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    • 1. 发明授权
    • Lead-based solders for high temperature applications
    • 用于高温应用的铅基焊料
    • US6059900A
    • 2000-05-09
    • US25638
    • 1998-02-18
    • Frank W. GayleJames A. Slattery
    • Frank W. GayleJames A. Slattery
    • B23K35/26C22C11/02C22C7/00
    • B23K35/268C22C11/02
    • A high lead solder exhibiting improved wettability to metal substrates, an advantageously controlled melting range, and excellent thermal fatigue properties. It comprises about 98-100% lead and a minor amount, typically about 0.0005-0.1 wt %, based on the total weight of the solder composition, of an alkali metal selected from the group consisting of Na, K, and Li. Additional embodiments additionally comprise an amount of a grain-size controlling additive, e.g., 0.001-0.5 wt % (based on the total weight of all the components in the solder composition) selected from the group consisting of Ce, Ba, La, Pr, Nd, Sm, Eu, Gd, Th, Dy, Ho, Er, Tm, Yb, Y, Lu, Sc, Mg, Na, Se, Te, oxides thereof and mixtures thereof, in amount effective to control the Pb grain size; and 0-1 wt % of an element selected from the group consisting of Sn, In, Bi, Sb, Ag, Au, and Ga, and mixtures thereof.
    • 表现出对金属基材的润湿性提高的高铅焊料,有利的受控熔融范围以及优异的热疲劳特性。 它包括约98-100%的铅和少量的,基于焊料组合物的总重量,通常约0.0005-0.1重量%的选自Na,K和Li的碱金属。 另外的实施方案另外包括一定量的粒度控制添加剂,例如0.001-0.5wt%(基于焊料组合物中所有组分的总重量),其选自Ce,Ba,La,Pr, Nd,Sm,Eu,Gd,Th,Dy,Ho,Er,Tm,Yb,Y,Lu,Sc,Mg,Na,Se,Te,其氧化物及其混合物, 和0-1重量%的选自Sn,In,Bi,Sb,Ag,Au和Ga的元素,以及它们的混合物。
    • 4. 发明授权
    • Method and apparatus for casting anodes
    • 铸造阳极的方法和装置
    • US4124482A
    • 1978-11-07
    • US816101
    • 1977-07-15
    • Bill J. Knight
    • Bill J. Knight
    • C22C11/00B22D25/04C22C11/02C25C7/02C25C1/12
    • C22C11/02B22D25/04C22C11/00
    • A method for casting an insoluble anode for use in the electrowinning of copper, the anode being formed by casting molten lead alloy preferably including calcium as an alloying agent in a suitable mold necessary flow of the molten alloy being minimized within the mold, the temperature of the molten alloy and the temperature of the mold being selected to minimize the time necessary for solidification of the molten alloy within the mold, the lead alloy anode preferably being removed from the mold substantially as soon as it is mechanically self-supporting and rapidly cooling the anode in an unstressed configuration to freeze its grain structure and develop dimensional stability. The present invention also relates to a lead alloy casting produced by the above method as well as to an insoluble anode formed from a lead alloy including calcium as an alloying agent, the anode being characterized by the uniform precipitate distribution illustrated in FIG. 7 and the surface finish illustrated in FIG. 9.
    • 一种用于铸造用于铜的电解冶金的不溶性阳极的方法,阳极通过将熔融铅合金优选地包括作为合金剂的钙浇铸而形成,所述合金化合金在合适的模具中,熔融合金的必要流动在模具内最小化, 熔融合金和模具的温度被选择以最小化熔融合金在模具内固化所需的时间,铅合金阳极优选地从模具中移除,基本上一旦机械自支撑并迅速冷却 阳极处于不受压力的构型以冻结其晶粒结构并显现尺寸稳定性。 本发明还涉及通过上述方法制造的铅合金铸件以及由包含钙作为合金剂的铅合金形成的不溶性阳极,阳极的特征在于均匀的沉淀物分布如图1所示。 7和表面处理如图7所示。 9。