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    • 6. 发明授权
    • Electrodeposition method
    • 电沉积法
    • US3662047A
    • 1972-05-09
    • US3662047D
    • 1970-04-09
    • SONY CORP
    • TOKUMOTO SHIN-ICHITANAKA EIJI
    • C25D3/66C25C3/04C25C3/26C25C3/28C25C3/30C22D3/00C22D3/20
    • C25C3/28
    • A METHOD FOR THE ELECTRODEPOSITIONOF TITANIUM OR ITS ALLOYS IS SHOWN. A FUSED SALT ELECTROLYTIC BATH CONTAINING (1) A MIXTURE OF THE CHLORIDE SALTS OF BARIUM, MAGNESIUM, SODIUM AND CALCIUM HAVING A FREEZING POINT OF LESS THAN 600*C., AND (2) TILANIUM DICHLORIDE, AND IF DESIRED, (3) A SOURCE OF A SUITABLE ALLOY METAL IS ELECTROLYZED. THE ELECTROLYTIC BATH IS MAINTAINED AT A TEMPERATURE OF 400*C. TO 580*C. AND UNDER SUCH CONDITIONS AS WILL MAINTAIN THE MOLAR RATIO OF TILANIUM TRICHLORIDE TO TITANIUM DICHLORIDE LESS THAN 0.5 IN THE VICINITY OF THE ELECTRODE TO BE ELECTROPESPOSITED. A PORTION OF THE BATH IS DESIRABLY MAINTAINED AT A TEMPERATURE ABOVE 500*C. TO CONVERT TITANIUM TRICHLORIDE TO TITANIUM DICHLORIDE TO MAINTAIN THE ABOVE MOLAR RATIO NEAR THE CATHODE. A UNIQUE POLARIZED REGION IS FORMED ABOUT THE CATHODE AS MAGNESIUM IS SIMULTANEOUSLY ELECTRODESPOSITED WITH TITANIUM OR ITS ALLOY AND THEN REHALOGENIZED INTO THE ELECTROLYTE. THE PLATE PRODUCT IS SMOOTH IN SURFACE AND NUMEROUS CAPITAL AND OPERATING EFFICIENCIES ARE ACHIEVED.