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1. 发明申请

US20030187308A1 PROCESS FOR SPLITTING WATER-SOLUBLE ETHERS 失效
标题翻译：分离水溶性物质的方法
公开(公告)号：US20030187308A1
公开(公告)日：2003-10-02
申请号：US10136083
申请日：2002-04-29
发明人： Thomas Haas , Christian Ronge , Torsten Hahm
IPC分类号： C07C029/141
CPC分类号： C07C29/10 , C07C29/141 , C07C2601/14 , C12C11/02 , C07C31/202 , C07C35/14 , C07C33/03 , C07C31/08 , C07C31/10 , C07C31/20 , C07C31/04 , C07C31/22 , C07C31/205
摘要： A process for production of 1,3-propanediol including the steps: (a) hydrating acrolein in the presence of an acid hydration catalyst; (b) catalytically hydrogenating the reaction mixture of step (a), which reaction mixture comprises 3-hydroxypropionaldehyde and is freed of unreacted acrolein; (c) refining the reaction mixture of step (b) containing water, 1,3-propanediol and the by-products boiling higher than 1,3-propanediol; and (d) treating 4-oxa-1,7-heptanediol to form 1,3-propanediol by (1) removing a boiler sump comprising 4-oxa-1,7-heptanediol from the refining step (c), (2) treating the boiler sump in an aqueous solution in the presence of an acid catalyst at about 200 to about 300null C. to form a solution comprising 1,3-propanediol, (3) neutralizing the solution obtained is step (2), and returning the neutralized solution from step (3) to the refining step (c). In addition, a process for splitting oligomeric water-soluble ether comprising: (a) treating an aqueous solution comprising oligomeric water-soluble ether in the presence of homogeneous acid catalyst at a temperature of from about 200 to about 300 null C. to form the monomer of the oligomeric water-soluble ether; and (b) neutralizing the solution obtained in step (a),
摘要翻译：一种制备1,3-丙二醇的方法，包括以下步骤：（a）在酸性水合催化剂存在下水合丙烯醛; （b）催化氢化步骤（a）的反应混合物，该反应混合物包含3-羟基丙醛，并且不含未反应的丙烯醛; （c）精制含有水，1,3-丙二醇和沸点高于1,3-丙二醇的副产物的步骤（b）的反应混合物; （d）通过（1）从精制步骤（c），（2）中除去包含4-氧杂-1,7-庚二醇的锅炉贮槽，处理4-氧杂-1,7-庚二醇以形成1,3-丙二醇，在约200〜约300℃的酸催化剂存在下，在水溶液中处理锅炉池，形成含有1,3-丙二醇的溶液，（3）中和所得溶液为步骤（2），并返回从步骤（3）到精制步骤（c）的中和溶液。另外，一种分解低聚水溶性醚的方法，包括：（a）在均聚酸催化剂存在下，在约200至约300℃的温度下处理包含低聚水溶性醚的水溶液，以形成低聚水溶性醚的单体; 和（b）中和步骤（a）中获得的溶液，

2. 发明申请

US20030069456A1 Process for preparing a 1,3-alkandiol from 3-hydroxyester 失效
公开(公告)号：US20030069456A1
公开(公告)日：2003-04-10
申请号：US10212671
申请日：2002-08-06
申请人： Samsung Electronics Co., Ltd. and
发明人： Byeong No Lee , In Sun Jung , Eun Joo Jang , Jung Ho Lee , Hyung Rok Kim , Yo Han Han
IPC分类号： C07C029/141 , B01J023/72
CPC分类号： B01J23/72 , B01J21/08 , B01J23/8892 , B01J37/0009 , B01J37/03 , B01J37/18 , C07C29/149 , C07C31/205
摘要： A process for preparing a 1,3-alkandiol from a 3-hydroxyester, comprises preparing a catalyst by adding an alkaline precipitator to an aqueous copper salt solution to form copper hydroxide particles, and aging the particles following the addition of a colloidal silica thereto; activating the catalyst by reduction with a H2 gas or a H2-containing gas and applying a pressure of about 5 psig to about 2000 psig at a temperature of about 100null C. to about 250null C. in the presence of an activation solvent; and hydrogenating a 3-hydroxyester in a liquid phase slurry with a H2 gas or a H2-containing gas and applying a pressure of about 50 psig to about 3000 psig at a temperature of about 100null C. to about 250null C. in the presence of the activated catalyst and a reaction solvent, whereby a 1,3-alkanediol can be selectively prepared from a 3-hydroxyester with a high yield.

3. 发明申请

US20030009062A1 Method for producing trimethylol alkanes 审中-公开
标题翻译：三羟甲基烷烃的制备方法
公开(公告)号：US20030009062A1
公开(公告)日：2003-01-09
申请号：US10181011
申请日：2002-07-12
发明人： Frank Dobert , Alexander Klausener , Paul Wagner
IPC分类号： C07C029/141 , C07C053/06
CPC分类号： C07C29/14 , C07C45/75 , C07C31/22 , C07C47/19
摘要： 1 The invention relates to a two-step method for producing trimethylol alkanes of the general formula (I), (HOCH2)3nullCnullR, wherein R represents methylol C1-C12 alkyl, C6-C10 aryl or C1-C22 aralkyl, and simultaneously producing calcium formiate on the basis of an aldehyde of the formula (II), RCH2CHO, wherein R has the meaning indicated above. In a first step, an aldehyde of the formula (II) and a formaldehyde are reacted in the presence of a base to give a 2,2-dimethylol alkanal of formula (III), wherein R has the meaning indicated above. In a second step, the compound of formula (III) is reacted with formaldehyde in the presence of calcium hydroxide. The invention provides a method for obtaining trimethylol alkanes of the general formula (I) with a high purity and in high yields.
摘要翻译：本发明涉及用于制备通式（I），（HOCH 2）3-CR的三羟甲基烷烃的两步法，其中R表示羟甲基C1-C12烷基，C6-C10芳基或C1-C22芳烷基，同时产生基于式（II）的醛，RCH 2 CHO，其中R具有上述含义。在第一步中，式（II）的醛和甲醛在碱的存在下反应，得到式（III）的2,2-二羟甲基亚烷基，其中R具有上述含义。在第二步中，式（III）化合物在氢氧化钙存在下与甲醛反应。本发明提供了一种以高纯度和高产率获得通式（I）的三羟甲基烷烃的方法

4. 发明申请

US20030114720A1 Method of producing saturated C3-C20-alcohols 有权
标题翻译：饱和C 3 -C 20醇的制备方法
公开(公告)号：US20030114720A1
公开(公告)日：2003-06-19
申请号：US10276219
申请日：2002-11-14
发明人： Herwig Hoffmann , Michael Roper , Heinrich-Josef Blankertz , Max Strohmeyer , Helmut Walz , Helmut Zinke-Allmang
IPC分类号： C07C029/141
CPC分类号： C07C29/141 , C07C31/12
摘要： The invention relates to a process for the preparation of saturated C3-C20-alcohols in which a liquid hydrogenation feed comprising at least one C3-C20-aldehyde is passed over a bed of a hydrogenation catalyst in the presence of a hydrogen-containing gas, which comprises adding to the hydrogenation feed an amount, homogeneously soluble therein, of a salt-like base. The addition of base suppresses side reactions, such as acetalization, aldolization, Tischtschenko reaction or ether formation.
摘要翻译：本发明涉及一种制备饱和C 3 -C 20醇的方法，其中包含至少一种C 3 -C 20醛的液体氢化进料在含氢气体存在下通过氢化催化剂床，其包括向氢化进料中加入其中均匀溶解的盐类碱的量。碱的添加抑制副反应，如缩醛化，醛醇缩合，Tischtschenko反应或醚形成。

5. 发明申请

US20030114719A1 Method for catalytic hydrogenation on rhenium-containing active carbon carrier catalysts 失效
标题翻译：用于含铼活性炭载体催化剂的催化氢化方法
公开(公告)号：US20030114719A1
公开(公告)日：2003-06-19
申请号：US10220566
申请日：2002-10-29
发明人： Rolf Hartmuth Fischer , Rolf Pinkos , Stephan Andreas Schunk , Joachim Wulff-Doring , Frank Stein , Thomas Nobel , Sylvia Huber
IPC分类号： C07C029/149 , C07C029/145 , C07C029/141
CPC分类号： C07C29/177 , B01J21/18 , B01J23/6567 , B01J23/8986 , C07C2601/20 , C07C31/207 , C07C31/20 , C07C31/133
摘要： In a process for preparing alcohols by catalytic hydrogenation of carbonyl compounds over a catalyst comprising rhenium on activated carbon, the catalyst used comprises rhenium (calculated as metal) in a weight ratio to the activated carbon of from 0.0001 to 0.5, platinum (calculated as metal) in a weight ratio to the activated carbon of from 0.0001 to 0.5 and, if appropriate, at least one further metal selected from among Zn, Cu, Ag, Au, Ni, Fe, Ru, Mn, Cr, Mo, W and V in a weight ratio to the activated carbon of from 0 to 0.25, and the activated carbon has been nonoxidatively pretreated It is also possible to prepare ethers and lactones if the hydrogen pressure is not more than 25 bar. In this case, the activated carbon in the catalyst may also have been nonoxidatively pretreated.
摘要翻译：在通过羰基化合物催化氢化羰基化合物的方法中，所用的催化剂包括铼在活性炭上的催化剂，所用的催化剂包括铼（以金属计）与活性炭的重量比为0.0001至0.5，铂（以金属计算），活性炭的重量比为0.0001〜0.5，如果合适，选自Zn，Cu，Ag，Au，Ni，Fe，Ru，Mn，Cr，Mo，W和V中的至少一种以上的金属活性炭的重量比为0至0.25，并且活性炭未经氧化预处理。如果氢气压力不超过25巴，也可制备醚和内酯。在这种情况下，催化剂中的活性炭也可以被非氧化预处理。

6. 发明申请

US20020169344A1 PROCESS FOR LACTOSE CONVERSION TO POLYOLS 有权
标题翻译：乳酸转化为多元醇的方法
公开(公告)号：US20020169344A1
公开(公告)日：2002-11-14
申请号：US09851678
申请日：2001-05-08
申请人： Battelle Memorial Institute
发明人： Douglas Charles Elliott
IPC分类号： C07C029/141
CPC分类号： C13K1/00 , C07B2200/09 , C07C29/00 , C07C29/141 , C12P19/02 , C13K13/00 , C07C31/202 , C07C31/205 , C07C31/225 , C07C31/26
摘要： A process for converting lactose into polyols that includes (a) hydrolyzing lactose to produce a hydrolyzate that includes at least one monosaccharide, (b) subsequently hydrogenating the hydrolyzate to produce an alditol-containing intermediate composition, and (c) hydrogenolyzing the alditol-containing intermediate composition to produce at least one polyol.
摘要翻译：一种将乳糖转化成多元醇的方法，其包括（a）水解乳糖以产生包含至少一种单糖的水解产物，（b）随后使所述水解产物加氢以产生含有醛糖醇的中间体组合物，和（c）将含有醛糖的中间体组合物以产生至少一种多元醇。

7. 发明申请

US20040002597A1 Catalytic process for the modification of carbohydrates, alcohols, aldehydes or polyhydroxy compounds 审中-公开
标题翻译：用于碳水化合物，醇，醛或多羟基化合物改性的催化方法
公开(公告)号：US20040002597A1
公开(公告)日：2004-01-01
申请号：US10340901
申请日：2003-01-10
申请人： SUDZUCKER AKTIENGESELLSCHAFT
发明人： Emine Capan , Marc Sascha Hahnlein , Ulf Prusse , Klaus-Dieter Vorlop , Alireza Haji Begli
IPC分类号： C07H005/06 , C07H005/04 , C07C051/235 , C07C029/141 , C07C29/26
CPC分类号： C07H7/033 , C07H7/027
摘要： The invention relates to the industrial conversion of carbohydrates, alcohols, aldehydes or polyhydroxy compounds in aqueous phase. According to the invention a catalytic method is used for the conversion, using a metal catalyst consisting of polymer-stabilized nanoparticles. A catalyst of this type is not deactivated by the conversion reaction as long as the stabilizing interaction between the polymer and the nanoparticles is maintained.
摘要翻译：本发明涉及碳水化合物，醇，醛或多羟基化合物在水相中的工业转化。根据本发明，使用由聚合物稳定的纳米颗粒组成的金属催化剂进行转化的催化方法。只要保持聚合物和纳米颗粒之间的稳定相互作用，这种类型的催化剂就不会通过转化反应失活。

8. 发明申请

US20030018224A1 High-purity 1,3-butylen glycol, process for producing 1,3-butylene glycol, and process for producing by -product butanol and butyl acetate 有权
公开(公告)号：US20030018224A1
公开(公告)日：2003-01-23
申请号：US09958129
申请日：2002-01-02
发明人： Yasuo Tsuji , Hiroaki Uenakai , Hiroshi Koyama
IPC分类号： C07C029/141
CPC分类号： C07C31/20 , C07C29/141 , C07C29/80 , C07C67/08 , C07C69/14 , C07C31/207
摘要： A first invention group is characterized by 1,3-butylene glycol which, at a period of three months after production, exhibits potassium permanganate color-fading time of at least five minutes as measured according to JIS K1351 3.10. A second invention group is characterized in that, when 1,3-butylene glycol is synthesized through hydrogenation of acetaldols in the presence of a catalyst, Raney nickel having an acetone hydrogenation activity of 2,000 ml/g-Ni/hr or more and/or a phenol hydrogenation activity of 500 ml/g-Ni/hr or more is used as the catalyst. A third invention group is characterized in that acetaldols obtained through condensation of acetaldehyde in the presence of a basic catalyst are hydrogenated in the presence of a hydrogenation catalyst and under an acidic condition. A fourth invention group is characterized in that acetaldols obtained through condensation of acetaldehyde in the presence of a basic catalyst is hydrogenated in the presence of a catalyst, to thereby synthesize 1,3-butylene glycol; a hydrogenation crude mixture is basified; alcohols are removed from the basified crude mixture; and 1,3-butylene glycol is obtained as a distillate and purified. A fifth invention group is characterized in that acetaldols are hydrogenated in the presence of a catalyst to thereby synthesize 1,3-butylene glycol; a hydrogenation crude mixture is subjected to distillation to thereby separate low-boiling-point components (L); the resultant mixture is further subjected to distillation to thereby yield 1,3-butylene glycol as a distillate; and the 1,3-butylene glycol distillate is treated with ozone. A sixth invention group is characterized in that, when acetaldols are synthesized from acetaldehyde and the acetaldols are hydrogenated in a hydrogenation step to thereby produce 1,3-butylene glycol; crotonaldehyde which is by-produced during synthesis of the acetaldols is hydrogenated together with acetaldols during the hydrogenation step, to thereby allow by-production of butanol; a butanol-containing distillate is separated from a 1,3-butylene glycol distillate through distillation; the butanol-containing distillate is subjected to distillation and a chemical treatment; and then the resultant distillate is further subjected to distillation to thereby separate low-boiling-point components and high-boiling-point components, thereby yielding butanol.

9. 发明申请

US20020183564A1 PROCESS FOR PRODUCING AN ALICYCLIC UNSATURATED ALCOHOL 失效
标题翻译：生产非水不饱和醇的方法
公开(公告)号：US20020183564A1
公开(公告)日：2002-12-05
申请号：US10160356
申请日：2002-05-30
发明人： Hiroto Tanigawa , Koichi Okumura , Masaya Uenoya , Kango Fujitani , Yoshihiro Kihara
IPC分类号： C07C029/141
CPC分类号： C07C29/141 , C07C33/22
摘要： An alicyclic unsaturated alcohol (for example, tetrahydrobenzyl alcohol) having the purity of 99% by weight or more, the water content of 0.1% by weight or less and the acid value of 0.1 mg KOH/g or less can be produced, with high selectivity, by hydrogenating using an unsaturated cyclic aldehyde having the acid value of 10 mg KOH/g or less as a raw material; terminating the hydrogenation in the conversion of 70 to 99.8%; and rectifying the reaction product containing the unreacted unsaturated cyclic aldehyde. The high purity alicyclic unsaturated alcohol is useful as raw material chemicals for synthesizing drugs, agricultural chemicals, perfumes, and dyes etc.
摘要翻译：可以制造纯度为99重量％以上，水分为0.1重量％以下，酸值为0.1mgKOH / g以下的脂环族不饱和醇（例如四氢苄醇），高选择性，通过使用酸值为10mg KOH / g以下的不饱和环醛作为原料进行氢化; 终止氢化转化率为70〜99.8％; 并对含有未反应的不饱和环醛的反应产物进行精馏。高纯度脂环族不饱和醇可用作合成药物，农药，香水和染料等的原料化学品。

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