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    • 9. 发明授权
    • Polymers containing silver and copper
    • 含银和铜的聚合物
    • US3953545A
    • 1976-04-27
    • US341385
    • 1973-03-15
    • Arthur Stoy
    • Arthur Stoy
    • C02F1/50C08F8/00C08F220/44C08J5/22C08K3/00C08L33/20G03C1/053G03C1/494C08F13/00C12G1/00G03C1/86
    • B01D67/0006B01D69/141B01D71/80C02F1/505C08F8/00C08K3/0083C08L33/20G03C1/053G03C1/494B01D71/42
    • New polymers and copolymers containing silver and/or copper, useful e.g. in manufacturing dialysis and filtration membranes, ion exchangers, light sensitive layers, catalysts and hydrophilic coatings, are prepared from copolymers or polymer mixtures containing both nitrile groups and strong acidic groups, by bringing them in contact with monovalent silver or copper ions or with their mixtures. Silver and/or copper are attached to nitrile groups by secondary valences, thus forming complex compounds. The probable formulae of the complex groups are: --CN.Ag.sup.+ or perhaps --CN.Ag.sup.+.NC-- and --CN.Cu.sup.+ or perhaps --CN.Cu.sup.+.Cu.sup.+.NC-- , the complex cations forming polymeric salts with strong acidic groups of the same or of an adjoining macromolecule, to which all said nitrile and strongly acidic groups are attached as substituents.
    • 含有银和/或铜的新型聚合物和共聚物,例如有用的。 在制造透析和过滤膜,离子交换剂,光敏层,催化剂和亲水涂层中,由含有腈基和强酸性基团的共聚物或聚合物混合物通过使其与一价银或铜离子或其混合物接触而制备 。 银和/或铜通过二价键连接到腈基上,从而形成复合化合物。 复合基团的可能配方是:-CN.Ag +或者-CN.Ag +,NC-和-CN.Cu +或者也可以是-CN.Cu +,Cu + 形成与其相同或邻接的大分子的强酸性基团的聚合盐的络合物阳离子,其中所有腈和强酸性基团作为取代基连接。