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    • 6. 发明授权
    • Methods for forming a metal layer on a semiconductor
    • 在半导体上形成金属层的方法
    • US07067420B2
    • 2006-06-27
    • US10404360
    • 2003-04-01
    • Kyung-In ChoiGil-Heyun ChoiByung-Hee KimSang-Bum Kang
    • Kyung-In ChoiGil-Heyun ChoiByung-Hee KimSang-Bum Kang
    • H10L21/4763H10L21/20H10L21/44
    • H01L21/76843C23C16/34C23C16/45542C23C16/45553H01L21/28562H01L21/32051H01L21/76877
    • A metal layer is formed on an integrated circuit device including forming an insulating layer on an integrated circuit substrate. A contact hole is formed by selectively etching the insulating layer to thereby partially expose the substrate. A metal layer including tantalum nitride is formed on the insulating layer including the contact hole using a tantalum precursor including a tantalum element and at least one bonding element that is chemically bonded to the tantalum element. A part of the at least one bonding element include at least one ligand bonding element that is ligand-bonded to the tantalum element. Forming the metal layer may include removing at least some of the ligand bonded elements with a removing gas that is substantially free of hydrogen radicals. The metal layer may be formed using a chemical vapor deposition (CVD) or an atomic layer deposition (ALD) process. A copper or other metal layer may be deposited on the metal layer including tantalum nitride.
    • 金属层形成在集成电路器件上,包括在集成电路衬底上形成绝缘层。 通过选择性地蚀刻绝缘层从而部分地暴露衬底而形成接触孔。 包括氮化钽的金属层使用包括钽元素的钽前体和与钽元素化学键合的至少一个结合元件在包括接触孔的绝缘层上形成。 至少一个键合元件的一部分包括与钽元素配位键合的至少一个配体结合元件。 形成金属层可以包括用基本上不含氢自由基的去除气体去除至少一些配体键合元件。 可以使用化学气相沉积(CVD)或原子层沉积(ALD)工艺来形成金属层。 可以在包括氮化钽的金属层上沉积铜或其它金属层。