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1. 发明授权

US06916951B2 Continuous carbonylation process 失效
标题翻译：连续羰基化工艺
公开(公告)号：US06916951B2
公开(公告)日：2005-07-12
申请号：US10434596
申请日：2003-05-09
申请人： Gerald Charles Tustin , Regina Michelle Moncier
发明人： Gerald Charles Tustin , Regina Michelle Moncier
IPC分类号： C07C51/145 , C07B61/00 , C07C51/12 , C07C51/56 , C07C53/08 , C07C53/12 , C07C53/122 , C07C67/36 , C07C69/02 , C07C51/10 , C07C51/54
CPC分类号： C07C51/56 , C07C51/12 , C07C67/36 , C07C53/122 , C07C53/08 , C07C53/12 , C07C69/24 , C07C69/14
摘要： Disclosed is a continuous process wherein carbon monoxide, a carbonylatable reactant, and a halide in the gas phase are contacted with a non-volatile catalyst solution comprising an ionic liquid and a Group VIII metal to produce a carbonylation product in the gas phase. The process is useful for the continuous preparation of acetic acid by the carbonylation of methanol.
摘要翻译：公开了一种连续方法，其中气相中的一氧化碳，可羰基化反应物和卤化物与包含离子液体和第Ⅷ族金属的非挥发性催化剂溶液接触以在气相中产生羰基化产物。该方法可用于通过甲醇羰基化连续制备乙酸。

2. 再颁专利

USRE35615E Process for removing iodide compounds from carboxylic acids and carboxylic acid anhydrides 失效
标题翻译：从羧酸和羧酸酐中除去碘化物的方法
公开(公告)号：USRE35615E
公开(公告)日：1997-09-23
申请号：US492287
申请日：1995-06-19
申请人： Michael David Jones , Derrick John Watson , Bruce Leo Williams
发明人： Michael David Jones , Derrick John Watson , Bruce Leo Williams
IPC分类号： B01J39/04 , C07B63/00 , C07C51/12 , C07C51/47 , C07C51/573 , C07C53/08 , C07C53/12 , C07C53/122 , C07C53/124 , C07C53/126
CPC分类号： C07C51/573 , C07C51/47
摘要： In a process for removing iodide compounds from a liquid composition comprising carboxylic acids having 2 to 6 carbon atoms or anhydrides thereof, by passing the liquid composition through a silver, mercury, palladium and/or rhodium-exchanged strong acid cation exchange resin, prior to contacting with the metal-exchanged resin the composition is contacted with a cation exchanger in the acid form to remove at least a portion of the metal ion contaminants in the liquid composition which have been found to displace the silver, mercury, palladium and/or rhodium from the metal-exchanged resin.
摘要翻译：在通过使液体组合物通过银，汞，钯和/或铑交换的强酸阳离子交换树脂从包含具有2至6个碳原子的羧酸或其酸酐的液体组合物中除去碘化合物的方法中，与金属交换的树脂接触，使组合物与酸形式的阳离子交换剂接触以除去液态组合物中已发现取代银，汞，钯和/或铑的至少一部分金属离子污染物从金属交换树脂。

3. 发明授权

US5466876A Process for the removal of corrosion metal contaminants from liquid compositions 失效
标题翻译：从液体组合物中除去腐蚀性金属污染物的工艺
公开(公告)号：US5466876A
公开(公告)日：1995-11-14
申请号：US206072
申请日：1994-03-04
申请人： Andrew R. McClarron , Stephen J. Smith , Derrick J. Watson , Bruce L. Williams , Euan S. Ross
发明人： Andrew R. McClarron , Stephen J. Smith , Derrick J. Watson , Bruce L. Williams , Euan S. Ross
IPC分类号： B01J38/00 , B01J38/74 , B01J45/00 , C07C51/12 , C07C51/47 , C07C51/487 , C07C51/573 , C07C53/08 , C07C53/12 , B01J31/30
CPC分类号： C07C51/47 , B01J45/00 , C07C51/573
摘要： Corrosion metal contaminants are removed from a liquid composition comprising a carboxylic acid and/or an anhydride thereof, a rhodium carbonylation catalyst, and a carbonylation catalyst co-promoter by using a chelating resin selective for the removal of corrosion metals rather than carbonylation catalyst and co-promoter.
摘要翻译：通过使用选择性去除腐蚀金属而不是羰基化催化剂和钴的螯合树脂，从包含羧酸和/或其酸酐的液体组合物，羰基化铑催化剂和羰基化催化剂助催化剂中除去腐蚀金属污染物启动子。

4. 发明授权

US5364822A Process for the recovery of group VIII noble metals 失效
标题翻译：回收第VIII族贵金属的工艺
公开(公告)号：US5364822A
公开(公告)日：1994-11-15
申请号：US101477
申请日：1993-08-02
申请人： John L. Carey
发明人： John L. Carey
IPC分类号： C22B7/00 , C07C51/48 , C07C51/573 , C22B11/00 , B01J31/40 , B01J38/68 , C07C53/12 , C22B11/04
CPC分类号： C07C51/48 , C07C51/573
摘要： In the process for recovery of Group VIII noble metal carbonylation catalyst from a process stream which also contains tar produced during a carbonylation process for carboxylic acid anhydride production, the process stream is diluted with alkyl halide and then extracted with a water, carboxylic acid, iodide salt alkyl halide solution, the iodide salt being a co-promoter derived from the carbonylation process. The recovered noble metal may be recycled to the carbonylation process with iodide salt co-promoter.
摘要翻译：在从含有羧酸酐生产羰基化过程中产生的焦油的工艺流中回收第VIII族贵金属羰基化催化剂的方法中，用烷基卤稀释工艺流，然后用水，羧酸，碘化物盐烷基卤溶液，碘化物盐是衍生自羰基化方法的助催化剂。回收的贵金属可以用碘化物盐助催化剂再循环到羰基化过程中。

5. 发明授权

US5362365A Purification of acetic anhydride or acetic anhydride and acetic acid using ozone 失效
标题翻译：使用臭氧纯化乙酸酐或乙酸酐和乙酸
公开(公告)号：US5362365A
公开(公告)日：1994-11-08
申请号：US88035
申请日：1993-07-06
申请人： Hiroyuki Niijima , Kazuyuki Akita
发明人： Hiroyuki Niijima , Kazuyuki Akita
IPC分类号： C07C51/487 , C07C51/573 , C07C53/08 , C07C53/12 , B01D3/34 , C07C51/42
CPC分类号： C07C51/487 , C07C51/573 , Y10S203/20
摘要： Acetic acid and/or acetic anhydride containing methyl crotonate, vinyl acetate, or both as impurities, is contacted with ozone in an amount of excess molar to the carbon-carbon double bond in said methyl crotonate and/or vinyl acetate and the impurities produced by ozone-treatment are removed off by distillation. A large quantity of impurities such as aldehydes are produced after treatment by treating acetic acid and/or acetic anhydride containing much amount of unsaturated compounds as impurities with ozone. Distilling the ozone-treated acetic acid and/or acetic anhydride make it possible to remove methyl crotonate and vinyl acetate, which are unsaturated compounds difficult to remove by the conventional separation methods, to give high-quality acetic acid and/or acetic anhydride excellent in the residence time in the potassium permanganate test.
摘要翻译：含有巴豆酸甲酯，乙酸乙烯酯或二者均为杂质的乙酸和/或乙酸酐与所述巴豆酸甲酯和/或乙酸乙烯酯中的碳 - 碳双键过量摩尔的量与臭氧接触，由通过蒸馏除去臭氧处理。通过处理含有大量不饱和化合物的乙酸和/或乙酸酐作为杂质与臭氧处理后，产生大量杂质如醛。蒸馏臭氧处理的乙酸和/或乙酸酐可以除去作为常规分离方法难以除去的不饱和化合物的巴豆酸甲酯和乙酸乙烯酯，得到优质的乙酸和/或乙酸酐在高锰酸钾试验中的停留时间。

6. 发明授权

US5002914A Process for purifying and recovering the contaminated catalyst solution arising in the carbonylation of methanol and/or methyl acetate and/or dimethyl ether 失效
标题翻译：用于纯化和回收在甲醇和/或乙酸甲酯和/或二甲醚的羰基化中产生的污染的催化剂溶液的方法
公开(公告)号：US5002914A
公开(公告)日：1991-03-26
申请号：US491352
申请日：1990-03-09
申请人： Heinz Erpenbach , Winfried Lork , Norbert Weferling , Peter Prinz
发明人： Heinz Erpenbach , Winfried Lork , Norbert Weferling , Peter Prinz
IPC分类号： B01J38/00 , B01J31/40 , C07B61/00 , C07C27/00 , C07C51/12 , C07C51/42 , C07C51/48 , C07C51/56 , C07C51/573 , C07C53/08 , C07C53/12 , C07C67/36 , C07C67/37 , C07C67/48 , C07C69/16
CPC分类号： C07C51/56 , C07C51/12 , C07C51/42 , C07C51/48 , C07C51/573 , C07C67/48 , Y02P20/584
摘要： A process for purifying and recovering the contaminated catalyst solution arising from the carbonylation of methanol, methyl acetate and/or dimethyl ether. The solution contains carbonyl complexes of rhodium, quaternary organophosphorus compounds as organic promoters, undistillable organic impurities, and acetic acid, acetic anhydride and ethylidene diacetate. The carbonyl complex of rhodium together with acetic acid, acetic anhydride and ethylidene diacetate are extracted from the contaminated catalyst solution by using a tri-C.sub.3 - to C.sub.8 -alkylphosphine. The trialkylphosphine phase is separated from the promoter phase and is separated into the volatile constituents acetic acid, acetic anhydride and ethylidene diacetate as well as trialkylphosphine. The rhodium carbonyl complex remaining as the residue and the recovered trialkylphosphine is used for further extraction. The contaminated promoter phase is freed of the organic impurities by extraction with dialkyl ethers, carboxylic acid esters or hydrocarbons and, after the extractant phase has been separated off, is recombined with the recovered acetic acid/acetic anhydride and ethylidene diacetate mixture and with the rhodium carbonyl complex and recycled to the carbonylation reactor. The impurities remaining as the residue from a distillation of the extractant phase which has been separated off are removed from the system.
摘要翻译：一种纯化和回收由甲醇，乙酸甲酯和/或二甲醚羰基化产生的污染的催化剂溶液的方法。该溶液含有铑羰基络合物，季有机磷化合物作为有机促进剂，不可渗透的有机杂质，以及乙酸，乙酸酐和亚乙基二乙酸酯。通过使用三-C 3 -C 8烷基膦，从污染的催化剂溶液中提取铑与乙酸，乙酸酐和亚乙基二乙酸酯的羰基络合物。将三烷基膦相与助催化剂相分离，并分离成挥发性成分乙酸，乙酸酐和亚乙基二乙酸酯以及三烷基膦。剩余的作为残留物的铑羰基络合物和回收的三烷基膦用于进一步萃取。被污染的促进剂相通过用二烷基醚，羧酸酯或烃萃取除去有机杂质，并且在萃取相分离后，与回收的乙酸/乙酸酐和亚乙基二乙酸酯混合物与铑重组羰基络合物并循环到羰基化反应器中。从分离出的萃取相的蒸馏中残留的杂质作为残留物从体系中除去。

7. 发明授权

US4746640A Process for purifying and recovering catalyst solution contaminated during the carbonylation of methyl acetate and/or dimethylether 失效
标题翻译：纯化和回收在乙酸甲酯和/或二甲醚羰基化过程中污染的催化剂溶液的方法
公开(公告)号：US4746640A
公开(公告)日：1988-05-24
申请号：US25962
申请日：1987-03-16
申请人： Heinz Erpenbach , Klaus Gehrmann , Winfried Lork
发明人： Heinz Erpenbach , Klaus Gehrmann , Winfried Lork
IPC分类号： B01J38/00 , B01J31/40 , C07B61/00 , C07C51/00 , C07C51/12 , C07C53/12 , C07C67/00 , C07C67/37 , C07C69/14 , B01J38/68 , C07C51/56 , C07C67/36
CPC分类号： B01J31/0268 , B01J31/0239 , B01J31/20 , B01J31/4046 , C07C51/42 , C07C51/48 , C07C51/573 , C07C67/48 , B01J2231/34 , B01J2531/822 , Y02P20/584
摘要： Catalyst solution contaminated during the carbonylation of methyl acetate and/or dimethylether. To this end, the contaminated catalyst solution is subjected in a first processing stage to extraction with a dialkylether and alkanol, each of which has from 1-4 carbon atoms per alkyl group, and thereby freed from its organic contaminants, from acetic acid, acetic anhydride and ethylidene diacetate, and the ether phase is separated from the purified promoter-containing catalyst solution; next, the ether phase is treated in a second processing stage with iodine and/or methyl iodide; the precipitated promoter containing catalyst complex is separated and dissolved in the purified catalyst solution coming from the first processing stage; the ether phase is separated into its constituents by distilling it; recovered dialkylether and alkanol are used again in the extraction stage; fresh catalyst solution is prepared from the recovered mixture of acetic acid, acetic anhydride and ethylidene diacetate and from the united purified catalyst solution while residual dialkylether and alkanol are distilled off, and the organic contaminants retained in the residue of the ether phase distillation are expelled.
摘要翻译：催化剂溶液在乙酸甲酯和/或二甲醚的羰基化过程中被污染。为此，将污染的催化剂溶液在第一个处理阶段进行，用二烷基醚和链烷醇进行萃取，每个烷基烷基和烷醇每个烷基具有1-4个碳原子，从而从乙酸，乙酸中除去其有机污染物酸酐和亚乙基二乙酸酯，并从纯化的含有助催化剂的催化剂溶液中分离出醚相; 接下来，乙醚相在碘和/或碘甲烷的第二个处理阶段进行处理; 将含有沉淀促进剂的催化剂配合物分离并溶解在来自第一处理阶段的纯化催化剂溶液中; 通过蒸馏将乙醚相分离成其成分; 在提取阶段再次使用回收的二烷基醚和链烷醇; 从回收的乙酸，乙酸酐和亚乙基二乙酸酯的混合物中制备新鲜的催化剂溶液，并从合并的纯化的催化剂溶液中蒸出残余的二烷基醚和链烷醇，并且保留在醚相蒸馏残余物中的有机污染物被排出。

8. 发明授权

US4534912A Preparation of anhydrides 失效
标题翻译：酸酐的制备
公开(公告)号：US4534912A
公开(公告)日：1985-08-13
申请号：US611348
申请日：1984-05-17
申请人： John Cook
发明人： John Cook
IPC分类号： C07C53/12 , B01J31/00 , C07B61/00 , C07C51/00 , C07C51/56 , C07C67/00 , C12Q1/68 , C12Q1/6804 , C12Q1/682
CPC分类号： C12Q1/682 , C07C51/56 , C12Q1/6804
摘要： Acetic anhydride is prepared by reacting, at elevated temperature, methyl acetate or dimethyl ether with carbon monoxide in the presence of an effective amount of a catalyst which comprises: (1) cobalt, (2) a compound containing at least one quaternary nitrogen or phosphorus atom and (3) a source of iodide or bromide wherein the atomic ratio of iodide or bromide to cobalt is from 0.5:1 to 5:1. The compound containing at least one quaternary nitrogen or phosphorus atom can optionally be generated in situ by a quaternization reaction.
摘要翻译：乙酸酐通过在有效量的催化剂存在下，在升高的温度下使乙酸甲酯或二甲醚与一氧化碳反应制备，所述催化剂包括：（1）钴，（2）含有至少一个季氮或磷原子和（3）碘化物或溴化物源，其中碘化物或溴化物与钴的原子比为0.5:1至5:1。含有至少一个季氮或磷原子的化合物可以任选地通过季铵化反应原位产生。

9. 发明授权

US4529560A Process for making acetic anhydride 失效
标题翻译：制备乙酸酐的方法
公开(公告)号：US4529560A
公开(公告)日：1985-07-16
申请号：US515284
申请日：1983-07-19
申请人： Wilhelm Vogt , Erhard Jagers , Hermann Glaser
发明人： Wilhelm Vogt , Erhard Jagers , Hermann Glaser
IPC分类号： C07C53/12 , B01J31/00 , C07B61/00 , C07C51/00 , C07C51/56 , C07C67/00 , C07C51/54
CPC分类号： C07C51/56
摘要： The disclosure relates to a process for making acetic anhydride by reacting methyl acetate and/or dimethylether with carbon monoxide, which may be used in admixture with up to 30 volume % hydrogen, under practically anhydrous conditions at temperatures of 390.degree. to 540.degree. K., under pressures of 1 to 300 bars in the presence of a catalyst system containing nickel or nickel compounds, iodine and/or its compounds as well as a tertiary or quaternary organic nitrogen, phosphorus, arsenic or antimony compound. More particularly a catalyst system is used which contains vanadium or niobium or a compound thereof as an additional constituent.
摘要翻译：本公开涉及通过使乙酸甲酯和/或二甲醚与一氧化碳反应制备乙酸酐的方法，其可以在几乎无水条件下在390°至540°K的温度下与最多30体积％的氢混合使用。在含有镍或镍化合物的催化剂体系，碘和/或其化合物以及叔或季有机氮，磷，砷或锑化合物的存在下，在1至300巴的压力下进行。更具体地，使用含有钒或铌或其化合物作为附加成分的催化剂体系。

10. 发明授权

US4511517A Carbonylation of methyl acetate 失效
标题翻译：乙酸甲酯的羰基化
公开(公告)号：US4511517A
公开(公告)日：1985-04-16
申请号：US398802
申请日：1982-07-16
申请人： Jean Gauthier-Lafaye , Robert Perron , Claude Doussain
发明人： Jean Gauthier-Lafaye , Robert Perron , Claude Doussain
IPC分类号： C07C53/12 , B01J31/00 , C07B61/00 , C07C51/00 , C07C51/56 , C07C67/00
CPC分类号： C07C51/56
摘要： Methyl acetate is carbonylated, advantageously to acetic anhydride, in a homogeneous liquid phase, advantageously in a virtually anhydrous reaction medium, in the presence of (a) a cobalt source, (b) a source of iron in the zero oxidation state, (c) an ionic iodide of the formula A.sup.+ I.sup.- in which A.sup.+ is a nitrogen group quaternary onium cation, or an alkali metal cation, and, (d) if appropriate, a carboxylate of the formula A'.sup.n+ (OCOR).sub.n.sup.-, in which n is 1 or 2 and A'.sup.n+ is defined as was A.sup.+, or is an alkaline earth metal cation, with A'.sup.n+ and A.sup.+ either being the same or different, and R is an alkyl, aralkyl or aryl radical having a maximum of 8 carbon atoms, with the total amount of halogen compounds present in the carbonylation reaction medium (expressed in gram atoms of halogen and designated by X.sub.T) being such that the atomic ratio X.sub.T /(A.sup.+ +n.A'.sup.n+) is less than or equal to 1.
摘要翻译：在（a）钴源的存在下，（b）在零氧化态的铁源（c（c）），乙酸甲酯有利地在均相液相中，有利地在几乎无水的反应介质中羰基化，）式A + I的离子碘化物，其中A +是氮基季鎓阳离子或碱金属阳离子，和（d）如果合适的话，式A'n +（OCOR）n-的羧酸酯，其中n为1或2，A'n +定义为A +，或者是碱金属阳离子，其中A'n +和A +相同或不同，R是具有烷基，芳烷基或芳基的烷基，芳烷基或芳基，最多8个碳原子，而羰基化反应介质中卤素化合物的总量（用卤素的克原子表示，由XT表示）使原子比XT /（A ++ n.A'n +）为小于或等于1。

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