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    • 5. 发明授权
    • Cemented carbide body with improved high temperature and thermomechanical properties
    • 具有改善高温和热机械性能的硬质合金体
    • US06423112B1
    • 2002-07-23
    • US09546607
    • 2000-04-10
    • Jan ÅkermanThomas Ericson
    • Jan ÅkermanThomas Ericson
    • C22C2902
    • C22C29/08E21B10/56
    • There is now provided a cemented carbide grade for rock excavation purposes with 88-96 weight % WC, preferably 91-95% weight % WC, with a binder phase consisting of only cobalt or cobalt and nickel, with a maximum of 25% of the binder being Ni, possibly with small additions of rare earth metals, such as Ce and Y, up to a maximum of 2% of the total cemented carbide. The WC grains are rounded because of the process of coating the WC with cobalt, and not recrystallized or showing grain growth or very sharp cornered grains like conventionally milled WC, thus giving the bodies surprisingly high thermal conductivity. The average grain size should be from 8-30 &mgr;m, preferably from 12-20 &mgr;m. The maximum grain size does not exceed 2 times the average value and no more than 2% of the grains found in the structure are less than half of the average grain size.
    • 现在提供了用于岩石开挖目的的硬质合金级别,其具有88-96重量%的WC,优选为91-95重量%的WC,粘结相仅由钴或钴和镍组成,最大为25% 粘合剂是Ni,可能添加少量稀土金属如Ce和Y,最多可达到总硬质合金的2%。 WC颗粒由于用钴涂覆WC而没有重结晶或显示晶粒生长或非常锋利的角状颗粒的方法是圆形的,如常规研磨的WC,从而使得物体具有惊人的高导热性。 平均晶粒尺寸应为8-30μm,优选12-20μm。 最大晶粒尺寸不超过平均值的2倍,结构中发现的不超过2%的晶粒小于平均晶粒尺寸的一半。
    • 9. 发明授权
    • Tungsten-carbide articles made by metal injection molding and method
    • 通过金属注射成型制成的碳化钨制品和方法
    • US06790252B2
    • 2004-09-14
    • US10124883
    • 2002-04-18
    • David J. SmithThomas B. ShappieRobert A. SanfordRichard J. Liesz
    • David J. SmithThomas B. ShappieRobert A. SanfordRichard J. Liesz
    • C22C2902
    • B22F3/225B22F1/0059B22F2998/00B22F2998/10C22C1/051C22C29/08B22F3/22B22F3/1025
    • A process of making an article of a tungsten-carbide-cobalt alloy with or without an additive of one or more of tantalum, cobalt-nickel, nickel-tantalum, tantalum-carbide, titanium-carbide, niobium-carbide, chromium-carbide, titanium-nitride and diamond dust. The method includes forming a homogeneous mixture of polygonal-shaped powder tungsten-carbide-cobalt and a polygonal-shaped powder additive and a binder including wax and a high molecular weight polyolefin polymer and injecting the mixture under heat and pressure into a metal injection mold to form a green preform of the article. The green preform is immersed in a linear hydrocarbon or a halogenated hydrocarbon or mixtures to dissolve and remove the wax and convert the green preform into a brown preform which is sintered to remove the remainder of the binder and to densify the brown preform into an article having a density not less than 98%. Various tungsten-carbide articles are disclosed.
    • 制备具有或不具有钽,钴 - 镍,镍 - 钽,钽 - 碳化物,碳化钛,碳化铌,碳化铬,碳化钛, 氮化钛和金刚石粉尘。 该方法包括形成多边形粉末碳化钨 - 钴和多边形粉末添加剂的均匀混合物和包含蜡和高分子量聚烯烃聚合物的粘合剂,并将该混合物在热和压力下注入金属注射模具中 形成物品的绿色预制件。 将绿色预成型件浸入线性烃或卤代烃或混合物中以溶解和除去蜡并将生坯预成型体转化成棕色预成型坯,其被烧结以除去剩余的粘合剂并将棕色预成型体致密化成具有 密度不低于98%。 公开了各种碳化钨制品。