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1. 发明授权

US09679672B2 Low band gap conjugated polymeric compositions and applications thereof 有权
公开(公告)号：US09679672B2
公开(公告)日：2017-06-13
申请号：US14394198
申请日：2013-04-12
申请人： WAKE FOREST UNIVERSITY
发明人： Nicole Levi , David L. Carroll , Christopher MacNeill , Elizabeth Graham
IPC分类号： H01B1/12 , H01L51/00 , C08F126/06 , C08F28/06 , A61K41/00 , A61K47/48 , C08G61/12 , C08L65/00 , A61N5/06 , A61N7/00
CPC分类号： H01B1/127 , A61K41/0052 , A61K47/59 , A61N5/062 , A61N7/00 , A61N2005/0659 , C08F28/06 , C08F126/06 , C08G61/123 , C08G61/126 , C08G2261/124 , C08G2261/1412 , C08G2261/3229 , C08G2261/323 , C08G2261/3243 , C08G2261/3245 , C08G2261/3246 , C08G2261/3247 , C08G2261/414 , C08G2261/90 , C08L65/00 , H01L51/0043
摘要： In one aspect, electrically conductive conjugated polymeric compositions are described herein demonstrating compatibility with aqueous solvents and/or phases. The ability to provide aqueous compatible compositions from previously water insoluble conjugated polymeric systems, in some embodiments, can facilitate use of such systems in a variety of aqueous applications, including biological applications.

2. 发明授权

US09472693B2 Solar cell and method for manufacturing the same 有权
标题翻译：太阳能电池及其制造方法
公开(公告)号：US09472693B2
公开(公告)日：2016-10-18
申请号：US13777621
申请日：2013-02-26
申请人： Samsung Electronics Co., Ltd.
发明人： Soo-Ghang Ihn , Kilwon Cho , Yeong Suk Choi , Sae Byeok Jo , Heung Gyu Kim , Myungsun Sim
IPC分类号： H01L31/0216 , H01L31/18 , H01L51/42 , H01L51/44 , H01L51/00
CPC分类号： H01L31/02167 , C08G2261/124 , C08G2261/1412 , C08G2261/1414 , C08G2261/1424 , C08G2261/143 , C08G2261/148 , C08G2261/3142 , C08G2261/3223 , C08G2261/3229 , C08G2261/3243 , C08G2261/344 , C08G2261/91 , H01L51/0036 , H01L51/0043 , H01L51/4253 , H01L51/4273 , H01L51/445 , H01L2251/308 , Y02E10/549 , Y02P70/521
摘要： A solar cell includes a first electrode, a second electrode facing the first electrode, a photoactive layer between the first electrode and the second electrode and including an electron donor and an electron acceptor, and a partially oxidized metal thin film between the first electrode and the photoactive layer.
摘要翻译：太阳能电池包括第一电极，面对第一电极的第二电极，第一电极和第二电极之间的光活性层，并且包括电子给体和电子受体，以及在第一电极和第二电极之间的部分氧化的金属薄膜光敏层。

3. 发明申请

US20130200336A1 METHOD FOR PRODUCING AN ORGANIC SEMICONDUCTOR DEVICE 有权
标题翻译：用于生产有机半导体器件的方法
公开(公告)号：US20130200336A1
公开(公告)日：2013-08-08
申请号：US13365673
申请日：2012-02-03
申请人： Subramanian VAIDYANATHAN , Marcel Kastler , Bertha Tan , Mi Zhou
发明人： Subramanian VAIDYANATHAN , Marcel Kastler , Bertha Tan , Mi Zhou
IPC分类号： H01L51/30 , H01L51/40
CPC分类号： C08G61/126 , C08G2261/124 , C08G2261/1412 , C08G2261/146 , C08G2261/312 , C08G2261/3223 , C08G2261/3229 , C08G2261/3246 , C08G2261/3327 , C08G2261/334 , C08G2261/344 , C08G2261/364 , C08G2261/414 , C08G2261/51 , C08G2261/92 , H01L51/0036 , H01L51/0043 , H01L51/0558
摘要： A method for producing an organic semiconductor device (110) having at least one organic semiconducting material (122) and at least two electrodes (114) adapted to support an electric charge carrier transport through the organic semiconducting material (122) is disclosed. The organic semiconducting material (122) intrinsically has ambipolar semiconducting properties. The method comprises at least one step of generating at least one intermediate layer (120) which at least partially is interposed between the organic semiconducting material (122) and at least one of the electrodes (114) of the organic semiconductor device (110). The intermediate layer (120) comprises at least one thiol compound having the general formula HS—R, wherein R is an organic residue. The thiol compound has an electric dipole moment pointing away from the SH-group of the thiol compound. The electric dipole moment has at least the same magnitude as the electric dipole moment in 4-Phenylthiophenol. By the intermediate layer (120) an ambipolar charge carrier transport between the electrodes (114) is suppressed in favor of a unipolar charge carrier transport.
摘要翻译：公开了一种用于制造具有至少一种有机半导体材料（122）和至少两个电极（114）的有机半导体器件（110）的方法，所述至少两个电极（114）适于支持通过有机半导体材料（122）传输的电荷载流子。有机半导体材料（122）本身具有双极性半导体性质。所述方法包括产生至少一个中间层（120）的至少一个步骤，所述中间层至少部分地介于有机半导体材料（122）和有机半导体器件（110）的至少一个电极（114）之间。中间层（120）包含至少一种具有通式HS-R的硫醇化合物，其中R是有机残基。硫醇化合物具有指向远离硫醇化合物的SH基团的电偶极矩。电偶极矩与4-苯基苯硫酚中的电偶极矩至少相同。通过中间层（120），电极（114）之间的双极电荷载流子传输被抑制以有利于单极电荷载流子传输。

4. 发明申请

US20130170102A1 ELECTROLYTIC MATERIAL FORMULATION, ELECTROLYTIC MATERIAL POLYMER FORMED THEREFROM AND USE THEREOF 有权
标题翻译：电解材料配方，其形成的电解材料聚合物及其用途
公开(公告)号：US20130170102A1
公开(公告)日：2013-07-04
申请号：US13478997
申请日：2012-05-23
申请人： Shinn-Horng Chen
发明人： Shinn-Horng Chen
IPC分类号： H01G9/025 , H01G9/02 , C08G75/06
CPC分类号： C08G61/123 , C08G61/124 , C08G61/126 , C08G2261/1424 , C08G2261/3221 , C08G2261/3222 , C08G2261/3223 , C08G2261/3228 , C08G2261/3229 , H01G9/0036 , H01G9/028 , H01G9/15
摘要： An electrolytic material formulation and a polymer polymerized therefrom are provided. The formulation includes: (a) a monomer of formula (I); and (b) a monomer of formula (II), wherein, A, X, B1, B2, R1 to R3, q and w are defined as recited in the specification, and the amount of monomer (b) is about 1 part by weight to about 800 parts by weight per 100 parts by weight of monomer (a). The polymer is useful as an electrolytic material of a solid capacitor.
摘要翻译：提供电解材料配方和从其聚合的聚合物。制剂包括：（a）式（I）的单体; 和（b）式（II）的单体，其中A，X，B1，B2，R 1至R 3，q和w如说明书所述定义，单体（b）的量约为1份重量至约800份重量/ 100份重量的单体（a）。该聚合物可用作固体电容器的电解材料。

5. 发明申请

US20120088900A1 PROCESS FOR PREPARING REGIOREGULAR POLY-(3-SUBSTITUTED) THIOPHENES, SELENOPHENES, THIAZOLES AND SELENAZOLES 失效
标题翻译：制备邻苯二酚（3-取代的）噻吩，苯丙烯，噻唑和精油的方法
公开(公告)号：US20120088900A1
公开(公告)日：2012-04-12
申请号：US13378069
申请日：2010-06-14
申请人： Marcel Kastler , Silke Annika Koehler
发明人： Marcel Kastler , Silke Annika Koehler
IPC分类号： C08G75/00
CPC分类号： H01B1/127 , C08G61/123 , C08G61/126 , C08G2261/3223 , C08G2261/3225 , C08G2261/3229 , C08G2261/323 , C08G2261/416 , C08G2261/417 , H01L51/0036
摘要： A process for preparing a regioregular homopolymer or copolymer of 3-substituted thiophene, 3-substituted selenophene, 3-substituted thiazol or 3-substituted selenazol by a) reacting a 3-substituted 2,5-dihalothiophene, 2,5-dihaloselenophene, 2,5-dihalothiazol or 2,5-dihaloselenazol with reactive zinc, magnesium and/or an organomagnesium halide to give an organozinc or organomagnesium intermediate containing one halozinc or one halomagnesium group, b) bringing the organozinc or the organomagnesium intermediate into contact with a Ni(II), Ni(O), Pd(II) or Pd(O) catalyst to initiate the polymerization reaction, and c) polymerizing the organozinc or the organomagnesium intermediate to give a regioregular head-to-tail homopolymer or copolymer of 3-substituted thiophene, 3-substituted selenophene, 3-substituted thiazol or 3-substituted selenazol characterized in that the polymerization reaction is carried out at a temperature rising from a lower temperature T1 to a higher temperature T2 during a time t1, wherein T1 is in the range of from −40 to 5 ° C. and T2 is in the range of from −20 to 40 ° C., wherein T2−T1 is at least 10 ° C. and the average rate of increase (T2−T1)/t1 is in the range of from 0.05 ° C/min to 1 ° C/min.
摘要翻译：制备3-取代噻吩，3-取代的硒吩，3-取代的噻唑或3-取代的硒吩的区域性均聚物或共聚物的方法，通过以下步骤a）使3-取代的2,5-二卤代噻吩，2,5-二卤代硒吩，2 ，5-二卤噻唑或2,5-二卤代硒唑与反应性锌，镁和/或有机卤化镁反应，得到含有一个卤素或一个卤代镁基团的有机锌或有机镁中间体，b）使有机锌或有机镁中间体与Ni （II），Ni（O），Pd（II）或Pd（O）催化剂以引发聚合反应，以及c）使有机锌或有机镁中间体聚合，得到区域性的头 - 尾均聚物或3- 取代噻吩，3-取代硒吩，3-取代噻唑或3-取代硒吩，其特征在于聚合反应在从较低温度T1升高至更高温度T2 dur的温度下进行时间t1，其中T1在-40至5℃的范围内，T2在-20至40℃的范围内，其中T2-T1至少为10℃，平均值为增加率（T2-T1）/ t1在0.05℃/分钟至1℃/分钟的范围内。

6. 发明授权

US07928433B2 Electronic device comprising semiconducting polymers 有权
标题翻译：包含半导体聚合物的电子器件
公开(公告)号：US07928433B2
公开(公告)日：2011-04-19
申请号：US12193189
申请日：2008-08-18
申请人： Yuning Li
发明人： Yuning Li
IPC分类号： H01L51/30 , C08G73/08
CPC分类号： C08G73/08 , C08G61/123 , C08G61/126 , C08G73/06 , C08G73/0616 , C08G2261/3221 , C08G2261/3223 , C08G2261/3229 , C08G2261/3243 , C08L79/06 , H01L51/0035 , H01L51/0036 , H01L51/0042 , H01L51/0541 , H01L51/0545
摘要： An electronic device comprises a semiconducting polymer of Formula (I): wherein X is independently selected from S, Se, O, and NR, wherein R is independently selected from hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, heteroaryl, and —CN; Ar is independently a conjugated divalent moiety; a is an integer from 1 to about 10; and n is an integer from 2 to about 5,000. The electronic device may be an organic thin film transistor.
摘要翻译：电子器件包括式（I）的半导体聚合物：其中X独立地选自S，Se，O和NR，其中R独立地选自氢，烷基，取代的烷基，芳基，取代的芳基，杂芳基和 - CN; Ar独立地为共轭二价部分; a是1至约10的整数; 且n为2至约5,000的整数。电子器件可以是有机薄膜晶体管。

7. 发明授权

US09893288B2 Diketopyrrolopyrrole polymers for use in organic field effect transistors 有权
公开(公告)号：US09893288B2
公开(公告)日：2018-02-13
申请号：US15364978
申请日：2016-11-30
申请人： BASF SE
发明人： Mathias Duggeli , Mahmoud Zaher Eteish , Pascal Hayoz , Olivier Aebischer , Marta Fonrodona Turon , Margherita Fontana , Marian Lanz , Mathieu G. R. Turbiez , Beat Schmidhalter , Jean-Charles Flores
IPC分类号： C08G73/00 , H01L51/00 , C08G61/12 , H01L51/05 , H01L27/28
CPC分类号： H01L51/0036 , C08G61/12 , C08G61/124 , C08G61/126 , C08G2261/124 , C08G2261/1412 , C08G2261/18 , C08G2261/228 , C08G2261/3223 , C08G2261/3229 , C08G2261/3241 , C08G2261/3243 , C08G2261/3246 , C08G2261/334 , C08G2261/364 , C08G2261/411 , C08G2261/92 , H01L27/283 , H01L51/0001 , H01L51/0007 , H01L51/0043 , H01L51/0053 , H01L51/0558
摘要： The present invention relates to polymers comprising a repeating unit of the formula I, or III and their use as organic semiconductor in organic devices, especially an organic field effect transistor (OFET), or a device containing a diode and/or an organic field effect transistor. The polymers according to the invention have excellent solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the polymers according to the invention are used in organic field effect transistors.

8. 发明申请

US20170069845A1 ORGANIC SEMICONDUCTOR MATERIAL 审中-公开
标题翻译：有机半导体材料
公开(公告)号：US20170069845A1
公开(公告)日：2017-03-09
申请号：US15118658
申请日：2015-02-03
申请人： TOYOBO CO., LTD.
发明人： Atsushi Wakamiya , Kazutake Hagiya , Shiro Hamamoto , Hikaru Tanaka
IPC分类号： H01L51/00 , C07F7/08 , C07F7/22 , C07D513/04 , C08G61/12
CPC分类号： H01L51/0036 , C07D513/04 , C07F7/0814 , C07F7/2208 , C08G61/123 , C08G61/126 , C08G2261/124 , C08G2261/1412 , C08G2261/149 , C08G2261/3223 , C08G2261/3229 , C08G2261/3241 , C08G2261/3243 , C08G2261/3246 , C08G2261/3328 , C08G2261/334 , C08G2261/344 , C08G2261/413 , C08G2261/91 , H01L51/0035 , H01L51/0043 , H01L51/0094 , H01L51/0558 , H01L51/424
摘要： Provided are: a macromolecular compound for providing an organic semiconductor material exhibiting excellent conversion efficiency; a starting-material compound having high material design freedom; and methods for producing the same.The macromolecular compound according to the present invention comprising a benzobisthiazole structural unit represented by the formula (1): [in the formula (1), T1 and T2 each independently represent an alkoxy group, a thioalkoxy group, a thiophene ring optionally substituted by a hydrocarbon group or an organosilyl group, a thiazole ring optionally substituted by a hydrocarbon group or an organosilyl group, or a phenyl group optionally substituted by a hydrocarbon group, an alkoxy group, a thioalkoxy group, an organosilyl group, a halogen atom or a trifluoromethyl group; and B1 and B2 each represent a thiophene ring optionally substituted by a hydrocarbon group, a thiazole ring optionally substituted by a hydrocarbon group, or an ethynylene group].
摘要翻译：提供：用于提供显示出优异转化效率的有机半导体材料的大分子化合物; 具有高材料设计自由度的原料化合物; 及其制造方法。包含式（1）所示的苯并二噻唑结构单元的本发明的高分子化合物：[式（1）中，T 1和T 2各自独立地表示烷氧基，硫代烷氧基，任选取代的噻吩环通过烃基或有机甲硅烷基，任选被烃基或有机甲硅烷基取代的噻唑环，或任选被烃基，烷氧基，硫代烷氧基，有机甲硅烷基，卤素原子取代的苯基或三氟甲基; B 1和B 2各自表示任选被烃基取代的噻吩环，任选被烃基取代的噻唑环或亚乙炔基。

9. 发明授权

US09455059B2 Phenanthro [1,10,9,8-c,d,e,f,g]carbazole polymers and their use as organic semiconductors 有权
标题翻译：菲咯啉[1,10,9,8-c，d，e，f，g]咔唑聚合物及其作为有机半导体的用途
公开(公告)号：US09455059B2
公开(公告)日：2016-09-27
申请号：US13389906
申请日：2010-07-14
申请人： Nicolas Blouin , William Mitchell , Changsheng Wang , Steven Tierney
发明人： Nicolas Blouin , William Mitchell , Changsheng Wang , Steven Tierney
IPC分类号： H02B1/00 , C08G61/00 , H01B1/12 , B82Y10/00 , C07D209/56 , C07D417/14 , C08G61/12 , C08L65/00 , C09K11/06 , H01L51/00 , H05B33/14 , H01L51/42
CPC分类号： H01B1/12 , B82Y10/00 , C07D209/56 , C07D417/14 , C08G61/123 , C08G61/124 , C08G61/126 , C08G2261/3223 , C08G2261/3229 , C08G2261/3241 , C08G2261/411 , C08G2261/51 , C08G2261/596 , C08G2261/91 , C08G2261/92 , C08L65/00 , C09K11/06 , C09K2211/1466 , C09K2211/1483 , H01L51/0036 , H01L51/0047 , H01L51/4253 , H05B33/14 , Y02E10/549 , Y02P70/521
摘要： The invention relates to novel phenanthro[1,10,9,8-c,d,e,f,g]carbazole polymers, methods and materials for their preparation, their use as semiconductors in organic electronic (OE) devices, and to OE devices comprising these polymers.
摘要翻译：本发明涉及新颖的菲咯啉[1,10,9,8-c，d，e，f，g]咔唑聚合物，其制备方法和材料，它们在有机电子（OE）装置中作为半导体的用途，以及OE 包含这些聚合物的装置。

10. 发明申请

US20160237204A1 COPOLYMER AND ORGANIC SOLAR CELL COMPRISING SAME 有权
公开(公告)号：US20160237204A1
公开(公告)日：2016-08-18
申请号：US15022121
申请日：2014-09-16
申请人： LG CHEM, LTD.
发明人： Keun CHO , BAE Jaesoon , LEE Jaechol , LEE Jiyoung , LEE Hangken , KIM Jinseck , LIM Bogyu
IPC分类号： C08G61/12 , H01L51/42
CPC分类号： C08G61/126 , C08G61/123 , C08G73/06 , C08G2261/12 , C08G2261/122 , C08G2261/1412 , C08G2261/1424 , C08G2261/149 , C08G2261/3223 , C08G2261/3229 , C08G2261/3241 , C08G2261/3243 , C08G2261/334 , C08G2261/344 , C08G2261/364 , C08G2261/414 , C08G2261/514 , C08G2261/91 , C08L65/00 , H01L51/0035 , H01L51/0036 , H01L51/0043 , H01L51/0047 , H01L51/424 , H01L51/4253 , Y02E10/549
摘要： The present specification provides a copolymer and an organic solar cell including the same.

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