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    • 2. 发明申请
    • Photographic element, compound, and process
    • 摄影元素,复合和过程
    • US20020051945A1
    • 2002-05-02
    • US09982476
    • 2001-10-18
    • William J. BegleyFrank D. ComsGary M. Russo
    • G03C001/46G03C007/34C07D213/46C07D211/82
    • G03C7/346G03C7/3212
    • Disclosed is a photographic element comprising a light-sensitive silver halide emulsion layer having associated therewith a cyan nullNB couplernull having the formula (I): 1 wherein the term nullNB couplernull represents a coupler of formula (I) that forms a dye for which the left bandwidth (LBW) using spin-coating is at least 5 nm less than that of the same dye in solution form; Y is H or a coupling-off group; each Znull and Z* is an independently selected substituent group where n is 0 to 4 and p is 0 to 2; W2 represents the atoms necessary to complete a heterocyclic ring group; and V is a sulfone or sulfoxide containing group; provided that the combined sum of the aliphatic carbon atoms in V, all Znull and all Z* is at least 8. The element exhibits improved cyan dye hue.
    • 公开了一种照相元件,其包含感光卤化银乳剂层,其具有与其相关联的具有式(I)的青色“NB偶联剂”:其中术语“NB偶联剂”表示式(I)的成色剂,其形成用于 其中使用旋涂的左带宽(LBW)比溶液形式的相同染料的至少5nm; Y为H或偶合离去基团; 每个Z“和Z'是独立选择的取代基,其中n为0至4,p为0至2; W2表示完成杂环基团所需的原子; 并且V是含有砜或亚砜的基团; 条件是V,全Z'和全Z *中的脂族碳原子的总和为至少8.该元素表现出改善的青色染料色调。
    • 3. 发明申请
    • Colour photographic print material
    • 彩色照相打印材料
    • US20040018455A1
    • 2004-01-29
    • US10609355
    • 2003-06-27
    • Markus GeigerAxel JochumRalf Weimann
    • G03C007/34G03C001/46
    • G03C7/3225G03C7/3022G03C7/30535G03C7/346G03C7/3835G03C2001/03517
    • A colour photographic print material having at least one red-sensitive silver halide emulsion layer containing at least one cyan coupler, at least one green-sensitive silver halide emulsion layer containing at least one magenta coupler and at least one blue-sensitive silver halide emulsion layer containing at least one yellow coupler, characterised in that the magenta coupler is of the formula 1 in which R1 means a tertiary alkyl residue, Y means a hydrogen atom or a halogen atom, A means an alkylene residue and R2 means an alkyl residue or an aryl residue and the cyan coupler is of the formula 2 in which R3 means a hydrogen atom or an alkyl group, R4 means an alkyl group with at least 8 C atoms, R5 means a halogen atom, a cyano, trifluoromethyl or alkoxycarbonyl group, R6 means a hydrogen atom or R5 and Z means a hydrogen atom or a group eliminable under the conditions of chromogenic development, is distinguished by very good colour purity after long-term storage.
    • 具有至少一种含有至少一种青色成色剂的至少一种感红卤化银乳剂层的彩色照相印刷材料,至少一种含有至少一种品红成色剂的至少一种感光卤化银乳剂层和至少一种感蓝卤化银乳剂层 含有至少一个黄色成色剂,其特征在于品红成色剂具有下式:其中R 1表示叔烷基残基,Y表示氢原子或卤素原子,A表示亚烷基,R 2表示 烷基残基或芳基残基,而青色成色剂具有下式:其中R 3表示氢原子或烷基,R 4表示具有至少8个C原子的烷基,R 5表示 卤素原子,氰基,三氟甲基或烷氧基羰基,R 6表示氢原子或R 5,Z表示氢原子或在显色发展条件下可消除的基团,其特征在于非常好的色纯度 长期储存。
    • 4. 发明申请
    • Photographic element with dye-forming coupler and stabilizing compound
    • 具有染料成色剂和稳定化合物的摄影元件
    • US20020058212A1
    • 2002-05-16
    • US09934107
    • 2001-08-21
    • Eastman Kodak Company
    • David ClarkeLlewellyn J. LeyshonChristopher P. Moore
    • G03C001/34G03C001/46G03C007/32G03C007/34G03C007/36
    • G03C7/39288G03C7/34G03C7/36G03C7/38G03C7/384G03C7/3885
    • The invention relates to a photographic element comprising a light sensitive silver halide emulsion layer having associated therewith one or more dye-forming couplers and a stabilizer compound of formula (I): 1 wherein R1 and R2 are independently selected from hydrogen or an unsubstituted or substituted alkyl, aryl, alkoxy, aryloxy or amino group or may combine to complete a 5-10 membered heterocyclic ring which may contain in addition to the silicon atom one or more heteroatoms selected from nitrogen, oxygen and sulfur, which ring is unsubstituted or substituted; each Z independently represents the atoms necessary to complete a substituted or unsubstituted arene or heteroaromatic ring system; X is a single bond or a linking group having a single atom which connects the arene rings or heteroaromatic ring systems, or X forms, together with substituents ortho to X on the arene rings or heteroaromatic ring systems, a fused unsubstituted or substituted 5-, 6-or 7-membered ring, which may contain one or two heteroatoms selected from nitrogen, oxygen and sulfur. The stabilizer is used to enhance the image stability of the dye formed from a cyan, magenta or yellow dye-forming coupler without significantly degrading other photographic properties.
    • 本发明涉及一种照相元件,其包含与其相关联的一种或多种成色成色剂的光敏卤化银乳剂层和式(I)的稳定剂化合物:其中R 1和R 2独立地选自氢或未取代或取代的烷基 ,芳基,烷氧基,芳氧基或氨基,或者可以结合形成5-10元杂环,除了硅原子外还可以含有一个或多个选自氮,氧和硫的杂原子,该环是未取代的或取代的; 每个Z独立地表示完成取代或未取代的芳族或杂芳族环系统所必需的原子; X是单键或具有连接芳环或杂芳环系统或X形式的单个原子的连接基团与芳环或杂芳族环体系上的X邻位的取代基,稠合的未取代或取代的5-, 6-或7-元环,其可以含有一个或两个选自氮,氧和硫的杂原子。 稳定剂用于增强由青色,品红色或黄色染料形成成色剂形成的染料的图像稳定性,而不会显着降解其它照相性能。
    • 6. 发明申请
    • Colour photographic print material
    • 彩色照相打印材料
    • US20040023173A1
    • 2004-02-05
    • US10612809
    • 2003-07-02
    • Agfa-Gevaert
    • Ralf WeimannMarkus GeigerCuong LyKlaus SinzgerBeate WeberHeinz Wiesen
    • G03C007/34G03C001/46
    • G03C7/346G03C1/09G03C5/04G03C7/30G03C7/3022G03C7/39204G03C2001/03517G03C2001/093G03C2200/19
    • A print material having a support, at least one red-sensitive silver halide emulsion layer containing at least one cyan coupler, at least one green-sensitive silver halide emulsion layer containing at least one magenta coupler and at least one blue-sensitive silver halide emulsion layer containing at least one yellow coupler, characterised in that the silver halide crystals of the red-sensitive layer have a chloride content of at least 95 mol %, contain 20 to 500 nmol of iridium per mol of silver halide and the cyan coupler is of the formula 1 in which R1 means a hydrogen atom or an alkyl group, R2 means an alkyl, aryl or hetaryl group, R3 means an alkyl or aryl group, R4 means an alkyl, alkenyl, alkoxy, aryloxy, acyloxy, acylamino, sulfonyloxy, sulfamoylamino, sulfonarnido, ureido, hydroxycarbonyl, hydroxycarbonylamino, carbamoyl, alkylthio, arylthio, alkylamino or arylamino group or a hydrogen atom and Z means a hydrogen atom or a group eliminable under the conditions of chromogenic development, is distinguished in that it is equally ideally suitable for analogue and scanning exposure and exhibits very good latent image stability.
    • 具有载体的印刷材料,至少一种含有至少一种青色成色剂的感红卤化银乳剂层,至少一种包含至少一种品红成色剂的至少一种感光卤化银乳剂层和至少一种感蓝卤化银乳剂 含有至少一种黄色成色剂的层,其特征在于,红色敏感层的卤化银晶体的氯化物含量为至少95摩尔%,每摩尔卤化银含有20-500nmol的铱,青色成色剂为 其中R 1表示氢原子或烷基的式,R 2表示烷基,芳基或杂芳基,R 3表示烷基或芳基,R 4表示烷基,烯基 ,烷氧基,芳氧基,酰氧基,酰氨基,磺酰氧基,氨磺酰氨基,磺酰氨基,脲基,羟基羰基,羟基羰基氨基,氨基甲酰基,烷硫基,芳硫基,烷基氨基或芳基氨基或氢原子,Z表示氢原子或可在色度条件下消除的基团 基因发育的区别在于它同样理想地适用于模拟和扫描曝光,并且表现出非常好的潜像稳定性。
    • 8. 发明申请
    • Photographic elements containing a cyan dye-forming coupler, stabilizer and solvent
    • 含有青色染料成色剂,稳定剂和溶剂的摄影元件
    • US20020061480A1
    • 2002-05-23
    • US09934143
    • 2001-08-21
    • Eastman Kodak Company
    • Danuta Gibson
    • G03C001/34G03C007/34
    • G03C7/39296G03C7/346G03C7/3885G03C7/39232G03C7/39236G03C7/39256G03C7/39276Y10S430/132
    • The invention provides a photographic element comprising at least one light-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, UV absorber and (A) a stabilizer of formula (I) 1 wherein R1 is an unsubstituted or substituted alkyl or aryl group or a 5- to 10- membered heterocyclic ring which contains one or more heteroatoms selected from nitrogen, oxygen and sulfur, which ring is unsubstituted or substituted; Z is a hydrogen atom or a substituent group; X is a group selected from nullSO2null, nullSOnull, nullCOOnull,nullCOnull and nullCSnull, W is one or more unsubstituted or independently substituted alkylene groups connecting the nitrogen atom to X, and p is 0 or 1; R2 is a substituent group; or the groups represented by Z and R2 can be joined to form a ring which may be substituted; and (B) a high-boiling solvent of formula (II) 2 wherein R3 is an unsubstituted or substituted alkyl or aryl group; and G is an unsubstituted or substituted alkyl group. The invention provides improved light and dark stability in a photographic element without degradation in hue or reactivity of the dyes therein.
    • 本发明提供一种照相元件,其包含至少一种感光卤化银乳剂层,其具有至少一种形成青色染料的成色剂,UV吸收剂和(A)式(I)的稳定剂,其中R 1是未取代或取代的烷基 或芳基或含有一个或多个选自氮,氧和硫的杂原子的5-至10-元杂环,该环是未取代或取代的; Z是氢原子或取代基; X是选自-SO 2 - , - SO - , - CO - , - CO-和-CS-的基团,W是连接氮原子与X连接的一个或多个未取代或独立取代的亚烷基,p是0或1 ; R2是取代基; 或由Z和R 2表示的基团可以连接形成可被取代的环; 和(B)式(II)的高沸点溶剂,其中R 3是未取代或取代的烷基或芳基; 并且G是未取代或取代的烷基。 本发明提供了在照相元件中改善的光和暗稳定性,而其中染料的色调或反应性不降低。
    • 9. 发明申请
    • Silver halide color photographic light-sensitive material and color image formation method using the same
    • 卤化银彩色摄影感光材料和使用其的彩色图像形成方法
    • US20020025497A1
    • 2002-02-28
    • US09899100
    • 2001-07-06
    • Naoto MatsudaHisashi Mikoshiba
    • G03C001/46G03C007/34G03C005/50
    • G03C7/3225G03C5/50G03C7/30G03C7/3029G03C7/346G03C7/3825G03C7/3885G03C2007/3034
    • A silver halide color photographic light-sensitive material has a red-, green-, and blue-sensitive emulsion layer in this order from the side closest to a support. The green-sensitive layer contains a coupler represented by formula (MC-I), and the red-sensitive emulsion layer contains a coupler represented by formula (CC-I): 1 wherein R1 represents a hydrogen atom or substituent; one of G1 and G2 represents C, the other represents N; and R2 represents a substituent which substitutes one of G1 and G2 which is C; X represents a hydrogen atom or a splitting off group; 2 wherein Rc1 represents a hydrogen atom or alkyl group, Rc2 represents an alkyl or aryl group, n is 1, 2, or 3, and Y is positioned in the meta and/or para position of the phenyl group with respect to the sulfonyl group, and represents alkyl, alkenyl, alkoxy, aryloxy, acyloxy, acylamino, sulfonyloxy, sulfamoylamino, sulfonamide, ureido, oxycarbonyl, oxycarbonylamino, or carbamoyl group.
    • 卤化银彩色照相感光材料从最靠近载体的一侧依次具有红,绿和蓝敏感乳剂层。 感光层包含由式(MC-1)表示的成色剂,并且感红乳剂层含有由式(CC-I)表示的成色剂:其中R1表示氢原子或取代基; G1和G2之一表示C,另一个表示N; 并且R 2表示取代基为G的G 1和G 2之一的取代基; X表示氢原子或分解基团; 其中Rc1表示氢原子或烷基,Rc2表示烷基或芳基,n为1,2或3,并且Y位于苯基相对于磺酰基的间位和/或对位, 并表示烷基,烯基,烷氧基,芳氧基,酰氧基,酰氨基,磺酰氧基,氨磺酰氨基,磺酰胺,脲基,氧羰基,氧羰基氨基或氨基甲酰基。