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    • 6. 发明授权
    • Multi-component coatings, adhesives and sealants and the use thereof
    • 多组分涂料,粘合剂和密封剂及其用途
    • US06756072B2
    • 2004-06-29
    • US10240861
    • 2002-10-04
    • Hubert BaumgartHeinz-Peter RinkSimone JurczikEdeltraud Hagemeister
    • Hubert BaumgartHeinz-Peter RinkSimone JurczikEdeltraud Hagemeister
    • C09D17504
    • C08G18/6229C08G18/2835C08G18/807C09D175/04Y10S525/934
    • Multicomponent coating materials, adhesives and sealing compounds comprising a (meth)acrylate (A) containing, based on (A), up to 90% by weight of hydroxyl-containing monomers in copolymerized form, of which (a1) from 20-90% by weight, based on (A), are 4-hydroxybutyl (meth)acrylate and/or 2-alkylpropane-1,3-diol mono(meth)acrylate, and (a2) from 0-40% by weight based on (A), are other hydroxyl-containing monomers; and (B) an adduct preparable from (b1) a diisocyanate, and (b2) a compound of the general formula I having an isocyanate-reactive group: wherein R1 and R2 are hydrogen or alkyl radicals, X and Y are oxygen, sulfur or >N—R6 where R6 is alkyl radical or aryl radical, R3 is alkylene radical and R4 and R5 are hydrogen, isocyanate-reactive groups or radicals R6; where R4, R5 or R6 contains an isocyanate-reactive group or R4 or R5 is an isocyanate-reactive functional group, and where R4, R5 or R6, where present, contain no isocyanate-reactive groups and the molar ratio of isocyanate groups in (b1) to the isocyanate-reactive groups in the compound I is 1.0.
    • 包含基于(A)至多90重量%的共聚形式的含羟基单体的(甲基)丙烯酸酯(A)的多组分涂料,粘合剂和密封化合物,其中(a1)为20-90% (甲基)丙烯酸4-羟基丁酯和/或2-烷基丙烷-1,3-二醇单(甲基)丙烯酸酯,和(a2)基于(A)为0-40重量% )是其它含羟基的单体; 和(B)可由(b1)二异氰酸酯制备的加合物,和(b2)具有异氰酸酯反应性基团的通式I化合物:其中R 1和R 2是氢或烷基,X和 Y是氧,硫或> NR 6,其中R 6是烷基或芳基,R 3是亚烷基,R 4和R 5是氢,异氰酸酯反应性基团或基团R <6>; 其中R 4,R 5或R 6含有异氰酸酯反应性基团,或者R 4或R 5是异氰酸酯反应性官能团,其中R 4,R 5, 或R 6不存在异氰酸酯反应性基团,并且(b1)中的异氰酸酯基与化合物I中的异氰酸酯反应性基团的摩尔比为1.0。
    • 10. 发明授权
    • Polyurethane coatings, based on polyisocyanates containing uretdione and/or oxadiazinetrione groups
    • 聚氨酯涂料,基于含有脲二酮和/或恶二嗪四酮基团的多异氰酸酯
    • US06806340B2
    • 2004-10-19
    • US10204978
    • 2002-08-27
    • Stefan GrothDetlef-Ingo Schütze
    • Stefan GrothDetlef-Ingo Schütze
    • C09D17504
    • D06N3/148C08G18/10C08G18/44C08G18/4854C08G18/798C09D175/04C14C11/006D06N3/14D06N3/146Y10T428/31551Y10T428/31558Y10T428/31591C08G18/3215
    • Polyurethane coatings which are the reaction product of A) an aliphatic, isocyanate-containing prepolymer having an isocyanate content of 1-8 wt. % and a free monomeric diisocyanate content of less than 2 wt. %, and containing 0.1 to 1.5 moles of per 1000 g of prepolymer of aliphatically bound uretdione and oxadiazinetrione groups, and B) a polyol component B) comprising at least 50 equivalent % of a compound corresponding to the formula HO—X—Y—X—OH where Y represents methylene, ethylene, —C≡C—, cyclohexylene-1,4, -1,3, -1,2, or phenylene-1,4, -1,3, -1,2 and X represents methylene, —OCH2CH2— (the oxygen being bound to the Y), or cyclohexylene-1,4, -1,3, -1,2, and where the equivalent ratio of the free NCO groups to isocyanate-reactive groups is 0.90 to 1.5. The coatings are applied to flexible substrates such as textile or leather by the casting or knife coating process by means of reactive compositions.
    • 聚氨酯涂料,其是A)具有异氰酸酯含量为1-8重量%的脂族异氰酸酯的预聚物的反应产物。 %和游离的单体二异氰酸酯含量小于2wt。 并且含有0.1-1.5摩尔的每1000克脂族酯结合的脲二酮和恶二嗪二酮基团的预聚物,和B)包含至少50当量%的对应于所述甲基的化合物的多元醇组分B)代表亚甲基,亚乙基,-C = C-,亚环己基-1,4,-1,3,...,1,2-或亚苯基-1,4,-1,3,-1,2-,X表示亚甲基,-OCH 2 CH 2 - (氧与 Y)或亚环己基-1,4,1,3 -1,2,其中游离NCO基团与异氰酸酯反应性基团的当量比为0.90至1.5。 通过使用反应性组合物的铸造或刮刀涂布将涂层施加到柔性基材如纺织品或皮革上。