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1. 发明授权

US10006131B1 Electrochemical deblocking solution for electrochemical oligomer synthesis on an electrode array 有权
公开(公告)号：US10006131B1
公开(公告)日：2018-06-26
申请号：US15050377
申请日：2016-02-22
申请人： CustomArray, Inc.
发明人： Karl Maurer , John J. Cooper, Jr.
IPC分类号： C25B3/00 , C07C50/00 , C25B3/04 , C07C309/30 , C07D213/16 , C25B3/02
CPC分类号： C25B3/00 , B01J19/0046 , B01J2219/00653 , C07B41/02 , C07B41/06 , C07C50/00 , C07C309/30 , C07D213/16 , C07H21/02 , C07H21/04 , C25B3/02 , C25B3/04 , C25B3/10 , Y02P20/55
摘要： There is disclosed an electrochemical deblocking solution for use on an electrode microarray. There is further disclosed a method for electrochemical synthesis on an electrode array using the electrochemical deblocking solution. The solution and method are for removing acid-labile protecting groups for synthesis of oligonucleotides, peptides, small molecules, or polymers on a microarray of electrodes while substantially improving isolation of deblocking to active electrodes. The method comprises applying a voltage or a current to at least one electrode of an array of electrodes. The array of electrodes is covered by the electrochemical deblocking solution.

2. 发明申请

US20170196976A1 PHOTODYNAMIC DIAGNOSIS, FORMULATIONS USABLE AS PHOTOSENSITIZERS FOR THIS PURPOSE, METHOD FOR THE PRODUCTION AND USE THEREOF 有权
公开(公告)号：US20170196976A1
公开(公告)日：2017-07-13
申请号：US15469602
申请日：2017-03-27
申请人： Sanochemia Pharmazeutika AG
发明人： Stefan WELZIG , Beate KÄLZ , József GUNGL , Klaus GERDES , Werner FRANTSITS , Christina ABRAHAMSBERG
IPC分类号： A61K41/00 , C07C50/00 , C07C50/36 , A61K31/121 , A61K36/38
CPC分类号： A61K41/00 , A61K9/0009 , A61K9/08 , A61K31/121 , A61K36/38 , A61K41/0057 , A61K47/32 , A61K49/0021 , A61K49/0054 , A61K49/0071 , C07C50/00 , C07C50/36
摘要： In the early detection of cancer, in particular bladder cancer, a photodynamic diagnosis uses, as a photosensitizer, a formulation that contains sodium hypericinate that is bonded to polyvinylpyrrolidone or complexed with polyvinylpyrrolidone.

3. 发明授权

US6043286A Pesticidal compounds 失效
标题翻译：杀虫化合物
公开(公告)号：US6043286A
公开(公告)日：2000-03-28
申请号：US891079
申请日：1997-07-10
申请人： Bhupinder Pall Singh Khambay , Duncan Batty
发明人： Bhupinder Pall Singh Khambay , Duncan Batty
IPC分类号： A01N35/06 , A01N35/10 , A01N37/02 , A01N37/10 , C07C46/00 , C07C50/32 , C07C69/013 , C07C251/46 , A01N33/02 , C07C50/00 , C07C50/12
CPC分类号： C07C251/46 , A01N35/06 , A01N35/10 , A01N37/02 , A01N37/10 , C07C46/00 , C07C50/32 , C07C69/013 , C07C2101/14 , C07C2101/18
摘要： Pesticidal as a pesticide against whitefly, Lepidoptera and certain fungi is provided of compound of general formula (I) ##STR1## or a salt thereof is provided, in which n represents an integer from 0 to 4; m represents an integer 0 or 1;each R independently represents a halogen atom or a nitro, cyano, hydroxyl, alkyl, alkenyl, haloalkyl, haloalkenyl, alkoxy, haloalkoxy, haloalkenoxy, amino, alkylamino, dialkylamino, alkoxycarbonyl, carboxyl, alkanoyl, alkylthio, alkylsulphinyl, alkylsulphonyl, carbamoyl, alkylamido, cycloalkyl, aryl or aralkyl group;R.sup.1 and R.sup.2 each independently represent an optionally substituted alkoxy group or together represent a group .dbd.O, .dbd.S or .dbd.N--OR.sup.9, where R.sup.9 represents a hydrogen atom or an optionally substituted alkyl group;R.sup.3 represents a hydroxyl group, or a group --OL where L is a leaving group, or a group which in vivo is transformed into a group --OL.sup.1 where L.sup.1 is a leaving group;R.sup.7 and R.sup.8 independently represent an optionally substituted alkoxy group or together represent a group .dbd.O, .dbd.S or .dbd.N--OR.sup.9, where R.sup.9 is as previously defined;wherein R.sub.4 and R.sub.5 independently represent a halogen atom or an optionally substituted alkyl or alkenyl group, or together with the interjacent carbon atom represent an optionally substituted cycloalkyl or cycloalkenyl ring; andA represents a straight or branched chain alkyl or alkenyl group, which may be optionally substituted, an acyclic carbon chain of which links the 3 position of the naphthalene ring shown and the moiety --CHR.sup.4 R.sup.5 and wherein A does not include a quaternary carbon atom in that chain; andwherein the total number of carbon atoms in the longest carbon chain running from the 3-position of the naphthalene ring shown is no more than 8.
摘要翻译：提供了杀虫剂作为粉虱，鳞翅目和某些真菌的杀虫剂，提供通式（I）的化合物或其盐，其中n表示0至4的整数; m表示整数0或1; 每个R独立地表示卤素原子或硝基，氰基，羟基，烷基，烯基，卤代烷基，卤代烯基，烷氧基，卤代烷氧基，卤代烯氧基，氨基，烷基氨基，二烷基氨基，烷氧基羰基，羧基，烷酰基，烷硫基，烷基亚磺酰基，烷基磺酰基，氨基甲酰基，，环烷基，芳基或芳烷基; R 1和R 2各自独立地表示任选取代的烷氧基或一起表示基团= O，= S或= N-OR 9，其中R 9表示氢原子或任选取代的烷基; R3表示羟基或其中L为离去基团的基团-OL，或将体内转化为基团-OL1的基团，其中L1为离去基团; R 7和R 8独立地表示任选取代的烷氧基或一起表示基团= O，= S或= N-OR 9，其中R 9如前所定义; 其中R 4和R 5独立地表示卤原子或任选取代的烷基或烯基，或与中间碳原子一起表示任选取代的环烷基或环烯基环; 并且A表示直链或支链烷基或烯基，其可以是任选取代的，其连接所示萘环的3位和部分-CHR 4 R 5的无环碳链，其中A不包括季碳原子那条链并且其中从所示的萘环的3位运行的最长碳链中的碳原子总数不大于8。

4. 发明授权

US5998330A UV stable microbial insecticides, methods of making, methods of using 失效
标题翻译：紫外线稳定微生物杀虫剂，制法，使用方法
公开(公告)号：US5998330A
公开(公告)日：1999-12-07
申请号：US803670
申请日：1997-02-21
申请人： Gary W. Felton
发明人： Gary W. Felton
IPC分类号： A01N63/00 , A01N35/06 , C07C50/00
CPC分类号： A01N63/00
摘要： A method of treating vegetation by application of a microbial insecticide in which a quinone has been covalently bonded to the viral occlusion body surface of the microbial insecticide in order to improve the UV stability of the microbial insecticide by forming a protective shield around the pathogen.
摘要翻译：通过应用微生物杀虫剂处理植物的方法，其中醌已经共价结合到微生物杀虫剂的病毒闭塞体表面，以通过在病原体周围形成保护屏蔽来改善微生物杀虫剂的UV稳定性。

5. 发明授权

US09775900B2 Photodynamic diagnosis, formulations usable as photosensitizers for this purpose, method for the production and use thereof 有权
公开(公告)号：US09775900B2
公开(公告)日：2017-10-03
申请号：US15469602
申请日：2017-03-27
申请人： Sanochemia Pharmazeutika AG
发明人： Stefan Welzig , Beate Kälz , József Gungl , Klaus Gerdes , Werner Frantsits , Christina Abrahamsberg
IPC分类号： A61K9/00 , A61K41/00 , A61K31/121 , A61K36/38 , C07C50/36 , C07C50/00
CPC分类号： A61K41/00 , A61K9/0009 , A61K9/08 , A61K31/121 , A61K36/38 , A61K41/0057 , A61K47/32 , A61K49/0021 , A61K49/0054 , A61K49/0071 , C07C50/00 , C07C50/36
摘要： In the early detection of cancer, in particular bladder cancer, a photodynamic diagnosis uses, as a photosensitizer, a formulation that contains sodium hypericinate that is bonded to polyvinylpyrrolidone or complexed with polyvinylpyrrolidone.

6. 发明授权

US6022658A Nitro group-containing naphthoquinone derivatives and photosensitive material using the same for electrophotography 有权
公开(公告)号：US6022658A
公开(公告)日：2000-02-08
申请号：US296812
申请日：1999-04-23
申请人： Kazunari Hamasaki
发明人： Kazunari Hamasaki
IPC分类号： C07C205/46 , G03G5/06 , C07C50/00
CPC分类号： C07C205/46 , G03G5/0609 , G03G5/0618
摘要： A nitro group-containing naphthoquinone derivative represented by the following general formula: ##STR1## wherein R is a monovalent hydrocarbon group having a nitro group, and a ring A may be substituted with a substituent.This compound is a novel substance and is useful as an electron-transporting agent for an electrophotosensitive material. The electrophotosensitive material using the electron-transporting agent is highly sensitive, exhibits favorable repetitive properties, and makes it possible to favorably form images for extended periods of time.

7. 发明授权

US4590301A Polymerization inhibitors 失效
标题翻译：聚合抑制剂
公开(公告)号：US4590301A
公开(公告)日：1986-05-20
申请号：US664282
申请日：1984-10-24
申请人： Drahoslav Lim , Peter C. Morris
发明人： Drahoslav Lim , Peter C. Morris
IPC分类号： C08F2/00 , C07B31/00 , C07B63/04 , C07C39/15 , C07C43/23 , C07C46/06 , C07C50/06 , C07C57/075 , C07C67/00 , C07C67/62 , C07C69/54 , C08F2/38 , C08F20/00 , C08F20/02 , C09K15/08 , C07C39/12 , C07C43/02 , C07C50/00
CPC分类号： C07C46/06 , C07C39/15 , C07C43/23 , C07C50/06 , C07C67/62 , C09K15/08
摘要： Compounds of the general formula ##STR1## wherein n, R.sub.1, R.sub.2 and X are defined herein, are effective inhibitors of polymerization of vinylic monomers, particularly acrylic monomers. The inhibitors are easily, efficiently, and thoroughly removed from solution with the monomer by contact with charcoal.
摘要翻译：通式（1）或其中n，R 1，R 2和X在本文中定义的通式为“IMAGE”（1）或其中的化合物是乙烯基单体，特别是丙烯酸单体的有效的聚合抑制剂。抑制剂通过与木炭的接触容易，有效和彻底地从溶液中除去。

8. 发明授权

US4489096A Quinone compounds, their production and use 失效
标题翻译：喹啉酮化合物，其生产和使用
公开(公告)号：US4489096A
公开(公告)日：1984-12-18
申请号：US511083
申请日：1983-07-05
申请人： Shinji Terao , Yoshitaka Maki
发明人： Shinji Terao , Yoshitaka Maki
IPC分类号： C07C69/73 , A61K31/12 , A61K31/122 , A61P3/06 , C07C45/00 , C07C46/00 , C07C47/228 , C07C47/277 , C07C50/38 , C07C51/00 , C07C59/52 , C07C59/64 , C07C66/00 , C07C67/00 , C07C69/95 , C07C231/00 , C07C235/78 , C07C239/00 , C07C271/06 , C07D309/12 , A61K31/275 , C07C50/00 , C07C50/14
CPC分类号： C07D309/12 , C07C46/00 , C07C50/38 , C07C66/00
摘要： New quinone compounds of the formula: ##STR1## wherein R is methyl or methoxy andY is formyl, carboxyl, an alkoxycarbonyl having 2 to 5 carbon atoms, carbamoyl, a mono- or di- alkylcarbamoyl whose alkyl moiety has 1 to 4 carbon atoms or carbamoyloxymethyl, ortheir hydroquinone-form compounds, or pharmaceutically acceptable salts thereof, have useful physiological activities such as antiasthmatic and antiallergic activities.
摘要翻译：新的具有下式的醌化合物：其中R是甲基或甲氧基，Y是甲酰基，羧基，具有2-5个碳原子的烷氧基羰基，氨基甲酰基，一或二烷基氨基甲酰基，其烷基部分具有1至4个碳原子或氨基甲酰氧基甲基或其氢醌形式的化合物或其药学上可接受的盐具有有用的生理活性，例如抗哮喘和抗过敏活性。

9. 发明授权

US4257851A Purification of naphthoquinone 失效
标题翻译：萘醌的纯化
公开(公告)号：US4257851A
公开(公告)日：1981-03-24
申请号：US22878
申请日：1979-03-22
申请人： Ryo Matsuura , Kazuaki Sakai , Tuneyasu Sato , Yorinobu Yamada , Kowzo Bandow
发明人： Ryo Matsuura , Kazuaki Sakai , Tuneyasu Sato , Yorinobu Yamada , Kowzo Bandow
IPC分类号： C07C46/10 , B01D3/10 , C07C50/00
CPC分类号： C07C46/10
摘要： A crude naphthoquinone produced by an oxidation of naphthalene is purified by a reduced pressure distillation of a crude 1,4-naphthoquinone having an acid content of less than 5 equivalent % calculated as monobasic acid and the crude naphthoquinone is preferably treated by an oxidation of oxidizable impurities.
摘要翻译：通过萘酸氧化生产的粗萘醌通过以一元酸计算的酸含量小于5当量的粗1,4-萘醌的减压蒸馏来纯化，粗萘醌优选通过氧化可氧化的杂质。

10. 发明授权

US10724143B1 Electrochemical deblocking solution for electrochemical oligomer synthesis on an electrode array 有权
公开(公告)号：US10724143B1
公开(公告)日：2020-07-28
申请号：US16016403
申请日：2018-06-22
申请人： CustomArray, Inc.
发明人： Karl Maurer , John J. Cooper
IPC分类号： C25B3/04 , C25B3/02 , C07H21/02 , C07H21/04 , B01J19/00 , C07B31/00 , C07B33/00 , C25B3/00 , C07D213/16 , C07C309/30 , C07C50/00 , C25B3/10 , C07B41/06 , C07B41/02
摘要： There is disclosed an electrochemical deblocking solution for use on an electrode microarray. There is further disclosed a method for electrochemical synthesis on an electrode array using the electrochemical deblocking solution. The solution and method are for removing acid-labile protecting groups for synthesis of oligonucleotides, peptides, small molecules, or polymers on a microarray of electrodes while substantially improving isolation of deblocking to active electrodes. The method comprises applying a voltage or a current to at least one electrode of an array of electrodes. The array of electrodes is covered by the electrochemical deblocking solution.

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