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1. 发明授权

US06620968B1 High hydrocarbon space velocity process for preparing unsaturated aldehydes and acids 有权
标题翻译：用于制备不饱和醛和酸的高烃空间速度方法
公开(公告)号：US06620968B1
公开(公告)日：2003-09-16
申请号：US09708138
申请日：2000-11-08
申请人： Charles Michael Lonzetta , James Edward Elder , Peter David Klugherz , Timothy Allen Hale
发明人： Charles Michael Lonzetta , James Edward Elder , Peter David Klugherz , Timothy Allen Hale
IPC分类号： C07C51235
CPC分类号： B01J8/06 , B01J2208/025 , C07C45/35 , C07C51/252 , Y02P20/582 , C07C47/22 , C07C57/04
摘要： This invention relates to a high load process for preparing (meth)acrylic acid from a reactive hydrocarbon using a high reactive hydrocarbon space velocity to provide increased capacity and throughput.
摘要翻译：本发明涉及使用高反应性烃空间速度从反应性烃制备（甲基）丙烯酸的高负载方法，以提供增加的容量和产量。

2. 发明授权

US06462232B1 Production process for acrylic acid under controlled temperature conditions 有权
标题翻译：在控制温度条件下丙烯酸的生产工艺
公开(公告)号：US06462232B1
公开(公告)日：2002-10-08
申请号：US09365845
申请日：1999-08-03
申请人： Daisuke Nakamura , Hideyuki Hironaka , Michio Tanimoto
发明人： Daisuke Nakamura , Hideyuki Hironaka , Michio Tanimoto
IPC分类号： C07C51235
CPC分类号： C07C51/252 , C07C57/04
摘要： Provided is a process for producing acrylic acid stably at a high yield over a long period of time by subjecting acrolein or acrolein-containing gas to catalytic vapor phase oxidation. The above process is characterized by controlling the reaction so that the following equations (1) and (2) are satisfied: 1° C.≦T0−T1≦15° C. (1) T1
摘要翻译：本发明提供通过使丙烯醛或含丙烯醛的气体进行催化气相氧化而长时间稳定地制备丙烯酸的方法。上述方法的特征在于控制反应，使得满足以下等式（1）和（2）：其中T0表示催化剂层入口中的丙烯醛或含丙烯醛的气体的温度; T1表示催化剂层的入口部的温度; T2表示催化剂层的出口部的温度。

3. 发明授权

US06800783B2 Method for the synthesis of aliphatic carboxylic acids from aldehydes 有权
标题翻译：从醛合成脂族羧酸的方法
公开(公告)号：US06800783B2
公开(公告)日：2004-10-05
申请号：US10204619
申请日：2002-09-05
申请人： Helmut Springer , Peter Lappe
发明人： Helmut Springer , Peter Lappe
IPC分类号： C07C51235
CPC分类号： C07C51/235 , Y02P20/582 , C07C53/126 , C07C53/124
摘要： The invention relates to a method for the synthesis of aliphatic carboxylic acids by the catalytic oxidation of aldehydes with oxygen, or oxygen-containing gas mixtures. Metals of groups 5 11 of the periodic table of elements, or the compounds thereof are used as catalyst, in amounts of up to 5 ppm, based upon the amount of aldehyde used.
摘要翻译：本发明涉及通过用氧或含氧气体混合物催化氧化醛来合成脂族羧酸的方法。基于元素周期表的第5组11的金属或其化合物，以所使用的醛的量为基准，最多可用量为5ppm。

4. 发明授权

US06310240B1 Vapor phase oxidation of acrolein to acrylic acid 失效
标题翻译：丙烯醛蒸气相氧化成丙烯酸
公开(公告)号：US06310240B1
公开(公告)日：2001-10-30
申请号：US09219944
申请日：1998-12-23
申请人： Rashmikant Maganlal Contractor , Mark William Andersen , Daniel Campos , Gerard Hecquet , Charlotte Pham , Michel Simon , Mireille Stojanovic , Roland Kotwica , Jean-Pierre Schirmann
发明人： Rashmikant Maganlal Contractor , Mark William Andersen , Daniel Campos , Gerard Hecquet , Charlotte Pham , Michel Simon , Mireille Stojanovic , Roland Kotwica , Jean-Pierre Schirmann
IPC分类号： C07C51235
CPC分类号： C07C51/16 , C07C57/04
摘要： An improved method for the selective vapor phase oxidation of acrolein to acrylic acid in a recirculating solids reactor system using a particulate molybdenum vanadate multimetal oxide as oxidant involving specific reactant concentrations (preferably 5 mol % to 30 mol % propylene, 0 to 20 mol % oxygen, 0 to 70 mol % water, and the remainder inert gas), solids particle size (20 to 300 micrometers), temperature (250 to 450° C.) and gas (1 to 15 seconds) and solids (2 to 60 seconds) residence times. Such a process leads to improved selectivity, conversion and solids conversion ratio.
摘要翻译：在循环固体反应器系统中使用钼酸钒钼多金属氧化物作为氧化剂的丙烯醛选择性气相氧化的改进方法，其涉及特定的反应物浓度（优选5mol％至30mol％的丙烯，0至20mol％的氧气，0至70mol％的水，剩余的惰性气体），固体颗粒尺寸（20-300微米），温度（250-450℃）和气体（1至15秒）和固体（2至60秒）停留时间这种方法导致提高的选择性，转化率和固体转化率。

5. 发明授权

US06774262B1 Method of novel noncatalytic organic synthesis 失效
标题翻译：新型非催化有机合成方法
公开(公告)号：US06774262B1
公开(公告)日：2004-08-10
申请号：US09659821
申请日：2000-09-11
申请人： Yutaka Ikushima , Osamu Sato , Kiyotaka Hatakeda
发明人： Yutaka Ikushima , Osamu Sato , Kiyotaka Hatakeda
IPC分类号： C07C51235
CPC分类号： C07C29/147 , C07C51/16 , Y02P20/544 , C07C63/06 , C07C29/14 , C07C33/22
摘要： The invention provides a method of increasing the reaction rate of an organic synthesis reaction by utilizing supply of OH− from water in the absence of catalyst without adding a basic catalyst in supercritical water or subcritical water of at least 350 ° C., and a method of generating alcohol and carboxylic acid with high reaction rate by performing a Cannizzaro reaction in the absence of catalyst without adding a basic catalyst in supercritical water, and to a method of synthesis of alcohol and carboxylic acid from an aldehyde in the absence of catalyst without adding a basic catalyst near the critical point (375 to 380 ° C., 22.5 to 25 MPa) of supercritical water.
摘要翻译：本发明提供了一种通过在不存在催化剂的情况下从水中提供OH而不增加至少350℃的超临界水或亚临界水中的碱性催化剂来提高有机合成反应的反应速率的方法，以及通过在不存在催化剂的情况下进行坎尼扎罗反应而不在超临界水中添加碱性催化剂的情况下以高反应速度生成醇和羧酸的方法，以及在不存在催化剂的情况下由醛合成醇和羧酸的方法在临界点附近（375〜380℃，22.5〜25MPa）的超临界水附近不添加碱性催化剂。

6. 发明授权

US06657080B2 Process for producing acrylic acid 失效
标题翻译：丙烯酸生产工艺
公开(公告)号：US06657080B2
公开(公告)日：2003-12-02
申请号：US09878421
申请日：2001-06-12
申请人： Hiromi Yunoki
发明人： Hiromi Yunoki
IPC分类号： C07C51235
CPC分类号： C07C51/252 , C07C57/04
摘要： The invention provides a process which, in producing acrylic acid through vapor-phase catalytic oxidation of acrolein-containing gas using a shell-and-tube type fixed bed reactor, can effectively inhibit occurrence of hot spots and produce acrylic acid at high yields. Said process is characterized by dividing each of the reaction tubes into at least three reaction zones in its axial direction, filling the first reaction zone closest to the gas inlet with a catalyst having a higher activity than that of the catalyst filling the adjacent, second reaction zone and filling the subsequent reaction zones with catalysts of different activity levels such that the catalytic activity successively rises from the second reaction zone toward the gas outlet side.
摘要翻译：本发明提供了一种通过使用壳管式固定床反应器通过气相催化氧化含丙烯醛气体来生产丙烯酸的方法，其可有效抑制热点的发生并以高产率生产丙烯酸。所述方法的特征在于将每个反应管在其轴向方向上分成至少三个反应区域，用最接近气体入口的第一反应区填充具有比填充相邻第二反应物的催化剂活性高的催化剂并用不同活性水平的催化剂填充随后的反应区，使得催化活性从第二反应区向气体出口侧依次升高。

7. 发明授权

US06664416B2 Process for producing (meth)acrylic acid 失效
公开(公告)号：US06664416B2
公开(公告)日：2003-12-16
申请号：US10118112
申请日：2002-04-06
申请人： Michio Tanimoto , Hiroto Kasuga
发明人： Michio Tanimoto , Hiroto Kasuga
IPC分类号： C07C51235
CPC分类号： C07C51/215 , C07C51/252 , C07C57/04
摘要： The present invention produces (meth)acrylic acid in a high yield in a process for producing (meth)acrylic acid by subjecting at least one member selected from the group consisting of (meth)acrolein, propane, and isobutane to catalytic gas phase oxidation with molecular oxygen or a molecular-oxygen-containing gas. In addition, the present invention makes it possible to produce (meth)acrylic acid in a high yield and stably for a long time. The present invention provides a process for producing (meth)acrylic acid by catalytic gas phase oxidation reaction, which is characterized by allowing a reaction gas to contain a reducible compound.

8. 发明授权

US06593494B2 Process for preparing carboxylic acids by oxidation of aldehydes 失效
公开(公告)号：US06593494B2
公开(公告)日：2003-07-15
申请号：US10107429
申请日：2002-03-28
申请人： Paul Alsters , Elisabeth Schmieder Van De Vondervoort
发明人： Paul Alsters , Elisabeth Schmieder Van De Vondervoort
IPC分类号： C07C51235
CPC分类号： C07C51/29 , C07C59/64
摘要： Process for the oxidation of aldehydes to the corresponding acids in which an aldehyde as substrate is oxidized to the corresponding acid in the presence of an equimolar amount, or a molar excess, of periodate, catalytic amounts of dichromate or CrO3, and in the presence of an acid in water, a water/solvent mixture or in a solvent at a temperature of −20° C. to +50° C.

9. 发明授权

US06476260B1 Method of producing aldehydes and carboxylic acids by oxidizing primary alcohols 失效
标题翻译：通过氧化伯醇生产醛和羧酸的方法
公开(公告)号：US06476260B1
公开(公告)日：2002-11-05
申请号：US09509640
申请日：2000-05-31
申请人： Albert Thomas Herrmann , Ernst Tönsen
发明人： Albert Thomas Herrmann , Ernst Tönsen
IPC分类号： C07C51235
CPC分类号： B01J23/644 , C07C45/38 , C07C45/84 , C07C51/235
摘要： The invention relates to a method for oxidizing primary alcohols in order to obtain aldehydes and/or carboxylic acids. The reaction takes place in the presence of a catalyst supported on aluminium oxides or aluminium silicates and containing palladium, platinum, cobalt, rhodium, ruthenium, iridium, rhenium, optionally with co-catalysts.
摘要翻译：本发明涉及氧化伯醇以获得醛和/或羧酸的方法。反应在负载在氧化铝或硅酸铝上的催化剂存在下进行，并且含有钯，铂，钴，铑，钌，铱，铼，任选与助催化剂。

10. 发明授权

US06737545B1 Multi-metal oxide compounds with a two-phase structure 失效
标题翻译：具有两相结构的多金属氧化物化合物
公开(公告)号：US06737545B1
公开(公告)日：2004-05-18
申请号：US09646884
申请日：2000-10-06
申请人： Hartmut Hibst , Signe Unverricht
发明人： Hartmut Hibst , Signe Unverricht
IPC分类号： C07C51235
CPC分类号： C01G30/02 , B01J23/002 , B01J23/8877 , B01J35/0006 , B01J2523/00 , C01G1/02 , C01P2006/12 , C07C51/252 , C07C57/04 , B01J2523/17 , B01J2523/53 , B01J2523/55 , B01J2523/68 , B01J2523/69
摘要： Multimetal oxide materials containing molybdenum, vanadium, antimony, one or more of the elements W, Nb, Ta, Cr and Ce and one or more of the elements Cu, Zn, Co, Fe, Cd, Mn, Mg, Ca, Sr and Ba and having a 2-component structure are used for the gas-phase catalytic oxidative preparation of acrylic acid.
摘要翻译：含有钼，钒，锑，元素W，Nb，Ta，Cr和Ce中的一种或多种的多金属氧化物材料以及一种或多种元素Cu，Zn，Co，Fe，Cd，Mn，Mg，Ca，Sr和具有2组分结构的Ba用于丙烯酸的气相催化氧化制备。

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