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    • 1. 发明授权
    • Process for forming direct positive color image
    • 形成直接正彩色图像的过程
    • US4933265A
    • 1990-06-12
    • US317142
    • 1989-02-23
    • Noriyuki InoueTatsuo HekiTetsuro KojimaShinji Ueda
    • Noriyuki InoueTatsuo HekiTetsuro KojimaShinji Ueda
    • C07D235/28C07D249/12C07D263/58C07D285/12C07D285/125C07D285/135C07D521/00G03C1/485G03C7/392G03C7/413
    • C07D263/58C07D231/12C07D233/56C07D235/28C07D249/08C07D249/12C07D285/125C07D285/135G03C1/48546G03C7/3924G03C7/413
    • A process for forming a direct positive color image is disclosed, the process comprising imagewise exposing a photosensitive material containing at least one emulsion layer of silver halide of internal latent image type, which has not been preliminarily fogged, and a color image-forming coupler; developing said material using a surface developing solution containing an aromatic primary amine color developing agent in the presence of a nucleating agent and/or in the condition that fogging exposure is carried out prior to the developing step or during the developing step; bleaching; and fixing, wherein said color coupler is a compound which is in itself substantially nondiffusible, and capable of forming or releasing a substantially nondiffusible dye upon oxidative coupling with said aromatic primary amine color developing agent and said development processing is carried out at a pH of 11.5 or less using a developing solution containing substantially no benzyl alcohol in the presence of at least one compound selected from the group consisting of the compounds represented by the general formula (I)A[(Y.sup.1).sub.n R].sub.m
    • 公开了一种用于形成直接正彩色图像的方法,该方法包括成像曝光含有至少一种尚未预先雾化的内部潜像型卤化银乳剂层的感光材料和彩色成像耦合器; 在成核剂存在下和/或在显影步骤之前或显影步骤中进行雾化曝光的条件下,使用含有芳族伯胺彩色显影剂的表面显影溶液显影所述材料; 漂; 和固定,其中所述着色剂是本身基本上不可扩散的化合物,并且能够在与所述芳族伯胺显色剂氧化偶联时形成或释放基本上不可扩散的染料,并且所述显影处理在pH为11.5的条件下进行 或更少使用在至少一种选自由通式(I)A [(Y1)nR] m表示的化合物组成的组的存在下,基本上不含苄醇的显影溶液
    • 4. 发明授权
    • Direct positive silver halide emulsions through synergistic effects of fogging agents and organic reducing agents and/or their oxidized forms
    • 通过挥发性有机物和有机还原剂和/或其氧化形式的协同作用产生直接阳性银盐乳化剂
    • US3816135A
    • 1974-06-11
    • US23973472
    • 1972-03-30
    • DU PONT
    • HUNT H
    • G03C7/00G03C1/485G03C5/24G03C1/28
    • G03C1/48546
    • High-speed direct positive silver halide emulsions characterized by improved densities and highlights are prepared containing a combination of a strong inorganic chemical fogging agent and an organic reducing agent and/or its oxidized form taken from the group consisting of methyl-p-aminophenol (metol), hydroquinone, quinone, quinhydrone, 1,4-naphthalenediol and 1,5naphthalenediol, and an alkali metal sulfite, said combination being in an inert environment where it is unable to cause the formation of chemical fog centers or sensitivity centers on the silver halide grain surfaces before exposure and processing. Such an environment can be established by adjusting the pH range between 4.9 and 6.5.
    • 制备特征在于改善的密度和亮度的高速直接正卤化银乳剂,其含有强无机化学起雾剂和有机还原剂的组合和/或其氧化形式,其取自甲基对氨基苯酚(metol ),氢醌,醌,醌氢醌,1,4-萘二醇和1,5-萘二醇,以及碱金属亚硫酸盐,所述组合处于惰性环境中,其不能在所述惰性环境中形成化学雾中心或敏感性中心 曝光和加工前的卤化银颗粒表面。 这种环境可以通过调节4.9至6.5之间的pH范围来建立。
    • 5. 发明授权
    • Method for forming a direct positive image from a material comprising a
nucleation accelerator
    • 从包含成核促进剂的材料形成直接正像的方法
    • US5037726A
    • 1991-08-06
    • US280904
    • 1988-12-07
    • Tetsuro KojimaNoriyuki Inoue
    • Tetsuro KojimaNoriyuki Inoue
    • G03C1/485
    • G03C1/48546Y10S430/141
    • A method for forming a direct positive image having a high Dmax and a low Dmin, which comprises image-wise exposing a photographic light-sensitive material having on a support at least one photographic emulsion layer containing unprefogged internal latent image-type silver halide grains and developing the photographic light-sensitive material after or while fogging to form direct positive image, wherein the aforesaid development is performed in the existence of at least one compound selected from the group consisting of compounds represented by formula (I), (II), (III), (IV), (V) or (VI), acid salts of compounds represented by formula (I) to (IV) provided substituents thereof contain an amino group, and acid salts of compound represented by formula (V) or (VI); ##STR1## wherein symbols are defined as in claim 1.
    • 一种用于形成具有高Dmax和低Dmin的直接正像的方法,该方法包括以下步骤:成像曝光具有载体的照相感光材料,所述照相感光材料至少含有未研磨的内部潜像型卤化银颗粒的照相乳剂层和 在雾化之后或同时显影照相感光材料以形成直接正像,其中上述显影是在存在至少一种选自由式(I),(II),(II),(II) III),(Ⅳ),(Ⅴ)或(Ⅵ)所示,由式(I)至(Ⅳ)表示的化合物的酸盐提供的取代基含有氨基,式(Ⅴ)或 六); (VI)其中符号如权利要求1中所定义,其中符号被定义为如图1所示。
    • 6. 发明授权
    • Method for forming a direct positive image
    • 形成直接正像的方法
    • US4968596A
    • 1990-11-06
    • US266605
    • 1988-11-02
    • Noriyuki InoueShigeo HiranoTetsuro KojimaMitsura YamamotoSatoshi Nagaoka
    • Noriyuki InoueShigeo HiranoTetsuro KojimaMitsura YamamotoSatoshi Nagaoka
    • G03C1/485
    • G03C1/48546Y10S430/141
    • A method for forming a direct positive image comprising the steps of:(a) imagewise exposing a photographic light-sensitive material composed of a support having thereon at least one unprefogged internal latent image type silver halide light-sensitive emulsion layer; and(b) developing the exposed photographic light-sensitive material to form a direct positive image in the presence of at least one nucleating agent represented by formula (N-I); ##STR1## wherein Z.sup.1 represents nonmetal atomic group necessary for forming a 5-membered or 6-membered heterocyclic ring, a 5-membered or 6-membered heterocyclic ring fused with an aromatic ring, or a 5-membered or 6-member heterocyclic ring fused with another heterocyclic ring; R.sup.1 represents an aliphatic group; X represents ##STR2## Q represents a nonmetallic atomic group necessary for forming a 4-membered to 12-membered nonaromatic hydrocarbon ring or a 4-membered to 12-membered nonaromatic heterocyclic ring; provided that at least one of R.sup.1, Z.sup.1 and Q is substituted with an alkynyl group; Y represents a counter ion required for charge balance; and n is a number required for charge balance; or Z.sup.1 contains a heterocyclic quaternary ammonium salt completed by said Z.sup.1 via a linkage group.
    • 一种用于形成直接正像的方法,包括以下步骤:(a)成像曝光由其上具有至少一个未反光内部潜像型卤化银感光乳剂层的支撑体组成的照相感光材料; 和(b)在存在由式(N-I)表示的至少一种成核剂的情况下,显影曝光的照相感光材料以形成直接正像; (NI)其中Z1表示形成5元或6元杂环所需的非金属原子团,与芳环稠合的5元或6元杂环,或5元或6元杂环, 与另一个杂环稠合的杂环; R1表示脂肪族基团; X表示形成4元〜12元非芳香烃环或4元〜12元非芳香族杂环所必需的非金属原子团; 条件是R1,Z1和Q中的至少一个被炔基取代; Y表示电荷平衡所需的抗衡离子; n是电荷平衡所需的数字; 或Z 1包含通过连接基团由所述Z1完成的杂环季铵盐。