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    • 4. 发明授权
    • Coating method for the preparation of coated nuclear fuels with carbides borides or nitrides by using high temperature and high pressure combustion synthesis
    • 通过使用高温高压燃烧合成制备涂覆核燃料的碳化物硼化物或氮化物的涂覆方法
    • US06190725B1
    • 2001-02-20
    • US09140691
    • 1998-08-26
    • Young Woo LeeBong Goo KimJung Won LeeSang Ho NaDong Sung SohnYong Choi
    • Young Woo LeeBong Goo KimJung Won LeeSang Ho NaDong Sung SohnYong Choi
    • G21C306
    • C23C16/44C23C16/325G21C3/20G21C3/623G21C3/626G21Y2002/304G21Y2002/50G21Y2004/40Y02E30/33Y02E30/38
    • The present invention relates to a coating method for the preparation of a coated nuclear fuel. Particularly, the present invention relates to the coating method of nuclear fuel surface with more than two coated layers of carbides, borides or nitrides and their compounds comprising deposition or permeation steps of i) elements or mixture that can form carbides, borides or nitrides and ii) a layer of pyrolytic carbon or boron prepared by chemical vapor deposition(CVD) or sputtering in sequence or in reverse sequence, or nitrogen prepared by gas permeation in sequence, on the nuclear fuel surface. The coated layers are formed with carbides, borides, nitrides or their mixture at high temperature and pressure by a combustion synthesis. The coating method of this invention can be applied to various types of nuclear fuels either in particle or in pellet type and control and preserve fine crystal structure without phase transition since the surface of nuclear fuel coated with pyrolytic carbon and silicon is heated only for several seconds by heat source such as laser beam, arc or microwave. Thus, the present invention is excellent method of coating nuclear fuel surface not only for particle type fuel which used in High Temperature Gas-cooled Reactor (HTGR) but also for pellet type fuel used for Water-cooled Reactors.
    • 本发明涉及一种涂覆核燃料的制备方法。 特别地,本发明涉及具有多于两个碳化物,硼化物或氮化物涂层的核燃料表面的涂覆方法及其化合物,其包括沉积或渗透步骤,i)可形成碳化物,硼化物或氮化物的元素或混合物,以及ii )通过化学气相沉积(CVD)或溅射按顺序或反向顺序制备的热解碳或硼的层,或通过气相渗透制备的氮在核燃料表面上。 涂覆层通过燃烧合成在高温和高压下由碳化物,硼化物,氮化物或它们的混合物形成。 本发明的涂布方法可以应用于颗粒或颗粒型的各种类型的核燃料,并且控制和保存没有相变的精细晶体结构,因为涂覆有热解碳和硅的核燃料的表面仅被加热几秒钟 通过激光束,电弧或微波等热源。 因此,本发明不仅用于高温气冷堆(HTGR)中使用的颗粒型燃料,而且用于水冷反应堆的颗粒型燃料,也是涂覆核燃料表面的优良方法。