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    • 7. 发明授权
    • Powerfeed polymers having improved block resistance performance
    • 具有改善阻块性能的加电聚合物
    • US08907005B2
    • 2014-12-09
    • US13889590
    • 2013-05-08
    • Rohm and Haas Company
    • Gary W. DombrowskiArnold S. BrownellAurelia de la Cuesta SheppardThomas R. Tepe
    • C08L33/06C08K5/07C09D113/02C08F220/18C09D133/10
    • C09D113/02C08F220/18C09D133/10C08F2220/1858C08F220/14C08F212/08C08F220/06C08F2220/1825
    • The present invention provides emulsion copolymers and coating compositions containing the same having improved room temperature and hot block resistance in coatings wherein the copolymers have a broad measured glass transition temperature and are the copolymerization product of a vinyl monomer composition A and a softer vinyl monomer composition B having a Hansch parameter of at least 3.2, and containing one or more vinyl monomer M, such that each of which vinyl monomer(s) M would when homopolymerized provide a homopolymer having a measured Tg of 20° C. or less, such as, for example, 2-ethylhexyl acrylate. In addition, the present invention provides methods for making the emulsion copolymers by a powerfeed process comprising feeding vinyl monomer composition A into a reactor from a feed vessel while feeding, simultaneously or after a delay, vinyl monomer composition B into the feed vessel while polymerizing the monomers in the reactor.
    • 本发明提供了含有该涂料的乳液共聚物和涂料组合物,其具有改进的室温和涂料中的耐热阻性,其中共聚物具有宽的测量玻璃化转变温度,并且是乙烯基单体组合物A和较软的乙烯基单体组合物B的共聚产物 具有至少3.2的Hansch参数,并且含有一种或多种乙烯基单体M,使得当均聚时每种乙烯基单体M将提供具有20℃或更低的测量Tg的均聚物, 例如丙烯酸2-乙基己酯。 此外,本发明提供了通过加电方法制备乳液共聚物的方法,包括将乙烯基单体组合物A从进料容器进料到反应器中,同时或延迟将乙烯基单体组合物B进料到进料容器中,同时聚合 反应器中的单体。