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1. 发明授权

US11059912B2 Polymer production method 有权
公开(公告)号：US11059912B2
公开(公告)日：2021-07-13
申请号：US16075283
申请日：2017-02-03
申请人： Nissan Chemical Corporation
发明人： Shinsuke Tadokoro , Masami Kozawa
IPC分类号： C08F2/01 , C08F4/48 , C08F12/08 , B01F5/00 , C08F297/02 , C08F12/04 , B01F5/06 , B01F15/02 , C08K5/56 , B01J19/00
摘要： A polymer production method whereby: a flow reactor comprising a flow path wherein a plurality of liquids can be mixed is used; and a monomer is anionically polymerized in the presence of an initiator. The flow reactor comprises a mixer for mixing two liquids, said mixer comprising either a joint member having a double pipe therein or a static mixer member.

2. 发明申请

US20190062464A1 POLYMER PRODUCTION METHOD 审中-公开
公开(公告)号：US20190062464A1
公开(公告)日：2019-02-28
申请号：US16075283
申请日：2017-02-03
申请人： Nissan Chemical Corporation
发明人： Shinsuke TADOKORO , Masami KOZAWA
IPC分类号： C08F2/01 , C08F297/02 , C08F12/04 , C08K5/56 , B01F5/06 , B01F5/00 , B01F15/02
摘要： A polymer production method whereby: a flow reactor comprising a flow path wherein a plurality of liquids can be mixed is used; and a monomer is anionically polymerized in the presence of an initiator. The flow reactor comprises a mixer for mixing two liquids, said mixer comprising either a joint member having a double pipe therein or a static mixer member.

3. 发明授权

US08729203B2 Polymer composition 有权
标题翻译：聚合物组成
公开(公告)号：US08729203B2
公开(公告)日：2014-05-20
申请号：US13319059
申请日：2009-05-07
申请人： Timothy Charles Higgs , Richard Alexander Young
发明人： Timothy Charles Higgs , Richard Alexander Young
IPC分类号： C08F12/04 , C08F20/38 , C08F32/02
CPC分类号： C08F220/38 , A61L27/16 , A61L2430/16 , C07C323/12 , C08L33/14
摘要： The present invention provides a monomer for a polymerizable composition, a polymerizable composition containing the monomers, a polymer formed from the polymerizable composition, and ophthalmic lens blanks and ophthalmic lenses formed from the polymer. The monomer is a compound having the formula (I) or (Ia).
摘要翻译：本发明提供了可聚合组合物的单体，含有单体的可聚合组合物，由可聚合组合物形成的聚合物，以及由聚合物形成的眼用透镜毛坯和眼镜片。单体是具有式（I）或（Ia）的化合物。

4. 发明授权

US07371805B2 Hydrogenated copolymer and composition thereof 有权
标题翻译：氢化共聚物及其组成
公开(公告)号：US07371805B2
公开(公告)日：2008-05-13
申请号：US10513926
申请日：2003-06-26
申请人： Masahiro Sasagawa , Toshinori Shiraki , Shigeki Takayama , Shigeru Sasaki , Katsumi Suzuki , Takahiro Hisasue , Kazuo Moritou
发明人： Masahiro Sasagawa , Toshinori Shiraki , Shigeki Takayama , Shigeru Sasaki , Katsumi Suzuki , Takahiro Hisasue , Kazuo Moritou
IPC分类号： C08F12/04 , C08F36/04
CPC分类号： C08F8/04 , C08F297/04
摘要： A hydrogenated copolymer obtained by hydrogenating an unhydrogenated copolymer comprising conjugated diene monomer units and vinyl aromatic monomer units, the hydrogenated copolymer containing at least one hydrogenated copolymer block (B) which is obtained by hydrogenating an unhydrogenated random copolymer block comprised of conjugated diene monomer units and vinyl aromatic monomer units, wherein the hydrogenated copolymer has the following characteristics: the hydrogenated copolymer has a content of the vinyl aromatic monomer units of from more than 40% by weight to less than 95% by weight; at least one peak of loss tangent (tan δ) is observed at −10 to 80° C. in a dynamic viscoelastic spectrum obtained with respect to the hydrogenated copolymer; and substantially no crystallization peak ascribed to the copolymer block (B) is observed at −20 to 80° C. in a differential scanning calorimetry (DSC) chart obtained with respect to the hydrogenated copolymer.
摘要翻译：通过氢化包含共轭二烯单体单元和乙烯基芳族单体单元的未氢化共聚物获得的氢化共聚物，所述氢化共聚物含有至少一个氢化共聚物嵌段（B），其通过氢化由共轭二烯单体单元组成的未氢化无规共聚物嵌段和乙烯基芳族单体单元，其中氢化共聚物具有以下特征：氢化共聚物的乙烯基芳族单体单元的含量大于40重量％至小于95重量％; 在相对于氢化共聚物获得的动态粘弹性光谱中，在-10〜80℃观察到损耗角正切（tanδ）的至少一个峰值。在相对于氢化共聚物获得的差示扫描量热法（DSC）图中，在-20〜80℃观察到基本上不归属于共聚物嵌段（B）的结晶峰。

5. 发明授权

US07371804B2 Monomers and polymers for optical elements 有权
标题翻译：用于光学元件的单体和聚合物
公开(公告)号：US07371804B2
公开(公告)日：2008-05-13
申请号：US10936030
申请日：2004-09-07
申请人： Jagdish Jethmalani , Andreas W. Dreher , Gomaa Abdel-Sadek , Jeffrey Chomyn , Jieming Li , Maher Qaddoura
发明人： Jagdish Jethmalani , Andreas W. Dreher , Gomaa Abdel-Sadek , Jeffrey Chomyn , Jieming Li , Maher Qaddoura
IPC分类号： C08F12/04 , C08F112/08 , C08F28/02
CPC分类号： C08F290/00 , C08F212/34 , C08F212/36 , C08F283/00 , C08F290/06 , C08F290/14 , C08F291/00 , C08G75/045 , C08G75/12 , C08L25/18 , G02B3/0087 , G02C2202/14 , Y10T428/31855 , C08L2666/04
摘要： Compositions comprising a matrix polymer and a mixture of monomers are used for making polymer mixtures containing the matrix polymer and a second polymer formed from the monomer mixture. Preferably, the matrix polymer comprises a polyester, polystyrene, polyacrylate, thiol-cured epoxy polymer, thiol-cured isocyanate polymer, or mixtures thereof. Preferably, the monomer mixture comprises a thiol monomer and at least one second monomer selected from the group consisting of ene monomer and yne monomer. The compositions may be used to fabricate optical elements such as lenses.
摘要翻译：包含基质聚合物和单体混合物的组合物用于制备含有基质聚合物和由单体混合物形成的第二聚合物的聚合物混合物。优选地，基质聚合物包括聚酯，聚苯乙烯，聚丙烯酸酯，硫醇固化的环氧聚合物，硫醇固化的异氰酸酯聚合物或其混合物。优选地，单体混合物包含硫醇单体和至少一种选自由单体和单体组成的组的第二单体。组合物可用于制造诸如透镜的光学元件。

6. 发明授权

US06894129B2 Multinuclear half metallocene catalyst and preparation of styrene polymer using the same 有权
标题翻译：多核半茂金属催化剂和使用苯乙烯聚合物的制备
公开(公告)号：US06894129B2
公开(公告)日：2005-05-17
申请号：US10380022
申请日：2002-07-11
申请人： Min-Hyung Lee , You-Mi Jeong , Jin-Young Ryu
发明人： Min-Hyung Lee , You-Mi Jeong , Jin-Young Ryu
IPC分类号： C08F4/60 , C07F17/00 , C08F4/642 , C08F4/6592 , C08F4/76 , C08F12/00 , C08F12/04 , C08F4/64 , C08F112/08
CPC分类号： C07F17/00 , C08F4/65912 , C08F12/08 , C08F2410/03 , C08F2420/04 , C08F4/6592
摘要： The present invention relates to a catalyst for preparing vinyl aromatic polymer and styrene polymerization using the same, and particularly to a transition metal half metallocene catalyst with a novel structure for preparing syndiotactic styrene polymer having high activity, superior stereoregularity, high melting point and various molecular weight distributions and a process for preparing styrene polymer using the same. The present invention provides a multinuclear half metallocene compound in which two or more of transition metals of groups 3 to 10 on periodic table are connected through bridge ligand simultaneously containing π-ligand cycloalkandienyl group and σ-ligand functional group and its preparation, and a process for preparing styrene polymer using the compound as a catalyst. Polymers with various molecular weight distributions as well as vinyl aromatic polymer having predominant syndiotactic structure can be prepared with high activity using the multinuclear half metallocene catalyst.
摘要翻译：本发明涉及一种用于制备乙烯基芳族聚合物的催化剂和使用该催化剂的苯乙烯聚合反应，特别涉及一种具有新型结构的过渡金属半茂金属催化剂，用于制备具有高活性，优异的立构规整性，高熔点和各种分子的间同立构苯乙烯聚合物重量分布和使用其制备苯乙烯聚合物的方法。本发明提供了一种多核半茂金属化合物，其中周期表上的3至10族的过渡金属中的两种或更多种通过桥联配体连接，同时含有π-配体环二烷基和σ-配体官能团及其制备方法用于制备使用该化合物作为催化剂的苯乙烯聚合物。具有各种分子量分布的聚合物以及具有主要间同立构结构的乙烯基芳族聚合物可以使用多核半茂金属催化剂以高活性制备。

7. 发明授权

US06855782B2 Process for producing stereospecific polymers 有权
标题翻译：制备立体有择聚合物的方法
公开(公告)号：US06855782B2
公开(公告)日：2005-02-15
申请号：US10114185
申请日：2002-04-02
申请人： Edwar S. Shamshoum , Margarito Lopez
发明人： Edwar S. Shamshoum , Margarito Lopez
IPC分类号： C08F4/02 , C08F4/60 , C08F4/6392 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/06 , C08F12/04 , C08F110/06
CPC分类号： C08F10/06 , C08F4/025 , C08F4/65912 , C08F4/65927 , C08F12/04 , C08F110/06 , Y02P20/52 , Y10S526/943 , C08F4/65916 , C08F2500/16
摘要： Supported stereospecific catalysts and processes for the stereotactic propagation of a polymer chain derived from ethylenically unsaturated monomers which contain three or more carbon atoms or which are substituted vinyl compounds, such as styrene and vinyl chloride. One application is the stereospecific propagation of C3-C4 alpha olefins, particularly the polymerization of propylene to produce syndiotactic polypropylene over a supported metallocene catalyst comprising a stereospecific metallocene catalyst component incorporating a metallocene ligand structure having two sterically dissimilar cyclopentadienyl ring structures coordinated with the central transition metal atom. Both of the cyclopentadienyl groups are in a relationship with one another by virtue of bridge or substituent groups, which provide a stereorigid relationship relative to the coordinating transition metal atom to prevent rotation of said ring structures. The metallocene catalyst component and a co-catalyst component, an alumoxane or an alkyl aluminum, are supported on a particulate silica support comprising spheroidal silica particles having an average diameter within the range of 5-40 microns and an average effective pore size within the range of 50-350 angstroms. The particulate silica support contains at least 50 wt. % of the supported catalyst component within the pore volume of the silica support.
摘要翻译：支持的立体定向催化剂和衍生自含有三个或更多个碳原子的乙烯基不饱和单体的聚合物链的立体定向增长的方法，或者是取代的乙烯基化合物如苯乙烯和氯乙烯。一个应用是C3-C4α烯烃的立体特异性扩增，特别是丙烯在负载金属茂催化剂下聚合制备间同立构聚丙烯的方法，该催化剂包含立体特异性茂金属催化剂组分，该组分含有具有两个与中心转移配位的空间不同的环戊二烯基环结构的茂金属配体结构金属原子。两个环戊二烯基通过桥或取代基相互关系，其提供相对于配位过渡金属原子的立体刚性关系以防止所述环结构的旋转。金属茂催化剂组分和助催化剂组分，铝氧烷或烷基铝负载在颗粒状二氧化硅载体上，所述颗粒二氧化硅载体包含平均直径在5-40微米范围内的平均直径范围的球形二氧化硅颗粒，并且平均有效孔径在该范围内 50-350埃。颗粒状二氧化硅载体含有至少50wt。负载的催化剂组分的百分比在二氧化硅载体的孔体积内。

8. 发明授权

US6075104A Syndiotactic vinylidene aromatic polymerization process 失效
标题翻译：间规亚乙烯芳族聚合方法
公开(公告)号：US6075104A
公开(公告)日：2000-06-13
申请号：US125954
申请日：1998-08-26
申请人： Thomas H. Newman , Karen K. Borodychuk
发明人： Thomas H. Newman , Karen K. Borodychuk
IPC分类号： C08F4/642 , C08F4/54 , C08F4/64 , C08F4/649 , C08F12/04 , C08F12/06
CPC分类号： C08F12/08 , C08F4/65912 , Y10S526/943
摘要： A process for polymerizing vinylidene aromatic monomers, such as styrene, to produce polymers having a high degree of syndiotacticity using a catalyst composition comprising a Group 4 metal complex and a hydrocarbylsilane or di(hydrocarbyl)silane catalyst adjuvant is disclosed.
摘要翻译： PCT No.PCT / US97 / 06428 Sec。 371日期：1998年8月26日 102（e）日期1998年8月26日PCT 1997年4月17日PCT公布。公开号WO97 / 42234 日期1997年11月13日公开了使用包含第4族金属络合物和烃基硅烷或二（烃基）硅烷催化剂助剂的催化剂组合物使亚乙烯基芳族单体如苯乙烯聚合以制备具有高程度间同立构规整度的聚合物的方法。

9. 发明授权

US6066706A Process for the preparation of crystalline vinylaromatic polymers with a predominately syndiotactic structure 失效
标题翻译：制备具有主要间同立构结构的结晶乙烯基芳族聚合物的方法
公开(公告)号：US6066706A
公开(公告)日：2000-05-23
申请号：US716882
申请日：1996-09-20
申请人： Roberto Santi , Giuseppe Cometti , Riccardo Po'
发明人： Roberto Santi , Giuseppe Cometti , Riccardo Po'
IPC分类号： C08F4/642 , C08F4/60 , C08F4/646 , C08F4/659 , C08F4/6592 , C08F12/00 , C08F12/04 , C08F12/08 , C08F12/06
CPC分类号： C08F12/04 , C08F10/00 , Y10S526/943
摘要： Process for the preparation of crystalline vinylaromatic polymers with a predominantly syndiotactic structure which comprises polymerizing the vinylaromatic monomers, alone or mixed with at least another copolymerizable ethylenically unsaturated monomer, in the presence of a catalytic system essentially consisting of:a) an adduct between a derivative of titanium having the formula R.sub.1 R.sub.2 R.sub.3 R.sub.4 Ti and a calix-[n]-arene, or an oxa-calix-[n]-arene;b) a co-catalyst selected from an alkylalumoxane and a compound of boron having the formula (II):BX.sub.1 X.sub.2 X.sub.3 or its salt.
摘要翻译：用于制备主要间同立构结构的结晶乙烯基芳族聚合物的方法，该方法包括在催化体系存在下单独或与至少另一种可共聚的烯属不饱和单体混合的乙烯基芳族单体聚合，所述催化体系基本上由以下组成：a）衍生物之间的加合物具有式R1R2R3R4Ti和杯[ - ] - 芳烃或氧杂 - 杯 - [n] - 芳烃的钛; b）选自烷基铝氧烷和具有式（II）的硼化合物的助催化剂：BX1X2X3或其盐。

10. 发明授权

US5948874A Acid catalyzed polymerization 失效
标题翻译：酸催化聚合
公开(公告)号：US5948874A
公开(公告)日：1999-09-07
申请号：US65974
申请日：1998-04-24
申请人： William C. Pike , Duane B. Priddy
发明人： William C. Pike , Duane B. Priddy
IPC分类号： C08F2/00 , C08F4/00 , C08F12/04 , C08F220/06 , C08F2/02 , C08F220/10
CPC分类号： C08F12/04
摘要： The present invention is an improvement in a free radical bulk polymerization process for preparing a high molecular weight polymer from a vinyl aromatic monomer characterized in that the polymerization is conducted in the presence of an acid catalyst having a pKa at 25.degree. C. of less than 2, or salt thereof, wherein the improvement comprises dispersing the acid catalyst, or salt thereof, in a (meth)acrylic acid or ester thereof, prior to contact with the vinyl aromatic monomer. The (meth)acrylic acid or ester allows the acid catalyst to be dispersed within the vinyl aromatic monomer without causing cationic polymerization. The acid catalyst, or salt thereof, catalyzes the free radical polymerization reaction such that high molecular weight polymers are produced in reasonable reaction times.
摘要翻译：本发明是一种用于由乙烯基芳族单体制备高分子量聚合物的自由基本体聚合方法的改进，其特征在于聚合反应在酸性催化剂存在下进行，其中pKa在25℃下小于 2或其盐，其中改进包括在与乙烯基芳族单体接触之前将酸催化剂或其盐分散在（甲基）丙烯酸或其酯中。（甲基）丙烯酸酯可使酸催化剂分散在乙烯基芳族单体中而不引起阳离子聚合。酸催化剂或其盐催化自由基聚合反应，使得在合理的反应时间内产生高分子量聚合物。

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