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1. 发明授权

US11932724B1 High density polymers based on norbornadiene 有权
公开(公告)号：US11932724B1
公开(公告)日：2024-03-19
申请号：US17220282
申请日：2021-04-01
申请人： The United States of America, as represented by the Secretary of the Navy
发明人： Benjamin G. Harvey , Kyle E. Rosenkoetter
IPC分类号： C08F36/02 , C07C1/20 , C08G61/02
CPC分类号： C08G61/02 , C07C1/20 , C08F36/02 , C08F2500/07 , C08G2261/13 , C08G2261/3325 , C08G2261/592 , C08G2261/76
摘要： A novel family of cycloalkanes compounds having one or more allylidene functionalities which can be used to create cross-linked thermosets and thermoplastics having thermal stability. An example heptacyclo [6.6.0.02,6.03,13.04,11.05,9.010,14] tetradecane (HCTD) complex with terminal allylidene groups at the 7- and 12-positions (HCTD-7,12-diallylidene) was generated from norbornadiene via an efficient six-step synthesis. Thermal polymerization at temperatures ranging from 160 to 240° C. yielded a robust cross-linked material with thermal stability up to 485° C. in air, a glass transition temperature of 377° C., and a char yield (600° C.) of 56% in air. Applications include heat resistant composites utilized in the aerospace, electronic, automotive and textile industries.

2. 发明授权

US09062175B2 Acetylene black semiconducting shield material with improved processing 有权
标题翻译：乙炔黑半导体屏蔽材料具有改进的加工性能
公开(公告)号：US09062175B2
公开(公告)日：2015-06-23
申请号：US13816401
申请日：2011-09-16
申请人： Paul J. Brigandi
发明人： Paul J. Brigandi
IPC分类号： C08F36/02 , C08K3/04 , C09C1/54
CPC分类号： C08K3/04 , C01P2002/72 , C01P2002/77 , C01P2006/10 , C01P2006/19 , C01P2006/40 , C09C1/54
摘要： A semiconducting shield composition comprising a polyolefin and acetylene black having at least one of the following properties: (a) a DBP oil adsorption of 150 ml/100 g to 200 ml/100 g; (b) an iodine absorption of 85 mg/g to 105 mg/g; (c) an apparent density of 0.2 g/ml to 0.4 g/ml; (d) a crystallite size along (002) less than 30 Å; and (e) a carbon-carbon bond length along (100) less than 2.42 Å. The semiconducting shield may be incorporated into a semiconducting layer and/or a semiconductor apparatus.
摘要翻译：一种半导体屏蔽组合物，其包含具有以下特性中的至少一种的聚烯烃和乙炔黑：（a）DBP油吸附量为150ml / 100g至200ml / 100g; （b）碘吸收量为85mg / g至105mg / g; （c）0.2g / ml至0.4g / ml的表观密度; （d）沿（002）小于30的微晶尺寸; 和（e）（100）小于2.42的碳 - 碳键长度。半导体屏蔽可以结合到半导体层和/或半导体器件中。

3. 发明授权

US08921436B2 Microporous polyolefin-based aerogels 有权
标题翻译：微孔聚烯烃基气凝胶
公开(公告)号：US08921436B2
公开(公告)日：2014-12-30
申请号：US13896156
申请日：2013-05-16
申请人： Aspen Aerogels, Inc.
发明人： Je Kyun Lee , George L Gould
IPC分类号： C08J9/28 , C08J9/00 , C08F36/00 , C08F36/02 , C08F36/20 , C08G61/08 , C08F34/00
CPC分类号： C08F34/00 , C08G61/08 , C08G2261/3325 , C08G2261/418 , C08J9/28 , C08J2201/0502 , C08J2203/08 , C08J2205/026
摘要： Microporous polyolefin and microporous polydicyclopentadiene (polyDCPD) based aerogels and methods for preparing and using the same are provided. The aerogels are produced by forming a polymer gel structure within a solvent from a olefin or dicyclopentadiene monomer 5 via Ring Opening Metathesis Polymerization (ROMP) reactions, followed by supercritical drying to remove the solvent from the aerogel. Other aerogels are prepared by sequentially (1) mixing at least one dicyclopentadiene monomer, at least one solvent at least one catalyst and at least one inorganic and/or organic reinforcing material, (2) gelling the mixture, (3) aging, and (4) supercritical drying. Aerogels provided herein are inexpensive to prepare, possess desirable 10 thermal, mechanical, acoustic, chemical, and physical properties and are hydrophobic. The aerogels provided herein are suitable for use in various applications, including but not limited to thermal and acoustic insulation, radiation shielding, and vibrational damping applications.
摘要翻译：提供微孔聚烯烃和微孔聚二环戊二烯（polyDCPD）为基础的气凝胶及其制备和使用方法。气凝胶是通过经由开环复分解聚合（ROMP）反应从烯烃或二环戊二烯单体5在溶剂中形成聚合物凝胶结构，然后通过超临界干燥从气凝胶中除去溶剂而制备的。其它气凝胶通过顺序地（1）混合至少一种二环戊二烯单体，至少一种溶剂至少一种催化剂和至少一种无机和/或有机增强材料，（2）胶凝该混合物，（3）老化和（ 4）超临界干燥。本文提供的气凝胶制备成本低廉，具有期望的10种热，机械，声学，化学和物理性质并且是疏水性的。本文提供的气凝胶适用于各种应用，包括但不限于热和隔音，辐射屏蔽和振动阻尼应用。

4. 发明申请

US20130052149A1 PROCESS FOR TREATING AND/OR FORMING A NON-NEWTONIAN FLUID USING MICROCHANNEL PROCESS TECHNOLOGY 失效
标题翻译：使用微通道工艺技术处理和/或形成非牛顿流体的方法
公开(公告)号：US20130052149A1
公开(公告)日：2013-02-28
申请号：US13644293
申请日：2012-10-04
申请人： Velocys, Inc.
发明人： Anna Lee Tonkovich , Ravi Arora , David Kilanowski , Eric Daymo
IPC分类号： A61K8/96 , C07C231/00 , C07C68/00 , C07C67/00 , A61Q15/00 , A61K45/00 , A01N61/00 , A61Q13/00 , A61P17/00 , A01P17/00 , A61Q17/04 , C08F10/00 , C08F36/02 , C08F20/06 , C08F20/10 , C08F18/08 , C08F12/08 , C08F20/44 , C08F14/26 , C08F110/02 , C08F110/06 , C08F236/10 , C08F236/12 , C07C41/01
CPC分类号： B01J19/0093 , B01F3/0807 , B01F5/0475 , B01F13/0059 , B01F15/065 , B01J2219/00835 , B01J2219/00837 , B01J2219/00844 , B01J2219/0086 , B01J2219/00873 , B01J2219/00889 , B01J2219/00891 , F28D7/0025 , F28D9/0081 , F28F3/086 , F28F2260/02 , Y10T137/0335 , Y10T137/2506
摘要： The disclosed invention relates to a process, comprising: conducting unit operations in at least two process zones in a process microchannel to treat and/or form a non-Newtonian fluid, a different unit operation being conducted in each process zone; and applying an effective amount of shear stress to the non-Newtonian fluid to reduce the viscosity of the non-Newtonian fluid in each process zone, the average shear rate in one process zone differing from the average shear rate in another process zone by a factor of at least about 1.2.
摘要翻译：所公开的发明涉及一种方法，包括：在处理微通道中的至少两个处理区中进行单元操作以处理和/或形成非牛顿流体，在每个处理区中进行不同的单元操作; 并且向非牛顿流体施加有效量的剪切应力以降低每个工艺区域中的非牛顿流体的粘度，一个工艺区域中的平均剪切速率与另一工艺区域中的平均剪切速率不同，至少约1.2。

5. 发明申请

US20120196994A1 NOVEL POST METALLOCENE-TYPE TRANSITION METAL COMPOUNDS 有权
标题翻译：新型金属茂型过渡金属化合物
公开(公告)号：US20120196994A1
公开(公告)日：2012-08-02
申请号：US13386282
申请日：2010-07-23
申请人： Sang-Jin Jeon , Hoon Chae , Cheon-Il Park , Kyung-Seop Noh , Won-Hee Kim
发明人： Sang-Jin Jeon , Hoon Chae , Cheon-Il Park , Kyung-Seop Noh , Won-Hee Kim
IPC分类号： C08F4/646 , C07F7/00 , C08F4/659 , C08F10/00 , C08F36/22 , C08F10/06 , C08F10/08 , C08F10/14 , C08F32/04 , C08F36/02 , C07D215/12 , C08F10/02
CPC分类号： C07D215/12
摘要： The present invention relates to a novel post metallocene-type ligand compound, to a metal compound containing the ligand compound, to a catalytic composition containing the metal compound, and to a method for preparing same, as well as to a method for preparing olefin polymers using the catalytic composition. The present invention provides a catalyst for preparing special polyolefin-based polymers having excellent activity
摘要翻译：本发明涉及一种新颖的后茂金属型配体化合物，含有配体化合物的金属化合物，涉及含有金属化合物的催化组合物及其制备方法，以及制备烯烃聚合物的方法使用催化剂组合物。本发明提供一种制备具有优异活性的特种聚烯烃基聚合物的催化剂

6. 发明申请

US20120164904A1 BONDING COMPOSITIONS 有权
标题翻译：粘结组合物
公开(公告)号：US20120164904A1
公开(公告)日：2012-06-28
申请号：US13412745
申请日：2012-03-06
申请人： Nigel Fay , Darren Nolan , Eimear M. Fleming , Brendan J. Kneafsey , Rainer K. Wefringhaus
发明人： Nigel Fay , Darren Nolan , Eimear M. Fleming , Brendan J. Kneafsey , Rainer K. Wefringhaus
IPC分类号： B32B5/02 , B32B17/06 , C08F36/02 , B32B9/04 , B32B37/12 , C07F7/04
CPC分类号： C08G77/045 , C07F7/1804 , C08K3/22 , C08K3/34 , C08K5/32 , C08K5/33 , C08K5/5419 , C08K5/544 , C09J5/06 , C09J2400/143 , C09J2407/006 , C09J2421/006 , Y10T428/31612 , Y10T428/31663 , Y10T442/3911
摘要： Methods for bonding polymeric substrates to hydroxylated surfaces such as glass are disclosed. The polymeric substrates may be elastomeric substrates such as a natural Or synthetic rubber. The method may comprise applying a compound comprising at least one alkoxy silane moiety and at least one moiety selected from a nitrosoaromatic or a nitrosoaromatic precursor to one of the substrates. The nitrosoaromatic moiety may be a nitrosobenzene. The nitrosoaromatic precursor may be a nitrosobenzene precursor, such as at least one of a quinone dioxime or a quinone oxime. Novel primers and compounds suitable for use in the bonding process are also disclosed.
摘要翻译：公开了将聚合物基体粘合到羟基化表面如玻璃上的方法。聚合物基材可以是弹性体基材，例如天然或合成橡胶。该方法可以包括将至少一种烷氧基硅烷部分和至少一个选自亚硝基芳族化合物或亚硝基芳族前体的部分的化合物施用到其中一个底物。亚硝基芳族部分可以是亚硝基苯。亚硝基芳族前体可以是亚硝基苯前体，例如醌二肟或醌肟中的至少一种。还公开了适用于粘合方法的新型底漆和化合物。

7. 发明申请

US20100249351A1 Synthetic rubber with narrow molecular weight distribution, a process for its preparation and a method of use 有权
公开(公告)号：US20100249351A1
公开(公告)日：2010-09-30
申请号：US12795035
申请日：2010-06-07
申请人： Lothar Reif , Stephen Pask
发明人： Lothar Reif , Stephen Pask
IPC分类号： C08F114/14 , C08G18/00 , C08F118/02 , C08F236/06 , C08F136/06 , C08F36/02 , B29C45/00 , B29C47/00 , B29C67/24
CPC分类号： C08C19/08 , B60C1/00 , C08F8/50
摘要： A novel process is used to prepare synthetic rubbers (B) which feature very narrow molecular weight distribution and a correspondingly low value for the polydispersity index. The preparation process encompasses the treatment of a synthetic rubber with ultrasound, where the resultant synthetic rubber (B) has a lower weight-average molecular weight (Mw) than the synthetic rubber (A) used. The resultant synthetic rubbers (B) have excellent suitability for processing via extruder processes or injection-moulding processes.

8. 发明授权

US07799884B2 Polymeric photoinitiators 有权
公开(公告)号：US07799884B2
公开(公告)日：2010-09-21
申请号：US11606686
申请日：2006-11-30
申请人： Donald E. Herr , Ziyi Hu , Charles W. Paul , Robert W. R. Humphreys
发明人： Donald E. Herr , Ziyi Hu , Charles W. Paul , Robert W. R. Humphreys
IPC分类号： C08F36/02 , G03C1/00
CPC分类号： C08L53/025 , C07F7/0838 , C08C19/25 , C08F2/50 , C08F8/32 , C08F8/34 , C08F8/42 , C08L53/02 , C08L2666/02 , C09J153/02 , C09J153/025 , Y10S430/114 , Y10S522/904 , Y10S522/905
摘要： UV curable compositions, polymeric photoinitiators and precursors therefor are described.

9. 发明授权

US6124513A Ethylene-alpha-olefin polymers, processes and uses 失效
标题翻译：乙烯-α-烯烃聚合物，工艺和用途
公开(公告)号：US6124513A
公开(公告)日：2000-09-26
申请号：US880151
申请日：1997-06-20
申请人： William J. Heilman , I-Ching Chiu , James C. W. Chien
发明人： William J. Heilman , I-Ching Chiu , James C. W. Chien
IPC分类号： C10M107/02 , C08F2/00 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F8/00 , C08F8/04 , C08F8/50 , C08F36/02 , C08F210/02 , C08F210/06 , C08F210/10 , C08F210/14 , C08F210/16 , C08F212/08 , C08F212/32 , C08F236/02 , C10M107/04 , C10M107/06 , C10M107/08 , C10M107/10 , C10M107/12 , C10M107/16 , C10M169/04 , C10M171/04 , C10N20/00 , C10N20/02 , C10N20/04 , C10N40/00 , C10N40/04 , C10N40/26 , C10N70/00 , C07C9/00 , C10L1/16
CPC分类号： C08F210/16 , C08F8/04 , C08F8/48 , C08F8/50 , C10M107/04 , C10M107/06 , C10M107/08 , C10M107/10 , C10M107/12 , C10M171/04 , C08F210/02 , C08F210/06 , C08F2800/10 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C10M2205/00 , C10M2205/02 , C10M2205/0206 , C10M2205/0225 , C10M2205/0245 , C10M2205/0265 , C10M2205/0285 , C10M2205/04 , C10M2205/043 , C10N2220/02 , C10N2230/06
摘要： A novel series of copolymers and terpolymers, usefull as base oils for synthetic lubricants, are produced by polymerization of ethylene, an alpha-olefin, and optionally a third monomer comprising an alpha-olefin of 3 to 20 carbon atoms, in the presence of a combination catalyst comprising a compound of a transition metal of Group IVb of the Periodic Table and an aluminoxane. The copolymer or terpolymer may be further processed by thermal cracking to yield novel cracked polymers, and the cracked polymers may be hydrogenated. The copolymers or terpolymers may also be hydroisomerized. All the polymers are useful as base oils for lubricating oils and consumer products.
摘要翻译：一种新型的共聚物和三元共聚物系列，用作合成润滑剂的基础油，是通过乙烯，α-烯烃和任选的包含3至20个碳原子的α-烯烃的第三单体在存在下制备的，组合催化剂包含周期表第IVb族过渡金属的化合物和铝氧烷。可以通过热裂解进一步处理共聚物或三元共聚物以产生新的裂化聚合物，并且裂化的聚合物可以被氢化。共聚物或三元共聚物也可以是加氢异构化的。所有聚合物都可用作润滑油和消费品的基础油。

10. 发明授权

US5753777A Telechelics containing ethanolamine or oligoether-ol-amine end groups and process for the preparation thereof 失效
标题翻译：含有乙醇胺或低聚醚 - 醇 - 胺端基的电视电影及其制备方法
公开(公告)号：US5753777A
公开(公告)日：1998-05-19
申请号：US553664
申请日：1995-11-17
申请人： Klaus Bronstert , Konrad Knoll
发明人： Klaus Bronstert , Konrad Knoll
IPC分类号： C08F8/30 , C08C19/44 , C08F4/48 , C08F36/00 , C08F36/02 , C08F36/04 , C08G18/69 , C08F136/06 , C08F8/32 , C08F136/08
CPC分类号： C08G18/696 , C08C19/44 , C08F36/04
摘要： A polydiene which is obtainable by anionic polymerization of a diene using a bifunctional Li initiator followed by polymer-like reaction and which contains at least one ethanolamine or oligoetherolamine terminal group of the general structure I ##STR1## in which R.sup.1 denotes alkyl or aryl, Ar denotes aryl, R.sup.2 denotes alkyl or hydrogen, and R.sup.3 denotes aryl, alkyl, or hydrogen and X can assume a value from 1 to 10, and the hydrogenation products thereof.
摘要翻译： PCT No.PCT / EP94 / 01802 Sec。 371日期：1995年11月17日 102（e）1995年11月17日日期PCT PCT 1994年6月3日PCT公布。第WO94 / 29354号公报日期：1994年12月22日A聚二烯，其可以通过使用双官能的Li引发剂进行二聚体的阴离子聚合，然后进行聚合物样反应并含有至少一种通式II的乙醇胺或低聚乙酰胺末端基，Ar表示芳基，R2表示烷基或氢，R3表示芳基，烷基或氢，X可以为1至10的值，并且其氢化产物。

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