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    • 1. 发明授权
    • Current balancing circuit for use with chromatographic system detector
    • 用于色谱系统检测器的电流平衡电路
    • US4068185A
    • 1978-01-10
    • US662768
    • 1976-03-01
    • Urs ChristenRichard M. Commins
    • Urs ChristenRichard M. Commins
    • G01N30/86H03G3/20H03F1/34
    • H03G3/001G01N30/8613H03G3/30G01N2030/626
    • An improvement is disclosed for use in a chromatographic system of the type including detector means providing a detector output signal indicative of the level of a component sought to be determined, detector output amplifier means for receiving the signal, an error signal balancing loop connected to the amplifier output to provide a balancing signal in feedback relationship to the amplifier, and means for adjusting the sensitivity range of the amplifier. The improvement, which enables adjustment of the error signal through the feedback loop, comprises control means connected in the feedback loop for varying the sensitivity range of the amplifier in accordance with a desired mode of system operation, the control means providing a bit correction pattern for feeding into the feedback loop in accordance with the output signal of the amplifier; digital-to-analog conversion means in the loop for converting the bit stream pattern to a first resolution level; and resistor network and switching means in the feedback loop for further resolving the error signal output from the digital-to-analog conversion means, and providing the further resolved signal in feedback relationship to the amplifier to effect balancing of same.
    • 公开了一种用于这种类型的色谱系统的改进,所述色谱系统包括提供检测器输出信号的检测器装置,所述检测器输出信号指示寻求确定的成分的电平,用于接收信号的检测器输出放大器装置,连接到 放大器输出以提供与放大器的反馈关系的平衡信号,以及用于调整放大器的灵敏度范围的装置。 能够通过反馈回路调整误差信号的改进包括连接在反馈回路中的控制装置,用于根据期望的系统操作模式改变放大器的灵敏度范围,该控制装置为 根据放大器的输出信号馈入反馈回路; 用于将比特流模式转换为第一分辨率级别的循环中的数模转换装置; 以及反馈环路中的电阻网络和开关装置,用于进一步分辨从数模转换装置输出的误差信号,并且将放大器的反馈关系中进一步解析的信号提供给放大器以实现其平衡。
    • 9. 发明授权
    • Method of and device for the identification and reduction of peaks in chromatograms
    • 用于鉴定和降低色谱图峰值的方法和装置
    • US3898837A
    • 1975-08-12
    • US39790773
    • 1973-09-17
    • BOEGE DIETRICH A H
    • BOEGE DIETRICH A H
    • G01N30/86G01N31/08
    • G01N30/8675G01N30/8613G01N30/8668
    • In measuring the signal peaks caused by unknown samples in, for example, the detector outputs of gas chromatographs, the peak signals are identified as to the unknown sample components by comparing their time of occurrence (the retention times of the sample components) to the times of occurrence of known components from a previously run known sample. The peak signals are then integrated to find their areas and each peak area is multiplied by a different stored calibration factor, in accordance with (the reciprocal of) the sensitivity of the detector to each particular sample component. Rather than determining whether the unknown sample components have a retention time within a tolerance range about the respective retention times of previously run known sample components as done in the past, the present technique uses the criterion of whether any part of the unknown peak has the same time of occurrence as the center of the known sample peak. In this manner, the effective tolerance range of the respective retention times is determined by the width of the unknown sample peak, so that the tolerance range is automatically compensated in accordance with the chromatographic operating conditions and inherent characteristics of the sample component, which affect the broadening of peaks.
    • 在测量由例如气相色谱仪的检测器输出中的未知样品引起的信号峰时,通过将其出现时间(样品组分的保留时间)与时间 从已经运行的已知样品的已知组分的发生。 然后,根据检测器对每个特定样品组分的灵敏度(的倒数),峰值信号被积分以找到它们的区域,并且每个峰面积乘以不同的存储校准因子。 不是确定未知样品组分的保留时间是否在相对于先前运行的已知样品组分的相应保留时间的公差范围内,如本文所述,本技术使用的是未知峰的任何部分是否相同的标准 发生时间作为已知样品峰的中心。 以这种方式,各个保留时间的有效容限范围由未知样品峰的宽度确定,从而根据色谱操作条件和样品成分的固有特性自动补偿公差范围,影响其 拓宽峰值。