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    • 5. 发明授权
    • Polymerization process
    • 聚合过程
    • US09328183B2
    • 2016-05-03
    • US14382114
    • 2013-03-07
    • Ineos Europe AG
    • Daniel MarissalPhilip Van BreuseghemBrent R. Walworth
    • C08F6/24C08F2/06C07C7/00C08F210/16C08F2/01C08F6/00
    • C08F6/005C07C7/00C08F2/01C08F2/06C08F6/001C08F10/00C08F210/16Y02P20/582C08L23/06C08F10/02C08F2/001C08F210/14C08F2500/05C08F2500/12
    • Polymerization process including polymerizing a monomer and a comonomer in a polymerization reaction, withdrawing an effluent stream containing solid polymer and a mixture of unreacted monomer and unreacted comonomer, and passing the effluent to a high pressure recovery system having (a) a high pressure separation step for separating vapor containing unreacted monomer and unreacted comonomer from the solids, and (b) a high pressure recycle system for recycling a portion of the vapor to the polymerization reaction, passing the solids from the high pressure recovery system to a low pressure recovery system having (a) a low pressure separation step for separating further unreacted monomer and unreacted comonomer from the solids, and (b) a low pressure recycle system for recycling at least a portion of the unreacted monomer and unreacted comonomer to the polymerization reaction. A portion of the vapor separated in step 2(a) is passed to the low pressure recovery system.
    • 聚合方法包括在聚合反应中聚合单体和共聚单体,取出含有固体聚合物的流出物流和未反应的单体与未反应的共聚单体的混合物,并将流出物送至高压回收系统,该系统具有(a)高压分离步骤 用于从固体中分离含有未反应的单体和未反应的共聚单体的蒸气,和(b)用于将一部分蒸气再循环到聚合反应中的高压循环系统,将固体从高压回收系统传递到具有 (a)用于从固体中分离未反应单体和未反应的共聚单体的低压分离步骤,和(b)将至少一部分未反应单体和未反应的共聚单体再循环至聚合反应的低压循环系统。 在步骤2(a)中分离出的蒸气的一部分被传递到低压回收系统。