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    • 4. 发明申请
    • Method for preparing a pearlescent pigment by coating metal oxides on the synthesized mica
    • 通过在合成云母上涂覆金属氧化物来制备珠光颜料的方法
    • US20040096579A1
    • 2004-05-20
    • US10398814
    • 2003-04-09
    • Chang Kil-WanKwang-su Lim
    • C04B014/20B05D007/00
    • C09C1/0021C01P2004/61C09C1/0015C09C2200/102C09C2220/106
    • Disclosed is a method for preparing a pearlescent pigment by coating metal oxides on the synthesized mica, involving the steps of grinding the synthesized mica by agitating the mica with water in a water mixer to a particle size between 100 and 500 nullm and separating the mica, dispersing the separated particles of the synthesized mica in water and adding acid thereto to adjust pH between 1 and 4, adding the metal oxide precursors and a basic aqueous solution thereto while maintaining said pH range until the desired color is attained, and thereby forming at least one hydrous metal oxide layer on the particles of the synthesized mica, and filtering, water-washing, drying and calcining the synthesized mica coated with the metal oxide layer. The method may further involve the step of further pulverizing the synthesized mica roughly ground in a water mixer by using a conventional wet pulverizer so that less than 100 nullm of the synthesized mica may be used as a base material. The suitable surfactants can be used in a water mixer as well as a conventional wet pulverizer. The pearlescent pigment prepared according to the present invention has excellent luster and chroma, since a coating layer of metal oxides is smooth and the dispersibility of the particles is excellent.
    • 公开了一种通过在合成云母上涂覆金属氧化物来制备珠光颜料的方法,包括通过在水混合器中用水搅拌云母来研磨合成云母的步骤至粒径在100-500μm之间并分离云母, 将合成的云母的分离颗粒分散在水中并加入酸以调节pH在1和4之间,在保持所述pH范围直到获得所需颜色的同时加入金属氧化物前体和碱性水溶液,从而形成至少 在合成云母的颗粒上的一个含水金属氧化物层,并且对涂覆有金属氧化物层的合成云母进行过滤,水洗,干燥和煅烧。 该方法可以进一步包括通过使用常规的湿式粉碎机在水混合器中进一步粉碎合成云母的步骤,使得可以使用小于100μm的合成云母作为基材。 合适的表面活性剂可以用于水混合器以及常规的湿式粉碎机中。 根据本发明制备的珠光颜料具有优异的光泽和色度,因为金属氧化物的涂层是光滑的并且颗粒的分散性优异。
    • 6. 发明申请
    • After coating of pearl luster pigments with hydrophobic coupling reagents
    • 用疏水性偶联剂涂覆珍珠光泽颜料后,
    • US20020096087A1
    • 2002-07-25
    • US09985942
    • 2001-11-06
    • Ralf Glausch
    • C04B014/20
    • C09C1/0015C01P2004/84
    • The present invention relates to a pearl luster pigment on the basis of a platelet-shaped substrate coated with metal oxides and a top layer which is located on the metal oxide layer and can possess a multilayer structure, comprising a first layer, containing a hydroxide or oxide hydrate of the elements aluminum or silicon, a second layer, containing at least one hydroxide or oxide hydrate of the elements aluminum, silicon, cerium or zirconium, with the exception of the hydroxide or oxide hydrate which forms the first layer, and a third layer, containing at least one organic hydrophobic coupling agent. The present invention also relates to a preparation process and the use of pigments in paints, inks, plastics, coatings and cosmetics.
    • 本发明涉及一种基于涂覆有金属氧化物的片状基材和位于金属氧化物层上并可具有多层结构的顶层的珍珠光泽颜料,其包含第一层,其含有氢氧化物或 除了形成第一层的氢氧化物或氧化物水合物之外,元素铝或硅的氧化物水合物是含有元素铝,硅,铈或锆的至少一种氢氧化物或氧化物水合物的第二层,以及第三层 层,含有至少一种有机疏水偶联剂。 本发明还涉及颜料在油漆,油墨,塑料,涂料和化妆品中的制备方法和用途。
    • 10. 发明申请
    • Pigment materials and their use in coating compositions
    • 颜料材料及其在涂料组合物中的应用
    • US20020035949A1
    • 2002-03-28
    • US09908565
    • 2001-07-20
    • Imerys Minerals, Ltd.
    • Anthony Gordon HiornsJanet Susan PrestonJames Philip Eynon Jones
    • C04B014/20C04B014/10C09C001/02C09C001/36
    • D21H19/38D21H19/385D21H19/40D21H19/42D21H19/82D21H21/52G03G7/0013
    • A pigment material for use in a coating composition suitable for coating a sheet material to be printed by an electrophotographic printer which pigment material comprises a blend of Components A and B as follows: Component A: a fine pigment material suitable for gloss coating of a sheet material the pigment material comprising particles at least 80% by weight of which have an equivalent spherical diameter (nullesdnull) of less than 2 nullm and having a particle size distribution (nullpsdnull) such that its d50 value, namely the particle esd value less than which 50% of the particles have an esd, is less than 1 nullm; and Component B: a coarse pigment material having a psd such that its d50 value is from 2 nullm to 10 nullm, desirably 2 nullm to 5 nullm and such that not more than 2% by weight of the particles of the coarse pigment material have an esd greater than 15 nullm, desirably not more than 2% have an esd greater than 10 nullm; wherein the weight ratio of Component A to Component B is at least 4:1.
    • 一种用于涂料组合物中的颜料,其适用于通过电子照相打印机涂覆要印刷的片材的颜料,其包含如下组分A和B的共混物:组分A:适用于片材的光泽涂布的细颜料 材料包含颗粒的颜料材料的至少80重量%具有小于2μm的等效球形直径(“esd”)并且具有粒度分布(“psd”),使得其d 50值即颗粒esd 小于50%的颗粒具有esd的值小于1um; 和组分B:具有psd的粗颜料材料,使得其d50值为2μm至10μm,理想的为2μm至5μm,并且使不大于2重量%的粗颜料材料的颗粒具有 esd大于15 mum,理想不超过2%,esd大于10 mum; 其中组分A与组分B的重量比为至少4:1。