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1. 发明授权

US3171853A S-benzylthiomethyl neutral esters of thiophosphorus pentavalent acids 失效
标题翻译：硫代磷酸五价酸的S-苄基硫代甲基中性酯
公开(公告)号：US3171853A
公开(公告)日：1965-03-02
申请号：US84893059
申请日：1959-10-27
申请人： BAYER AG
发明人： WALTER LORENZ , GERHARD SCHRADER
IPC分类号： C07F9/165 , C07F9/24 , C07F9/32 , C07F9/40 , C07F9/44
CPC分类号： C07F9/4075 , C07F9/1651 , C07F9/2408 , C07F9/3264 , C07F9/4015 , C07F9/4438

2. 发明授权

US3229000A Alkyl-or aryl-mercapto-(sulphoxido-, sulphono-) carboxylic acid derivatives of thiophosphoric, thiophosphonic and thiophosphinic acid esters and processes for their production 失效
标题翻译：硫代磷酸，硫代膦酸和硫代次膦酸酯的烷基或芳基 - 巯基 - （亚磺酰基，磺酰基）羧酸衍生物及其生产方法
公开(公告)号：US3229000A
公开(公告)日：1966-01-11
申请号：US27608763
申请日：1963-04-26
申请人： BAYER AG
发明人： WALTER LORENZ , HANS-GERD SCHICKE , GERHARD SCHRADER
IPC分类号： C07F9/165 , C07F9/24 , C07F9/32 , C07F9/40 , C07F9/44
CPC分类号： C07F9/4075 , C07F9/1651 , C07F9/2408 , C07F9/3264 , C07F9/4438

3. 发明授权

US3228999A Alkoxy carbonyl, amino carbonyl and cyano derivatives of alkyl or aryl mercapto, sulphono or sulphoxido ethyl esters of thio-phosphorus acids 失效
标题翻译：烷基或芳基巯基的烷氧基羰基，氨基羰基和氰基衍生物，硫代磷酸的磺酰基或亚磺酰基乙酯
公开(公告)号：US3228999A
公开(公告)日：1966-01-11
申请号：US20131962
申请日：1962-06-11
申请人： BAYER AG
发明人： HANS-GERD SCHICKE , WALTER LORENZ , GERHARD SCHRADER
IPC分类号： C07F9/28 , C07F9/32 , C07F9/40 , C07F9/44
CPC分类号： C07F9/4075 , C07C323/00 , C07F9/3264 , C07F9/4438

4. 发明授权

US4985415A Pesticidal thionophosphonic acid(amide) esters 失效
标题翻译：杀虫硫代膦酸（酰胺）酯
公开(公告)号：US4985415A
公开(公告)日：1991-01-15
申请号：US327650
申请日：1989-03-23
申请人： Herbert Sommer , Dieter Arlt , Jurgen Hartwig , Bernhard Homeyer , Hans-Detlef Matthaei
发明人： Herbert Sommer , Dieter Arlt , Jurgen Hartwig , Bernhard Homeyer , Hans-Detlef Matthaei
IPC分类号： A01N57/20 , A01N57/28 , C07F9/40 , C07F9/42 , C07F9/44
CPC分类号： C07F9/4075 , A01N57/20 , A01N57/28 , C07F9/425 , C07F9/4438
摘要： Pesticidal thionophosphonic acid(amide) esters of the formula ##STR1## in whichR.sup.1 stands for optionally substituted alkyl or alkenyl,R.sup.2 stands for optionally substituted alkoxy, alkenyloxy or alkinyloxy, or for the group ##STR2## in whichR.sup.3 and R.sup.4 are identical or different and independently of one another stand for hydrogen or for optionally substituted alkyl, cycloalkyl, alkenyl or alkinyl, or together with the nitrogen atom form a 5- to 7-membered, saturated or unsaturated ring andX stands for halogen.Intermediates of the formuula ##STR3## are also new.
摘要翻译： R 1代表任选取代的烷基或链烯基，R 2代表任选取代的烷氧基，烯氧基或烷氧基或对于其中R 3和R 4的基团相同或不同，彼此独立地代表氢或任选取代的烷基，环烷基，烯基或炔基，或与氮原子一起形成5-至7-元饱和或不饱和的环，X代表卤素。制剂的中间体也是新的。

5. 发明授权

US4166850A Combating pests with N-acetyl-0-(2-chloro-1-fluoro-ethyl)-thionophosphoric (phosphonic) acid ester-amides 失效
标题翻译：与N-乙酰基-O-（2-氯-1-氟 - 乙基） - 硫代磷酸（膦酸）酸酯 - 酰胺相结合的害虫
公开(公告)号：US4166850A
公开(公告)日：1979-09-04
申请号：US932073
申请日：1978-08-08
申请人： Hellmut Hoffmann , Dieter Arlt , Ingeborg Hammann , Bernhard Homeyer , Wilhelm Stendel
发明人： Hellmut Hoffmann , Dieter Arlt , Ingeborg Hammann , Bernhard Homeyer , Wilhelm Stendel
IPC分类号： A01N57/28 , C07F9/20 , C07F9/24 , C07F9/42 , C07F9/44 , A01N9/36 , C07F9/22
CPC分类号： C07F9/4492 , A01N57/28 , C07F9/20 , C07F9/2408 , C07F9/2487 , C07F9/425 , C07F9/4438
摘要： N-Acetyl-0-(2-chloro-1-fluoro-ethyl)-thionophosphoric (phosphonic) acid ester-amides of the formula ##STR1## IN WHICH R is alkyl or alkoxy, which possess arthropodicidal and nematicidal properties.
摘要翻译：式中的N-乙酰基-O-（2-氯-1-氟 - 乙基） - 硫代磷酸（膦酸） - 酸酯 - 酰胺，其中R是烷基或烷氧基，其具有节肢杀虫和杀线虫性质。

6. 发明授权

US3574793A Imino phosphoramidates 失效
标题翻译：亚硝基磷酰胺
公开(公告)号：US3574793A
公开(公告)日：1971-04-13
申请号：US3574793D
申请日：1968-07-24
申请人： VELSICOL CHEMICAL CORP
发明人： RICHTER SIDNEY B , KAPLAN EPHRAIM H
IPC分类号： C07F9/24 , C07F9/44 , C07F9/08 , C07F9/16 , C07F9/40
CPC分类号： C07F9/2408 , C07F9/4438
摘要： THIS INVENTION DISCLOSES COMPOUNDS OF THE FORMULA

R1-N(-R2)-P(=X1)(-Y)-X2-CH2-C(-O-R3)=N-O-R4

WHEREIN Y IS SELECTED FROM THE GROUP CONSISTING OF ALKYL, ALKENYL, ALKOXY, ALKENYLOXY, ALKYLTHIO AND

((Z)M,(H)(5-M)-PHENYL)-(A)N-

WHEREIN Z IS SELECTED FROM THE GROUP CONSISTING OF ALKYL, ALKENYL, ALKOXY, ALKYLTHIO, HALOGEN, NITRO, ALKYSULFOXIDE, ALKYLSULFONE AND DIALKYLAMINO, M IS AN INTEGER FROM 0 TO 5, A IS SELECTED FROM THE GROUP CONSISTING OF OXYGEN, SULFUR, AND ALKYLENE, AND N IS AN INTEGER FROM 0 TO 1;R1 AND R2 ARE INDEPENDENTLY SELECTED FROM THE GROUP CONSISTING OF HYDROGEN AND ALKYL; R3 AND R4 ARE ALKYL; AND X1 AND X2 ARE INDEPENDENTLY SELECTED FROM THE GROUP CONSISTING OF OXYGEN AND SULFUR. THE INVENTION ALSO DISCLOSES INSECTICIDAL AND ACARICIDAL COMPOSITIONS COMPRISING AN INERT CARRIER, AND AS AN ESSENTIAL ACTIVE INGREDIENT, IN A QUANTITY TOXIC TO INSECTS AND ACARIDS A COMPOUND OF THE ABOVD DESCRIPTION; AND FURTHER A METHOD OF DESTROYING INSECTS AND ACARIDS WHICH COMPRISES APPLYING TO SAID INSECTSD AND ACARIDS AN AFOREDESCRIBED INSECTICIDAL AND ACARICIDAL COMPOSITION.

7. 发明授权

US3093536A Stabilized halogenated enol ester pesticidal compositions 失效
标题翻译：稳定的卤代烯醇酯农药组合物
公开(公告)号：US3093536A
公开(公告)日：1963-06-11
申请号：US10080161
申请日：1961-04-05
申请人： SHELL OIL CO
发明人： LOEFFLER ERWIN S
IPC分类号： A01N57/02 , C07F9/09 , C07F9/165 , C07F9/24 , C07F9/40 , C07F9/44 , C22B9/22
CPC分类号： C22B9/228 , A01N57/02 , C07F9/091 , C07F9/1651 , C07F9/2408 , C07F9/40 , C07F9/4438 , Y10S514/97

8. 发明授权

US4390529A S-(Tertiary alkyl) alkylphosphonoamidodithioates and their use as insecticides and nematocides 失效
标题翻译： S-（叔烷基）烷基膦酰基二硫代磷酸酯及其作为杀虫剂和杀线虫剂的用途
公开(公告)号：US4390529A
公开(公告)日：1983-06-28
申请号：US221647
申请日：1980-12-31
申请人： Mohamed A. Fahmy
发明人： Mohamed A. Fahmy
IPC分类号： A01N57/28 , C07F9/44 , C07F9/24
CPC分类号： A01N57/28 , C07F9/4438
摘要： Compounds having the formula ##STR1## in which R is an alkyl of 1 to 8 carbon atoms, haloalkyl of 1 to 8 carbon atoms, alkenyl of 2 to 8 carbon atoms, haloalkenyl of 2 to 8 carbon atoms, alkynyl of 2 to 8 carbon atoms, or haloalkynyl of 2 to 8 carbon atoms;R.sub.1 is tertiary alkyl of 4 to 8 carbon atoms; andR.sub.2 and R.sub.3, independently are hydrogen, alkyl of 1 to 8 carbon atoms or cycloalkyl are disclosed as well as their use as insecticides and nematocides, e.g., in controlling Corn rootworm and Southern Armyworm.
摘要翻译：具有式“IMAGE”的化合物，其中R为1至8个碳原子的烷基，1至8个碳原子的卤代烷基，2至8个碳原子的烯基，2至8个碳原子的卤代链烯基，2至8个碳原子的炔基 2至8个碳原子的卤原子或卤代炔基; R1是4-8个碳原子的叔烷基; R2和R3独立地是氢，1-8个碳原子的烷基或环烷基，以及它们作为杀虫剂和杀线虫剂的用途，例如控制玉米根虫和南方蛔虫。

9. 发明授权

US3402224A Diacid ester dimethyl thioether diphosphorus compounds 失效
标题翻译：二酸酯二甲硫醚二磷化合物
公开(公告)号：US3402224A
公开(公告)日：1968-09-17
申请号：US43944265
申请日：1965-03-12
申请人： BAYER AG
发明人： HANS-GERD SCHICKE
IPC分类号： C07F9/165 , C07F9/24 , C07F9/32 , C07F9/40 , C07F9/44
CPC分类号： C07F9/4075 , C07F9/1651 , C07F9/2408 , C07F9/3264 , C07F9/4438

10. 发明授权

US3283038A Phosphorus containing compounds 失效
标题翻译：含磷化合物
公开(公告)号：US3283038A
公开(公告)日：1966-11-01
申请号：US14485461
申请日：1961-10-13
申请人： BAYER AG
发明人： WALTER LORENZ , GERHARD SCHRADER
IPC分类号： A01N57/04 , C07F9/06 , C07F9/09 , C07F9/165 , C07F9/24 , C07F9/32 , C07F9/40 , C07F9/44 , C07F9/6512 , C10L1/26 , C23F11/167
CPC分类号： C23F11/1673 , A01N57/04 , C07F9/06 , C07F9/091 , C07F9/1651 , C07F9/2408 , C07F9/3264 , C07F9/4071 , C07F9/4075 , C07F9/4438 , C07F9/65125 , C10L1/26 , C10L1/2616 , C10L1/265
摘要： The invention comprises phosphorus compounds of the general formula:- wherein R1 and R2 which may be the same or different are alkoxy, alkylmercapto, aryloxy, arylmercapto, aralkoxy, cycloalkoxy, alkyl, chloroalkyl, alkenyl, aralkyl, cycloalkyl, aryl or chloroaryl radicals, X1 is an oxygen or sulphur atom, X2 is a sulphur atom, X3 is a hydrogen atom or an alkyl or aryl radical and A is atom or an alkyl or aryl radical and A is the atomic grouping or groupings necessary to complete the residue of a malonic amide ester or thioester, a malonic acid diamide or a barbituric or thiobarbituric acid type compound. They may be obtained by reacting a halogeno-malonic acid amide ester (or thioester), ester), halogeno-malonic acid diamide, or halogeno-barbituric (or-thiobarbituric) acid type compound with a phosphorus compound of the formula: wherein R1, R2, X1 and X2 are as defined above, B is a hydrogen atom, alkali metal or ammonium and Hal is halogen, e.g. Cl or Br, the reaction being carried out in acid-binding agent when B is a hydrogen atom. The reaction is preferably effected at between room temperature and 80 DEG C. and may be carried out in the presence of water, an inert organic solvent or an aqueous organic solvent or in a two-phase sytem, e.g. water/ethylene chloride. The products may be of the type:- wherein R3 and R4 are hydrogen atoms, or alkyl, aralkyl, cycloalkyl or aryl radicals which may be substituted or are radicals which may be joined with the N-atom to form a heterocyclic ring, R5 is an alkoxy, alkylmercapto, aryloxy or arylmercapto radical or another NR3R4 group as defined above (including a heterocyclic ring, e.g. morpholine, piperidine, piperazine or pyrrolidine), and R1, R2, X1, X2 and X3 are as defined above. The barbituric acid type compounds may have the formula:- wherein the R1 and R2 attached to N are hydrogen atoms or alkyl radicals and Y is an oxygen or sulphur atom or an imino group and the other symbols are as defined above. Several examples are given and the products have pesticidal properties (see Division A5).ALSO:A pesticidal composition comprises a solid or liquid diluent or carrier and a phosphorus compound of the formula:- wherein R1 and R2 which may be the same or different are alkoxy, alkylmercapto, aryloxy, arylmercapto, aralkoxy, cycloalkoxy, alkyl, alkenyl chloroalkyl, alkenyl, aralkyl, cycloalkyl, aryl or chloroaryl radicals, X1 is an O or S atom, X2 is a sulphur atom, X3 is a hydrogen atom or an alkyl or aryl radical and A is the atomic grouping or groupings necessary to complete the residue of a malonic amide ester (or thioester), a malonic acid diamide or a barbituric or thiobarbituric acid type compound (see Division C2). The malonicamide type products may have the formula:- wherein R3 and R4 are hydrogen atoms, or alkyl, aralkyl, cycloalkyl or aryl radicals which may be substituted or are radicals which may be joined with the N atom to form a heterocyclic ring, R5 is an alkoxy, alkylmercapto, aryloxy or arylmercapto radical or another NR3R4 group as defined above (including a heterocyclic ring, e.g. morpholine, piperdine, piperazine or pyrrolidine) and R1, R2,X1,X2 and X3 are as defined above. The barbituric acid type compounds may have the formula:- wherein R1 and R2 attached to N are hydrogen atoms or alkyl radicals and Y is O, S, or are imino group and the other symbols are as defined above. Conventional solid and liquid diluants are specified and a suitable composition is obtained by dissolving the active ingredient in acetone, adding a commercial emulsifier and then diluting with water. Known insecticides and/or fertilisers may also be present.

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