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1. 发明授权

US06410650B1 Ethylene/&agr;-olefin/unconjugated polyene copolymer rubber, rubber composition for sealing, molded rubber for sealing, and process for producing the molded rubber 有权
标题翻译：乙烯/α-烯烃/非共轭多烯共聚物橡胶，密封用橡胶组合物，用于密封的模制橡胶和用于生产模制橡胶的方法
公开(公告)号：US06410650B1
公开(公告)日：2002-06-25
申请号：US09701304
申请日：2000-11-28
申请人： Taku Koda , Masaaki Kawasaki
发明人： Taku Koda , Masaaki Kawasaki
IPC分类号： C08F21018
CPC分类号： C09K3/10 , C08F210/18 , C09K2200/0642 , C08F2500/17 , C08F2500/04 , C08F2500/21 , C08F210/06
摘要： The present invention relates to an ethylene-&agr;-olefin-non-conjugated polyene copolymer rubber comprising ethylene, an &agr;-olefin having 3 to 20 carbon atoms and a non-conjugated polyene, characterized in that: (i) the intrinsic viscosity [&eegr;] as measured in decalin solvent at 135° C. is 1.5 to 5.0 dl/g; (ii) the g&eegr;* or g′ value is 0.6 to 0.9; (iii) the Mw/Mn is 3.0 to 50; (iv) the iodine value is 10 to 40; (v) the molar ratio of ethylene to the &agr;-olefin having 3 to 20 carbon atoms is 40/60 to 95/5; and (vi) the intensity ratio D of T&agr;&bgr; to T&agr;&agr; in 13C-NMR spectrum (T&agr;&bgr;/T&agr;&agr;) is 0.5 or less, as well as to a rubber composition for sealing using said copolymer rubber, a molded rubber part for sealing, and a process for preparing said molded part.
摘要翻译：本发明涉及包含乙烯，具有3-20个碳原子的α-烯烃和非共轭多烯的乙烯-α-烯烃 - 非共轭多烯共聚物橡胶，其特征在于：（i）特性粘度[η ]，在135℃下在十氢化萘溶剂中测得的值为1.5〜5.0dl / g;（ii）geta *或g'值为0.6〜0.9;（iii）Mw / Mn为3.0〜50;（iv）碘值为10〜40;（v）乙烯与碳原子数为3〜20的α-烯烃的摩尔比为40/60〜95/5，和（vi）13 C-NMR谱（Talphabeta / Talphaalpha）中Talphabeta至Talphaalpha的强度比D为0.5以下，以及使用所述共聚物橡胶密封的橡胶组合物，密封用成型橡胶部和制备所述模制件的方法。

2. 发明授权

US06822062B2 Supported group 8-10 transition metal olefin polymerization catalysts 失效
公开(公告)号：US06822062B2
公开(公告)日：2004-11-23
申请号：US09984620
申请日：2001-10-30
申请人： Peter Borden Mackenzie , Leslie Shane Moody , Christopher Moore Killian , Gino Georges Lavoie
发明人： Peter Borden Mackenzie , Leslie Shane Moody , Christopher Moore Killian , Gino Georges Lavoie
IPC分类号： C08F21018
CPC分类号： C07D241/06 , C07C251/36 , C07C257/14 , C07D231/12 , C07D233/56 , C07D233/96 , C07D249/08 , C07D265/30 , C07D285/10 , C07D319/12 , C07D339/08 , C07D513/04 , C07F9/5022 , C07F9/5031 , C07F15/006 , C07F15/0066 , C07F15/02 , C07F15/025 , C07F15/04 , C07F15/045 , C07F15/06 , C07F15/065 , C08F10/00 , C08F110/02 , C08F110/06 , C08F110/14 , C08F210/02 , C08F210/16 , C08F4/26 , C08F2500/10 , C08F2500/05 , C08F2500/03 , C08F2500/20 , C08F2500/02 , C08F2500/09 , C08F236/20 , C08F210/18 , C08F218/00 , C08F220/10 , C08F2500/04 , C08F210/14 , C08F4/7006
摘要： Methods for preparing olefin polymers, and catalysts for preparing olefin polymers are disclosed. The polymers can be prepared by contacting the corresponding monomers with a Group 8-10 transition metal catalyst and a solid support. The polymers are suitable for processing in conventional extrusion processes, and can be formed into high barrier sheets or films, or low molecular weight resins for use in synthetic waxes in wax coatings or as emulsions.

3. 发明授权

US06300447B1 Ethylene-&agr;-olefin-nonconjugated polyene random copolymer 有权
标题翻译：乙烯-α-烯烃 - 非共轭多烯无规共聚物
公开(公告)号：US06300447B1
公开(公告)日：2001-10-09
申请号：US09315233
申请日：1999-05-20
申请人： Hirofumi Johoji , Toshiyuki Kuwabara , Atsuko Ogawa
发明人： Hirofumi Johoji , Toshiyuki Kuwabara , Atsuko Ogawa
IPC分类号： C08F21018
CPC分类号： C08F210/18 , C08F4/65908 , C08F4/65912 , Y10S526/916 , C08F4/6592 , C08F210/06 , C08F236/20 , C08F2500/25 , C08F2500/17
摘要： An ethylene-&agr;-olefin-nonconjugated polyene random copolymer obtained by polymerizing the following components (a), (b) and (c) in the presence of a catalyst comprising a transition metal complex having at least one cyclopentadienyl skeleton and satisfying the conditions (1), (2), (3) and (4): (a) ethylene, (b) &agr;-olefin having 3 to 20 carbon atoms, and (c) one or more nonconjugated polyene at least containing a nonconjugated polyene in which at least one or more hydrogen atoms are respectively bound to all of carbon atoms having a double bond; (1) the molar ratio of a unit derived from ethylene to a unit derived from &agr;-olefin in the copolymer is 95/5 to 20/80, (2) the iodine value is 0 to 50 (g/100 g polymer), (3) the intrinsic viscosity [&eegr;] measured in xylene at 70° C. is 0.5 to 10 dl/g, and (4) the Q value (weight average molecular weight/number average molecular weight) measured by gel permeation chromatography (GPC) is 3.0 or more.
摘要翻译：通过在包含具有至少一个环戊二烯基骨架的过渡金属配合物的催化剂的存在下聚合以下组分（a），（b）和（c））获得的乙烯-α-烯烃 - 非共轭多烯无规共聚物， 1），（2），（3）和（4）:( a）乙烯，（b）具有3至20个碳原子的α-烯烃，和（c）至少含有非共轭多烯的一种或多种非共轭多烯，至少一个或多个氢原子分别与具有双键的所有碳原子键合;（1）共聚物中衍生自乙烯的单元与衍生自α-烯烃的单元的摩尔比为95/5至20 / 80，（2）碘值为0〜50（g / 100g聚合物），（3）在70℃下在二甲苯中测定的特性粘度η为0.5〜10dl / g，（4）通过凝胶渗透色谱法（GPC）测定的Q值（重均分子量/数均分子量）为3.0以上。

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