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    • 3. 发明授权
    • Process for preparing magnesium nitrate hexahydrate and for thermally
stabilizing ammonium nitrate using magnesium nitrate hexahydrate
    • 硝酸六水合物的制备方法,并使用硝酸镁六水合物热稳定硝酸铵
    • US4438083A
    • 1984-03-20
    • US418547
    • 1982-09-15
    • Michael H. WillemsWinfried J. W. Vermijs
    • Michael H. WillemsWinfried J. W. Vermijs
    • C01C1/18C01F5/38C05C1/02C01F11/14
    • C01C1/18C01C1/185C01F5/38C05C1/02C01P2006/12
    • Process for preparing magnesium nitrate hexahydrate without the need for filtering aids. A process for preparing magnesium nitrate hexahydrate essentially comprises: (a) forming a magnesium oxide or magnesium carbonate suspension in melted magnesium nitrate hexahydrate at a suspension temperature in excess of 90.degree. C.; (b) adding a nitric acid solution to the suspension while stirring thereby forming a reaction mixture containing additional magnesium nitrate hexahydrate; (c) filtering the liquid reaction mixture to obtain a clear magnesium nitrate hexahydrate filtrate; (d) discharging as product a part, corresponding to the amount of magnesium oxide or magnesium carbonate introduced, of the liquid magnesium nitrate hexahydrate obtained as clear filtrate; (e) utilizing the remaining part as liquid medium for the conversion of magnesium oxide or magnesium carbonate with nitric acid. Thermally stabilized ammonium nitrate containing granules may also be prepared containing magnesium nitrate hexahydrate according to the above process.
    • 制备硝酸镁六水合物的方法,无需过滤助剂。 制备硝酸镁六水合物的方法主要包括:(a)在熔融的硝酸镁六水合物中在悬浮温度超过90℃下形成氧化镁或碳酸镁悬浮液。 (b)在搅拌下向该悬浮液中加入硝酸溶液,形成含有另外的硝酸镁六水合物的反应混合物; (c)过滤液体反应混合物,得到透明的硝酸镁六水合物滤液; (d)将作为透明滤液得到的液体硝酸镁六水合物的一部分相当于导入的氧化镁或碳酸镁的量排出的部分; (e)利用剩余部分作为液体介质,用于将氧化镁或碳酸镁与硝酸转化。 根据上述方法,还可以制备含有水合硝酸铵的颗粒,其含有六水合硝酸镁。