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    • 5. 发明授权
    • Cementitious mixture containing high pozzolan cement replacement and compatabilizing admixtures therefor
    • 含有高火山灰水泥替代物的水泥混合物及其混合物
    • US06290770B1
    • 2001-09-18
    • US09371627
    • 1999-08-11
    • John MoreauRunhai LuJeffrey R. BuryThomas M. Vickers, Jr.
    • John MoreauRunhai LuJeffrey R. BuryThomas M. Vickers, Jr.
    • C04B713
    • C04B28/04C04B24/165C04B24/243C04B24/2658C04B24/267C04B24/2694C04B40/0039C04B2111/1062Y02W30/92Y02W30/94C04B14/10C04B14/106C04B14/14C04B18/08C04B18/141C04B18/146C04B2103/10C04B2103/408C04B2103/0088C04B2103/302
    • A cementitious mixture comprises a hydraulic cement; greater than about 10% by weight of a pozzolanic cement replacement selected from fly ash, slag, natural pozzolans, and mixtures thereof, based on the weight of said hydraulic cement and cement replacement; and a compatabilizing admixture, wherein the compatabilizing admixture comprises a compatabilizing derivatized polycarboxylate polymer dispersant capable of acting as a water reducer, in combination with an accelerator. The derivatized polycarboxylate dispersant, alone or in combination with other derivatized polycarboxylate dispersants, is a polymer comprising units derived from at least one of a substituted carboxylic acid monomer and a substituted ethylenically unsaturated monomer, at least one of an N-polyoxyalkylene maleimide and a condensation product of an unsubstituted carboxylic acid monomer and an alkoxypolyoxyalkylene primary amine substituted carboxylic acid monomer, and optionally including an unsaturated hydrocarbon. The derivatized polycarboxylate dispersant provides for a longer shelf life dispersant, improved dispersability of cementitious mixtures, water reduction in cementitious mixtures, and is an effective dispersant in high pozzolan replaced cementitious mixtures.
    • 水泥混合物包括水硬性水泥; 基于所述水硬性水泥和水泥替代物的重量,大于约10重量%的火山灰水泥替代物,其选自飞灰,矿渣,天然火山灰及其混合物; 和一种可配制的混合物,其中所述配混的混合物包括与促进剂组合的能够用作减水剂的可衍生的衍生的聚羧酸酯聚合物分散剂。 衍生化的聚羧酸酯分散剂单独或与其它衍生化的聚羧酸酯分散剂组合是包含衍生自取代的羧酸单体和取代的烯键式不饱和单体中的至少一种的单体的聚合物,N-聚氧化烯马来酰亚胺和缩合物中的至少一种 未取代的羧酸单体和烷氧基聚氧化烯伯胺取代的羧酸单体的产物,并且任选地包括不饱和烃。 衍生化的聚羧酸酯分散剂提供更长的保质期分散剂,改善水泥混合物的分散性,水泥混合物中的水分降解,并且是高火山灰替代水泥混合物中的有效分散剂。