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    • 1. 发明授权
    • Polymers, method of producing the same and use of the same
    • 聚合物,生产方法和使用方法
    • US06197923B1
    • 2001-03-06
    • US09051754
    • 1998-04-20
    • Takakazu Yamamoto
    • Takakazu Yamamoto
    • C08G4306
    • H01M4/60C08G61/12C09K9/02D01F6/58G02F1/15H01B1/128H01L51/0035H01M4/606H01M4/608
    • N-Oxides of nitrogenous heterocycle or nitrogenous fused heterocycle polymers of general formula (1) or (7) (wherein any two of a, b, c, d, e, f, g and h are carbon atoms participating in the bonding between repeating units; at least one of them is N→O; the rest are each CH, N or N→O; and the degree of polymerization “n” is at least 5). These polymers have excellent heat resistance, are soluble in aqueous or organic solvents and controllable in the degree of depolarization and electrochemical redox potential, exhibit clear color changes by chemical or electrochemical oxidation or reduction, and are conductive per se . They can be used as moldings such as fibers and films; electrochromic elements; active materials and electrodes of cells; semiconductors including n-type semiconductors; and so on.
    • 通式(1)或(7)的氮杂环或含氮稠合杂环聚合物的N-氧化物(其中a,b,c,d,e,f,g和h中的任何两个是参与重复键合的碳原子 单元;其中至少一个为N-> O;其余各为CH,N或N-> O;聚合度“n”至少为5)。 这些聚合物具有优异的耐热性,可溶于水性或有机溶剂,并且可以在去极化和电化学氧化还原电位的程度上控制,通过化学或电化学氧化或还原表现出明显的颜色变化,并且本身是导电的。 它们可以用作纤维和薄膜等模制品; 电致变色元件; 细胞活性物质和电极; 包括n型半导体的半导体; 等等。