ANDREW W , SHEINA ELENA E , JIA SHIJUN
发明人： HAMMOND TROY D , LAIRD DARIN W , WILLIAMS SHAWN P , HANNAH ANDREW W , SHEINA ELENA E , JIA SHIJUN
IPC分类号： H01L51/30
CPC分类号： B82Y10/00 , H01L27/302 , H01L51/00 , H01L51/0012 , H01L51/0036 , H01L51/0043 , H01L51/0046 , H01L51/0047 , H01L51/4213 , H01L51/424 , H01L51/4253 , Y02E10/549
摘要： Regioregular polythiophene polymers can be used in photovoltaic applications including copolymers and blends. The polymer can comprise heteroatoms in the side groups. Better efficiencies can be achieved.
摘要翻译：区域规整的聚噻吩聚合物可用于光伏应用，包括共聚物和共混物。该聚合物可以在侧基中包含杂原子。可以实现更好的效率。

4. 发明申请

WO2011028829A3 ORGANIC ELECTRONIC DEVICES AND POLYMERS, INCLUDING PHOTOVOLTAIC CELLS AND DIKETONE-BASED AND DIKETOPYRROLOPYRROLE-BASED POLYMERS 审中-公开
标题翻译：有机电子器件和聚合物，包括光伏电池和基于二酮的和二酮基吡咯并吡咯基聚合物
公开(公告)号：WO2011028829A3
公开(公告)日：2011-05-26
申请号：PCT/US2010047567
申请日：2010-09-01
申请人： PLEXTRONICS INC , BROWN CHRISTOPHER T , LANDIS CHAD , GRENIER CHRISTOPHE RENE GASTON , SHEINA ELENA E , XU TING
发明人： BROWN CHRISTOPHER T , LANDIS CHAD , GRENIER CHRISTOPHE RENE GASTON , SHEINA ELENA E , XU TING
IPC分类号： C08G61/12 , C07D487/04 , C07D519/00 , C08L65/00 , H01L51/00 , H01L51/42
CPC分类号： C08L65/00 , C07D487/04 , C07D495/04 , C07D519/00 , C07F7/0816 , C08G61/12 , C08G61/126 , C08G2261/124 , C08G2261/18 , C08G2261/226 , C08G2261/228 , C08G2261/3223 , C08G2261/334 , C08G2261/344 , C08G2261/364 , C08G2261/414 , C09B57/004 , C09B69/008 , C09B69/109 , C09D165/00 , H01L51/0036 , H01L51/0043 , H01L51/0069 , H01L51/0077 , H01L51/4253 , Y02E10/549 , Y10S428/917
摘要： Polymers which can be used in p-type materials for organic electronic devices and photovoltaic cells. Compounds, monomers, dimers, trimers, and polymers comprising formula (I) and/or formula (VIII); wherein A1 and A2 each independently comprise a fused ring system comprising at least two fused rings directly covalently linked to the pyrrole rings. Good photovoltaic efficiency and lifetime can be achieved. The R group can provide solubility, environmental stability, and fine tuning of spectroscopic and/or electronic properties. Different polymer microstructures can be prepared which encourage multiple band gaps and broad and strong absorptions. The carbonyl can interact with adjacent thiophene rings to provide backbone with rigidity, induce planarity, and reduce and/or eliminate intramolecular chain twisting defects.
摘要翻译：可用于有机电子器件和光伏电池的p型材料的聚合物。包含式（I）和/或式（VIII）的化合物，单体，二聚体，三聚体和聚合物; 其中A 1和A 2各自独立地包含稠环系统，所述稠环系统包含至少两个直接共价连接至吡咯环的稠合环。可以实现良好的光伏效率和使用寿命。 R基团可以提供溶解性，环境稳定性和光谱和/或电子性质的微调。可以制备不同的聚合物微结构，其鼓励多重带隙和宽而强的吸收。羰基可以与邻近的噻吩环相互作用以提供具有刚性的主链，引起平面性，并减少和/或消除分子内链扭曲缺陷。

5. 发明申请

WO2009103030A1 NOVEL COMPOSITIONS AND METHODS INCLUDING ALTERNATING COPOLYMERS COMPRISING DITHIENOPYRROLE UNITS 审中-公开
标题翻译：新型组合物和方法，包括包含双羟基化合物单元的交替共聚物
公开(公告)号：WO2009103030A1
公开(公告)日：2009-08-20
申请号：PCT/US2009/034157
申请日：2009-02-13
申请人： PLEXTRONICS, INC. , SHEINA, Elena, E.
发明人： SHEINA, Elena, E.
IPC分类号： C08G61/12 , H01B1/12 , H01L51/00
CPC分类号： H01L51/0036 , C08G61/123 , C08G61/124 , C08G61/126 , C08G2261/3246 , C08G2261/91 , H01B1/127 , H01L51/0043 , Y02E10/549
摘要： A composition comprising a copolymer comprising DTP units for use in, for example, low band gap materials including uses in organic photovoltaic active layers. The band gap and other properties can be engineered by copolymerization methods including selection of monomer structure and ratio of monomer components. In addition, a dimer adapted for making alternating copolymers further comprising one first monomer moiety comprising at least one DTP moiety compound covalently linked to one second monomer moiety comprising at least one non-DTP moiety or a different DTP moiety. The composition can be copolymerized to form an alternating copolymer that can be further processed to form a polymeric film used in a printed organic electronic device. A series of novel alternating dithieno[3,2-b:2',3'-d]pyrrole (DTP)-based donor repeat unit copolymers were designed that would allow fabrication of materials with tailor made electronic and/or mechanical properties that can be easily manipulated through molecules chemical structure and potentially result in long term stability under ambient conditions that can be advantageous for use in organic electronics (e.g., OPVs, OLEDs, OFETs).
摘要翻译：包含包含DTP单元的共聚物的组合物，其用于例如用于有机光伏有源层的低带隙材料。可以通过包括选择单体结构和单体组分比例的共聚方法来设计带隙和其它性质。此外，适于制备交替共聚物的二聚体还包含一个包含至少一个共价连接到包含至少一个非DTP部分或不同DTP部分的第二单体部分的DTP部分化合物的第一单体部分。该组合物可以共聚以形成可进一步加工以形成印刷有机电子器件中使用的聚合物膜的交替共聚物。设计了一系列新型交替的二噻吩并[3,2-b：2'，3'-d]吡咯（DTP）基供体重复单元共聚物，其可以制备具有量身定制的电子和/或机械性能的材料，通过分子化学结构易于操作，并且潜在地可以在环境条件下长期稳定，这对于用于有机电子学（例如，OPV，OLED，OFET）是有利的。

6. 发明申请

WO2008144758A2 ORGANIC ELECTRODES AND ELECTRONIC DEVICES 审中-公开
标题翻译：有机电极和电子器件
公开(公告)号：WO2008144758A2
公开(公告)日：2008-11-27
申请号：PCT/US2008064424
申请日：2008-05-21
申请人： PLEXTRONICS INC , UNIV PENNSYLVANIA , LAIRD DARIN W , SHEINA ELENA E , BROWN CHRISTOPHER TYLER , WILLIAMS SHAWN P , JACKSON THOMAS N
发明人： LAIRD DARIN W , SHEINA ELENA E , BROWN CHRISTOPHER TYLER , WILLIAMS SHAWN P , JACKSON THOMAS N
IPC分类号： H01L51/10
CPC分类号： H01L51/0036 , H01L51/0541 , H01L51/0545 , H01L51/105
摘要： A device comprising: a transistor comprising: at least one source; at least one drain; at least one channel; at least one gate insulator comprising (i) a first surface defining a first side, and (ii) a second surface defining a second side and opposing the first surface and first side, wherein the source and the drain are disposed on the gate insulator first side; at least one gate disposed on the gate insulator second side; wherein the source, the drain, or both comprise at least one polymer adsorbed to the source, drain, or both to minimize contact resistance between the source and the channel, the drain and the channel, or both. The polymer can comprise conjugated repeat units, can be a polythiopene, and also can be a regioregular polythiopene.
摘要翻译：一种装置，包括：晶体管，包括：至少一个源; 至少一个排水管; 至少一个通道; 至少一个栅极绝缘体包括（i）限定第一侧的第一表面和（ii）限定第二侧并与第一表面和第一侧相对的第二表面，其中源极和漏极首先设置在栅极绝缘体上侧; 设置在所述栅极绝缘体第二侧上的至少一个栅极; 其中源极，漏极或二者包括至少一个吸收到源极，漏极或二者的聚合物，以使源极和沟道，漏极和沟道之间的接触电阻最小化，或者两者。聚合物可以包含共轭重复单元，可以是聚噻吩，并且也可以是区域性聚噻吩。

7. 发明申请

WO2006107740A3 LIVING SYNTHESIS OF CONDUCTING POLYMERS INCLUDING REGIOREGULAR POLYMERS, POLYTHIOPHENES, AND BLOCK COPOLYMERS 审中-公开
公开(公告)号：WO2006107740A3
公开(公告)日：2006-10-12
申请号：PCT/US2006/011840
申请日：2006-03-31
申请人： CARNEGIE MELLON UNIVERSITY , MCCULLOUGH, Richard, D. , IOVU, Mihaela, C. , SHEINA, Elena, E.
发明人： MCCULLOUGH, Richard, D. , IOVU, Mihaela, C. , SHEINA, Elena, E.
IPC分类号： C08G18/64
摘要： Regioregular poly(3-alkylthiophenes) and other polythiophenes can be prepared by living polymerization which have good solubility, processability and environmental stability. The polymerization method can afford regioregular poly(3-alkylthiophenes) in high yields. Kinetic study of polymerization revealed the living character of this process. The molecular weight of ρoly(3-alkylthiophenes) is a function of the molar ratio of the monomer to nickel initiator, and conducting polymers with relatively narrow molecular weight distribution (PDKl.5) are now readily available. Sequential monomer addition resulted in new block copolymers containing different poly(3-alkylthiophene) segments, which further confirms the "livingness" of this system. Other synthetic methods can be used as well to conduct living polymerization. Blends and electronic devices can be prepared.

8. 发明申请

WO2010144472A3 PORPHYRIN AND CONDUCTIVE POLYMER COMPOSITIONS FOR USE IN SOLID-STATE ELECTRONIC DEVICES 审中-公开
公开(公告)号：WO2010144472A3
公开(公告)日：2010-12-16
申请号：PCT/US2010/037805
申请日：2010-06-08
申请人： PLEXTRONICS, INC. , BROWN, Christopher, T. , SHEINA, Elena, E.
发明人： BROWN, Christopher, T. , SHEINA, Elena, E.
IPC分类号： C08L65/00 , C08G61/12 , C08G73/06 , C09B69/10 , C09D11/00 , H01L51/00
摘要： Compositions comprising porphyrinic macrocycles and conjugated polymers for use in organic electronic devices including solar cells are presented. Covalent linkage of a porphyrinic macrocycle to a polymer or incorporation of a pophyrinic macrocycle into a polymer allows tuning of electronic and spectroscopic properties of conjugated polymers and can improve the heat stability of the system relative to a blended comparison. Compositions, devices, and methods are presented.

9. 发明申请

WO2008144758A3 ORGANIC ELECTRODES AND ELECTRONIC DEVICES 审中-公开
公开(公告)号：WO2008144758A3
公开(公告)日：2008-11-27
申请号：PCT/US2008/064424
申请日：2008-05-21
申请人： PLEXTRONICS, INC. , THE PENNSYLVANIA STATE UNIVERSITY , LAIRD, Darin, W. , SHEINA, Elena, E. , BROWN, Christopher, Tyler , WILLIAMS, Shawn, P. , JACKSON, Thomas, N.
发明人： LAIRD, Darin, W. , SHEINA, Elena, E. , BROWN, Christopher, Tyler , WILLIAMS, Shawn, P. , JACKSON, Thomas, N.
IPC分类号： H01L51/10
摘要： A device comprising: a transistor comprising: at least one source; at least one drain; at least one channel; at least one gate insulator comprising (i) a first surface defining a first side, and (ii) a second surface defining a second side and opposing the first surface and first side, wherein the source and the drain are disposed on the gate insulator first side; at least one gate disposed on the gate insulator second side; wherein the source, the drain, or both comprise at least one polymer adsorbed to the source, drain, or both to minimize contact resistance between the source and the channel, the drain and the channel, or both. The polymer can comprise conjugated repeat units, can be a polythiopene, and also can be a regioregular polythiopene.

10. 发明申请

WO2006107740A2 LIVING SYNTHESIS OF CONDUCTING POLYMERS INCLUDING REGIOREGULAR POLYMERS, POLYTHIOPHENES, AND BLOCK COPOLYMERS 审中-公开
标题翻译：导电聚合物的生物合成，包括后续聚合物，聚乙烯和嵌段共聚物
公开(公告)号：WO2006107740A2
公开(公告)日：2006-10-12
申请号：PCT/US2006011840
申请日：2006-03-31
申请人： UNIV CARNEGIE MELLON , MCCULLOUGH RICHARD D , IOVU MIHAELA C , SHEINA ELENA E
发明人： MCCULLOUGH RICHARD D , IOVU MIHAELA C , SHEINA ELENA E
IPC分类号： H01L29/24
CPC分类号： C08G61/126 , B01J31/2409 , B01J2231/4205 , B01J2531/847 , H01L51/0036 , H01L51/0043
摘要： Regioregular poly(3-alkylthiophenes) and other polythiophenes can be prepared by living polymerization which have good solubility, processability and environmental stability. The polymerization method can afford regioregular poly(3-alkylthiophenes) in high yields. Kinetic study of polymerization revealed the living character of this process. The molecular weight of ?oly(3-alkylthiophenes) is a function of the molar ratio of the monomer to nickel initiator, and conducting polymers with relatively narrow molecular weight distribution (PDKl.5) are now readily available. Sequential monomer addition resulted in new block copolymers containing different poly(3-alkylthiophene) segments, which further confirms the "livingness" of this system. Other synthetic methods can be used as well to conduct living polymerization. Blends and electronic devices can be prepared.
摘要翻译：方位聚（3-烷基噻吩）和其它聚噻吩可以通过具有良好的溶解性，加工性和环境稳定性的活性聚合来制备。聚合方法可以高收率地提供区域性聚（3-烷基噻吩）。聚合的动力学研究揭示了这一过程的生命特征。丙烯酸（3-烷基噻吩）的分子量是单体与镍引发剂的摩尔比的函数，而具有相对较窄分子量分布的导电聚合物（PDK1.5）现在是容易获得的。顺序单体加成产生含有不同聚（3-烷基噻吩）链段的新嵌段共聚物，这进一步证实了该体系的“活性”。也可以使用其它合成方法进行活性聚合。可以制备混合物和电子装置。

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