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1. 发明授权

US08308914B2 Electrolytic ozone cell anode spring board fixture structure 有权
标题翻译：电解臭氧池阳极弹簧板夹具结构
公开(公告)号：US08308914B2
公开(公告)日：2012-11-13
申请号：US12990840
申请日：2009-03-06
申请人： Mingyung Hsu
发明人： Mingyung Hsu
IPC分类号： C01B13/10 , C01B13/11 , C25B9/02 , C25B11/02 , C25B11/03 , C25B11/04 , C25B11/16
CPC分类号： C25B1/13 , C25B9/02 , C25B11/00
摘要： An electrolytic ozone cell anode spring fastening board structure includes a solid polymer electrolyte membrane (1), an anode electrocatalyst layer (2), a diffusion layer (3), frame body and support parts (5). A diffusion layer counterpiece (4) has one side attached to the diffusion layer (3), the other side of the diffusion layer counterpiece (4) equipped with a centered elevated step, which contacts the center of the convex side of a spherical spring board (6). In addition, the solid polymer electrolyte membrane (1), frame body and support parts (5), diffusion layer (3), diffusion layer counterpiece (4) and spring board (6) are held together by mechanical fastening means. It prevents a decrease in ozone generation rate in electrolytic ozone cell that can occur from the metal board deformation and thinning of the anode electrocatalyst layer. This will enable the cell to maintain stable fasten strength and good contact of the metal board and anode catalyst in long term operation, achieving stable electrolytic ozone generation rate and cell performance.
摘要翻译：电解臭氧池阳极弹簧紧固板结构包括固体聚合物电解质膜（1），阳极电催化剂层（2），扩散层（3），框架体和支撑件（5）。扩散层配件（4）的一侧与扩散层（3）相连接，扩散层配件（4）的另一侧装有中心的升高台阶，该中心提升台阶接触球形弹簧板的凸面中心（6）。此外，固体高分子电解质膜（1），框体和支撑部（5），扩散层（3），扩散层配件（4）和弹簧板（6）通过机械紧固装置保持在一起。防止电解臭氧层中的臭氧发生率降低，这可能由于金属板的变形和阳极电极催化剂层的变薄而发生。这将使电池在长期运行中保持稳定的紧固强度和金属板和阳极催化剂的良好接触，达到稳定的电解臭氧产生速率和电池性能。

2. 发明授权

US07871504B2 Method for forming an electrocatalytic surface on an electrode and the electrode 有权
标题翻译：在电极和电极上形成电催化表面的方法
公开(公告)号：US07871504B2
公开(公告)日：2011-01-18
申请号：US12090638
申请日：2006-09-26
申请人： Michael Harold Barker , Olli Hyvärinen , Karri Osara
发明人： Michael Harold Barker , Olli Hyvärinen , Karri Osara
IPC分类号： C25B11/04 , C25B11/06 , C25B11/16
CPC分类号： C25C7/02 , C23C4/02 , C23C4/11 , C23C4/129 , C23C24/04 , C25B11/0452
摘要： The invention relates to a method of forming an electrocatalytic surface on an electrode in a simple way, in particular on a lead anode used in the electrolytic recovery of metals. The catalytic coating is formed by a spraying method which does not essentially alter the characteristics of the coating powder during spraying. Transition metal oxides are used as the coating material. After the spray coating the electrode is ready for use without further treatment. The invention also relates to an electrode onto which an electrocatalytic surface is formed.
摘要翻译：本发明涉及一种在电极上形成电催化表面的方法，特别是用于电解回收金属的铅阳极上。催化涂层通过喷涂方法形成，喷涂方法在喷涂过程中基本上不改变涂层粉末的特性。过渡金属氧化物用作涂层材料。喷涂后，电极准备就绪，无需进一步处理。本发明还涉及其上形成有电催化表面的电极。

3. 发明授权

US06984295B2 Electrolytic cell for ozone generation 失效
标题翻译：用于臭氧发生的电解槽
公开(公告)号：US06984295B2
公开(公告)日：2006-01-10
申请号：US10068277
申请日：2002-02-06
申请人： Lin-Ren Shiue , Chia-Chann Shiue , Hsing-Chen Chung , Fei-Chen Hsieh , Yu-His Hsieh , Jiung-Jau Jou
发明人： Lin-Ren Shiue , Chia-Chann Shiue , Hsing-Chen Chung , Fei-Chen Hsieh , Yu-His Hsieh , Jiung-Jau Jou
IPC分类号： C25B1/13 , C25B11/16 , C25B9/04
CPC分类号： A61L2/0094 , A61L2/202 , C02F1/46104 , C02F1/4672 , C02F1/78 , C02F2001/46138 , C02F2001/46157 , C02F2201/46165 , C02F2201/4617 , C02F2201/4619 , C02F2303/04 , C25B1/13 , C25B15/02 , Y02W10/37
摘要： An electrolytic process of ozone generation using platinum-coated titanium grid as cathode, β-PbO2 deposited on the grid as anode, and batteries in conjunction with supercapacitors as a DC power source is described. No membrane is required to separate the electrodes, and a neutral salt such as NaCl is used to enhance the generation of ozone gas. The electrolytic apparatus comprising a cell, the electrodes, and a bubbler can also be inserted directly in water that needs ozone treatment. As batteries can power the ozone generation, the apparatus can be disposed at point-of-use and away from the city electricity. The electrolytic apparatus can be used for sterilization of water for pharmaceutical industry, household water supply, for surface cleaning of semiconductors, meats, fish, fruits, as well as for disinfection of SPA water and personal hygiene.
摘要翻译：描述了使用铂镀覆钛栅极作为阴极的电解臭氧产生电解方法，沉积在电网作为阳极的β-PbO 2 以及与作为直流电源的超级电容器相结合的电池。不需要膜来分离电极，并且使用中性盐如NaCl来增强臭氧气体的产生。包括电池，电极和起泡器的电解设备也可以直接插入需要臭氧处理的水中。由于电池可以为臭氧发电提供动力，因此可以将设备放在使用点和远离市电的地方。电解设备可用于制药工业，家庭用水，半导体，肉类，鱼类，水果的表面清洗以及SPA水和个人卫生的消毒用水的灭菌。

4. 发明授权

US5518777A Method of producing an electrolytic electode having a plasma flame-coated layer of titanium oxide and tantalum oxide 失效
标题翻译：一种具有氧化钛和氧化钽等离子体火焰涂覆层的电解电极的制造方法
公开(公告)号：US5518777A
公开(公告)日：1996-05-21
申请号：US345461
申请日：1994-11-21
申请人： Takayuki Shimamune , Yasuo Nakajima
发明人： Takayuki Shimamune , Yasuo Nakajima
IPC分类号： C25B11/04 , C25B11/16 , C23C4/10
CPC分类号： C25B11/0484 , C25B11/16
摘要： The instant invention relates to a method for manufacturing an electrolytic electrode comprising a core material made of a valve material, forming a plasma flame-coated layer containing the oxides of titanium and tantalum on the surface of the core material, forming an interlayer containing platinum and the oxides of titanium and tantalum on the surface of the plasma flame-coated layer, forming an .alpha.-lead dioxide layer on the interlayer and forming a .beta.-lead dioxide layer on the .alpha.-lead dioxide layer.
摘要翻译：本发明涉及一种电解电极的制造方法，其包括由阀材料制成的芯材，在芯材表面上形成含有钛和钽的氧化物的等离子体火焰涂层，形成含有铂的中间层和在等离子火焰涂覆层的表面上的钛和钽的氧化物，在中间层上形成α-二氧化碳层，并在α-二氧化碳层上形成β-二氧化碳层。

5. 发明授权

US5431798A Electrolytic electrode and method of production thereof 失效
标题翻译：电解电极及其制造方法
公开(公告)号：US5431798A
公开(公告)日：1995-07-11
申请号：US91044
申请日：1993-07-14
申请人： Takayuki Shimamune , Yasuo Nakajima
发明人： Takayuki Shimamune , Yasuo Nakajima
IPC分类号： C25B11/04 , C25B11/16
CPC分类号： C25B11/0478 , C25B11/16 , Y10S205/917
摘要： The present invention relates to an electrolytic electrode comprising a core material made of a valve metal, a dense electrically conductive tin oxide layer formed on the core material, an .alpha.-lead dioxide layer formed on the tin oxide layer, and a .beta.-lead dioxide layer formed on the .alpha.-lead dioxide layer. The present invention also relates to a method for preparing the electrolytic electrode.
摘要翻译：电解电极技术领域本发明涉及一种电解电极，其包括由阀金属制成的芯材，在芯材上形成的致密导电氧化锡层，形成在氧化锡层上的α-二氧化碳层和β-二氧化碳层形成在α-二氧化碳层上。本发明还涉及一种电解电极的制备方法。

6. 发明授权

US4822459A Lead oxide-coated electrode for use in electrolysis and process for producing the same 失效
标题翻译：用于电解的氧化铅涂层电极及其制造方法
公开(公告)号：US4822459A
公开(公告)日：1989-04-18
申请号：US91148
申请日：1987-08-31
申请人： Minoru Ueda , Akio Watanabe , Takayuki Shimamune
发明人： Minoru Ueda , Akio Watanabe , Takayuki Shimamune
IPC分类号： C25B11/04 , C25B11/10 , C25B11/16 , C25D5/00
CPC分类号： C25B11/0484 , C25B11/16 , Y10T428/3154
摘要： A lead oxide-coated electrode for use in electrolysis is disclosed, which comprises a primary layer comprising platinum and/or platinum oxide, an intermediate layer comprising .alpha.-PbO.sub.2, and a coating layer comprising .beta.-PbO.sub.2 successively coated on a substrate comprising a corrosion resistant metal. The electrode has a strong and durable lead oxide coating firmly bonded to the substrate, does not suffer from passivation, resistance increase, etc. and can be used stably for a long time at high current density. A process for producing the electrode is also disclosed.

7. 发明授权

US4297421A Battery and electrolytic cell electrodes 失效
标题翻译：电池和电解池电极
公开(公告)号：US4297421A
公开(公告)日：1981-10-27
申请号：US850290
申请日：1977-11-10
申请人： Pierre P. Turillon , Michael N. Hull , George F. Nordblom
发明人： Pierre P. Turillon , Michael N. Hull , George F. Nordblom
IPC分类号： C25B11/02 , C25B11/16 , C25C7/02 , H01M4/14 , H01M4/64 , H01M4/68 , H01M4/82 , H01M6/48 , H01M4/56
CPC分类号： H01M4/64 , H01M4/14 , H01M4/68 , H01M6/48
摘要： A composite electrode having a structural electrode member with at least a portion of one surface of the electrode member constructed from a continuous matrix of an anodically passivatable metal infiltrated by a metal capable of forming an electroconductive oxide and having the infiltrating metal at the electrode surface oxidized such that an electric current path is provided through the oxidized surface of the matrix metal. In one embodiment the matrix metal is an electrochemical valve metal, e.g., titanium and the infiltrating metal is lead.Applications for the composite electrode include battery grids and electrochemical processing electrodes.
摘要翻译：一种复合电极，其具有结构电极部件，其电极部件的一个表面的至少一部分由能够形成导电氧化物的金属渗透的阳极可钝化金属的连续基体构成，并且在电极表面处具有渗透金属氧化使得通过基体金属的氧化表面提供电流路径。在一个实施方案中，基质金属是电化学阀金属，例如钛，渗透金属是铅。复合电极的应用包括电池栅极和电化学处理电极。

8. 发明授权

US4231854A Anode for cathodic electrocoating 失效
标题翻译：阴极电涂阳极
公开(公告)号：US4231854A
公开(公告)日：1980-11-04
申请号：US951565
申请日：1978-10-16
申请人： Klaus Boehlke , Fritz E. Kempter
发明人： Klaus Boehlke , Fritz E. Kempter
IPC分类号： C25D13/22 , C04B35/26 , C04B35/54 , C25B11/12 , C25B11/16
CPC分类号： C25D13/22
摘要： Novel anodes consist of a mixture of from 30 to 95% by weight of nagnetite, lead dioxide, magnetite/natural graphite mixture or lead dioxide/natural graphite mixture and from 70 to 5% by weight of a plastic. They may be used for the surface-coating of metallic substrates by cathodic electrocoating.
摘要翻译：新型阳极由30至95重量％的磁铁矿，二氧化铅，磁铁矿/天然石墨混合物或二氧化铅/天然石墨混合物和70至5重量％的塑料的混合物组成。它们可以用于通过阴极电泳涂覆金属基底的表面涂覆。

9. 发明授权

US4222826A Process for oxidizing vanadium and/or uranium 失效
标题翻译：氧化钒和/或铀的工艺
公开(公告)号：US4222826A
公开(公告)日：1980-09-16
申请号：US949885
申请日：1978-10-10
申请人： Olen L. Riggs, Jr. , Dennis A. Brunsell
发明人： Olen L. Riggs, Jr. , Dennis A. Brunsell
IPC分类号： C25B1/00 , C25B11/16 , C25C1/22
CPC分类号： C25B11/16 , C25B1/00
摘要： The present invention provides a process for rapidly and efficiently oxidizing either or both vanadium and uranium from the trivalent and guadrivalent oxidation states, respectively, to the pentavelent and hexavalent oxidation states, respectively, through the use of a special electrode. The electrode is produced by anodically treating a substrate material selected from the group of titanium, zirconium, niobium, hafnium and alloys thereof in an aqueous electrolyte. The electrolyte comprises an aqueous solution of manganous ion in a concentration of from about 15 to 50 gm/l and from about 10 to 40 gm/l sulfuric acid. Manganese dioxide is electrodeposited on the substrate to form the electrode. The manganese dioxide coated electrode then is placed in an oxidation cell as an anode wherein it is potentiostaticly controlled to oxidize either or both vanadium and uranium without significant anode deterioration and without oxygen generation at the anode.
摘要翻译：本发明提供了通过使用特殊电极，分别将三价和三价氧化态的钒和铀分别快速有效地氧化成五价和六价氧化态的方法。电极通过在含水电解质中阳极处理选自钛，锆，铌，铪及其合金中的基材而制造。电解质包含浓度为约15至50gm / l和约10至40gm / l硫酸的二价锰离子水溶液。将二氧化锰电沉积在基底上以形成电极。然后将二氧化锰涂覆的电极放置在氧化池中作为阳极，其中其被静电控制以氧化钒和铀中的一种或两种，而不会显着地阳极劣化并且在阳极处没有产生氧。

10. 发明授权

US4040939A Lead dioxide electrode 失效
标题翻译：二氧化铅电极
公开(公告)号：US4040939A
公开(公告)日：1977-08-09
申请号：US645014
申请日：1975-12-29
申请人： Barry A. Schenker , C. Richard Franks
发明人： Barry A. Schenker , C. Richard Franks
IPC分类号： C25B11/04 , C25B11/10 , C25B11/16 , C25C7/02
CPC分类号： C25B11/0478 , C25B11/16
摘要： Disclosed is an electrode for use in electrochemical processes especially electrowinning processed wherein a valve metal substrate such as titanium carries a semi-conductive intermediate coating consisting of tin and antimony oxides laid down upon the valve metal substrate in a series of layers and a top coating of lead dioxide applied by a plating process.
摘要翻译：公开了一种用于电化学过程，特别是电沉积处理的电极，其中诸如钛的阀金属基底承载由一系列层压在阀金属基底上的锡和锑氧化物组成的半导电中间涂层和顶层涂层通过电镀工艺施加二氧化铅。

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