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1. 发明申请

US20160122241A1 PROCESS FOR MANUFACTURING FLUOROPOLYMER COMPOSITES 审中-公开
标题翻译：制备氟聚合物复合材料的方法
公开(公告)号：US20160122241A1
公开(公告)日：2016-05-05
申请号：US14895296
申请日：2014-05-29
申请人： SOLVAY SPECIALTY POLYMERS ITALY S.P.A.
发明人： Eliana IEVA , Rui LIU , Elisabetta SARTIRANA
IPC分类号： C03C25/30
CPC分类号： C03C25/305 , B29B15/125 , C03C2217/78 , C03C2218/111 , C03C2218/32 , C08J5/043 , C08J2327/16
摘要： The present invention pertains to a process for manufacturing a fluoropolymer composite, said process comprising the following sequential steps: (i) providing an aqueous latex comprising from 10% to 40% by weight, preferably from 15% to 35% by weight of at least one fluoropolymer comprising recurring units derived from vinylidene fluoride (VDF) [polymer (VDF)]; (ii) up-concentrating the aqueous latex provided in step (i) thereby providing an up-concentrated aqueous latex comprising from 45% to 60% by weight, preferably from 45% to 55% by weight of at least one polymer (VDF); (iii) contacting one continuous fibre or a bunch of continuous fibres with the up-concentrated aqueous latex provided in step (ii); (iv) squeezing the impregnated fibrous material provided in step (iii); (v) drying the squeezed fibrous material provided in step (iv), typically at a temperature comprised between 100° C. and 120° C.; (vi) baking the dried fibrous material provided in step (v) at a temperature comprised between 190° C. and 240° C.; (vii) cooling the coated fibrous material provided in step (vi), preferably to a temperature of about 20° C.; (viii) optionally, contacting the coated fibrous material provided in step (vii) with the up-concentrated aqueous latex provided in step (ii) and submitting the impregnated fibrous material so provided to sequential steps (iv) to (vii); and (ix) optionally, repeating step (viii) one or more times. The present invention also pertains to the fluoropolymer composite thereby provided and to uses of said fluoropolymer composite in various applications.
摘要翻译：本发明涉及一种制备含氟聚合物复合材料的方法，所述方法包括以下顺序步骤：（i）提供包含10重量％至40重量％，优选15重量％至35重量％的至少一种含氟聚合物，其包含衍生自偏氟乙烯（VDF）[聚合物（VDF）]的重复单元; （ii）向上浓缩步骤（i）中提供的水性胶乳，从而提供含有45重量％至60重量％，优选45重量％至55重量％的至少一种聚合物（VDF）的上层浓缩水性胶乳， ; （iii）使一个连续纤维或一束连续纤维与步骤（ii）中提供的上升浓缩水性胶乳接触; （iv）挤压步骤（iii）中提供的浸渍的纤维材料; （v）干燥步骤（iv）中提供的挤压纤维材料，通常在100℃和120℃之间的温度下进行干燥。（vi）在190℃和240℃之间的温度下烘烤步骤（v）中提供的干燥的纤维材料; （vii）将步骤（vi）中提供的涂覆的纤维材料冷却至约20℃的温度; （viii）任选地，使步骤（vii）中提供的涂覆的纤维材料与步骤（ii）中提供的向上浓缩的水性胶乳接触，并将浸渍的纤维材料提供给顺序步骤（iv）至（vii）; 和（ix）任选地，重复步骤（viii）一次或多次。本发明还涉及由此提供的含氟聚合物复合物以及所述氟聚合物复合材料在各种应用中的用途。

2. 发明授权

US08563762B2 Metal oxide surface treatment with a fluoroalkyl silanizing agent 有权
标题翻译：用氟代烷基硅烷化剂进行金属氧化物表面处理
公开(公告)号：US08563762B2
公开(公告)日：2013-10-22
申请号：US13791091
申请日：2013-03-08
申请人： Arthur W Snow , Edward E Foos
发明人： Arthur W Snow , Edward E Foos
IPC分类号： C07C7/00
CPC分类号： C07F7/1804 , B05D1/185 , B05D7/52 , B82Y30/00 , B82Y40/00 , C03C25/24 , C03C25/305 , C03C25/40
摘要： This disclosure concerns a metal oxide surface treatment with a fluoroalkyl silanizing agent.
摘要翻译：本公开涉及用氟代烷基硅烷化剂进行金属氧化物表面处理。

3. 发明授权

US5576381A Aqueous dispersion of fluoropolymers, its preparation and use for coatings 失效
标题翻译：含氟聚合物的水分散体，其制备和用于涂料
公开(公告)号：US5576381A
公开(公告)日：1996-11-19
申请号：US346410
申请日：1994-11-29
申请人： Hermann Bl adel , Bernd Felix , Klaus Hintzer , Gernot L ohr , Wolf D. Mitterberger
发明人： Hermann Bl adel , Bernd Felix , Klaus Hintzer , Gernot L ohr , Wolf D. Mitterberger
IPC分类号： C08L27/12 , C03C25/30 , C08F2/16 , C08F214/26 , C08J3/00 , C08J3/03 , C08L27/18 , C09D127/12 , C09D127/18 , D06M15/256 , D06N3/04
CPC分类号： C08J3/005 , C03C25/305 , C08J3/03 , C09D127/18 , D06M15/256 , D06N3/047 , C08J2327/12 , C08L2205/02 , C08L27/18
摘要： Aqueous dispersions of fluoropolymers which are obtained by emulsion polymerization, are not processsable from the melt and form a film on sintering, which comprise a fluoropolymer A) having an average particle size (number average) of from 180 to 400 nm and a fluoropolymer B) having an average particle size which is lower by a factor of from about 0.3 to about 0.7, so that the total dispersion has a non-monomadal number distribution of the particle diameter, are suitable for soaking, impregnating or coating surfaces, for example of fibers or planiform articles of fibers or porous materials, in particular for coating fiberglass fabrics, and also for the formulation of metal coating systems.
摘要翻译：通过乳液聚合获得的含氟聚合物的水分散体不能从熔体中加工并且在烧结时形成膜，其包含平均粒径（数均）为180-400nm的含氟聚合物A）和含氟聚合物B）具有平均粒径小于约0.3至约0.7的因子，使得总分散体具有非单峰数分布的粒径，适于浸泡，浸渍或涂覆表面，例如纤维或平面状的纤维制品或多孔材料，特别是用于涂覆玻璃纤维织物，以及用于金属涂层体系的配制。

4. 发明授权

US4645709A Coated glass fabric 失效
标题翻译：涂布玻璃织物
公开(公告)号：US4645709A
公开(公告)日：1987-02-24
申请号：US867158
申请日：1986-05-27
申请人： Robert J. Klare
发明人： Robert J. Klare
IPC分类号： C08J5/08 , B29C67/04 , B29C70/06 , B29C70/10 , C03C25/30 , C08J5/12 , B32B7/00
CPC分类号： C03C25/305 , Y10T442/2213 , Y10T442/2369
摘要： A woven glass fabric is provided which contains coatings in sequence of a silicone oil, a particulate solid, and a high molecular weight polytetrafluoroethylene, or an elastomeric fluoropolymer.

5. 发明授权

US2539329A Process of coating an inorganic fabric with polytetrafluoroethylene and product resulting therefrom 失效
标题翻译：用聚四氟乙烯涂覆无机织物的方法及由此产生的产物
公开(公告)号：US2539329A
公开(公告)日：1951-01-23
申请号：US8660649
申请日：1949-04-09
申请人： DU PONT
发明人： FRANCIS SANDERS PHILIP
IPC分类号： B05D7/20 , B29C43/22 , B29C63/00 , C03C25/30 , C04B26/08 , C09D127/18 , D06M15/256 , H01B3/08 , H01B3/44
CPC分类号： H01B3/445 , B05D7/20 , B05D2401/20 , B05D2506/15 , B29C43/22 , B29C63/00 , C03C25/305 , C04B26/08 , C09D127/18 , D06M15/256 , H01B3/082 , Y10S138/03 , Y10T29/4971 , Y10T428/31544 , Y10T442/2475 , Y10T442/2992

6. 发明申请

US20140302237A1 METHOD FOR TREATING HIGH STRENGTH FABRIC TO BE WATER REPELLENT 审中-公开
标题翻译：用于处理高强度织物以达到水分的方法
公开(公告)号：US20140302237A1
公开(公告)日：2014-10-09
申请号：US14357287
申请日：2011-12-27
申请人： In-Sik Han
发明人： In-Sik Han
IPC分类号： D06B15/04
CPC分类号： D06B15/04 , C03C25/305 , D06M15/277 , D06M2101/36 , D06M2101/40
摘要： The present invention relates to a method for treating high-strength fabric to be water-repellent, which includes dipping a high-strength fabric in a water-repellent agent composition to impregnate the high-strength fabric with the water-repellent agent composition, and then, using an air-suction machine to pick-up a part of the water-repellent agent composition impregnated in the high-strength fabric before drying and heating the same. The present invention has advantages in that a part of the water-repellent agent composition impregnated in the high-strength fabric may be uniformly picked-up during dipping, so as to improve water-repellent performance, especially, water-repellency after friction as well as initial water-repellency, and may effectively prevent occurrence of wrinkles on the high-strength fabric during water-repellent treatment. The high-strength fabric obtained by water-repellent treatment according to the present invention exhibits increased flexibility without wrinkles, so as to improve wearing comfort. Further, in case of using the fabric as a raw fabric for bulletproof garments, water-repellency is increased to prevent deterioration in bulletproof properties caused by water absorption.
摘要翻译：本发明涉及一种处理防水剂的高强度织物的方法，该方法包括将高强度织物浸渍在拒水剂组合物中以用防水剂组合物浸渍高强度织物，以及然后使用吸气机取出浸渍在高强度织物中的一部分憎水剂组合物，然后干燥并加热。本发明的优点在于，浸渍在高强度织物中的部分防水剂组合物可以在浸渍期间均匀地吸收，从而提高防水性能，特别是摩擦后的防水性作为初始防水性，并且可以有效地防止在防水处理期间在高强度织物上产生皱纹。通过根据本发明的拒水处理获得的高强度织物表现出增加的柔软性而没有皱纹，从而提高穿着舒适性。此外，在使用织物作为防弹衣物的原料织物的情况下，防水性提高，以防止由吸水引起的防弹性能的劣化。

7. 发明申请

US20050245150A1 Glass-ptfe textile material 审中-公开
标题翻译： Glass-ptfe纺织材料
公开(公告)号：US20050245150A1
公开(公告)日：2005-11-03
申请号：US10507985
申请日：2003-03-17
申请人： Horst-Dieter Rector
发明人： Horst-Dieter Rector
IPC分类号： B29C70/22 , C03C25/30 , D03D15/00 , B32B17/02 , B32B3/00 , B32B17/04 , B32B27/00
CPC分类号： D02G3/18 , B29C70/22 , C03C25/305 , D03D15/0011 , Y10T442/20 , Y10T442/2992 , Y10T442/30 , Y10T442/3049
摘要： The invention relates to a glass/PTFE textile material made from multifilament threads (1), the filaments (2) of which are coated with PTFE, whereby a rubbing of glass on glass in the final product, both between the threads and between the filaments to form pinholes can be reliably avoided. According to the invention, the filaments (2) are coated with sintered PTFE, the cavities (4) between the filaments (2) thus being filled and the outer surfaces of the threads (1) are formed by the coating (3) of the filaments (2).
摘要翻译：本发明涉及由复丝螺纹（1）制成的玻璃/ PTFE纺织材料，其长丝（2）涂覆有PTFE，从而在最终产品中玻璃上摩擦玻璃，两者之间的丝线和细丝可以可靠地避免形成针孔。根据本发明，细丝（2）涂覆有烧结的PTFE，因此，细丝（2）之间的空腔（4）被填充，并且螺纹（1）的外表面由（1）的涂层（3）形成细丝（2）。

8. 发明申请

US20040075074A1 Water-and oil-repellent composition, process for producing the same and use thereof 有权
标题翻译：拒水拒油剂组合物，其制造方法及其用途
公开(公告)号：US20040075074A1
公开(公告)日：2004-04-22
申请号：US10470305
申请日：2003-07-29
发明人： Kouji Kubota , Takuya Yoshioka , Masato Kashiwagi
IPC分类号： D06M010/00 , C08K003/00
CPC分类号： D06M15/263 , C03C17/32 , C03C25/305 , C09K3/18 , D06M15/277 , D06M2101/20 , D06M2200/10 , D06M2200/11 , D06M2200/12
摘要： Excellent water- and oil-repellency performances resulting from low temperature curing are achieved by an aqueous dispersion type fluorine-containing water- and oil-repellent composition containing a polymer of a perfluoroalkyl group-containing ethylenically unsaturated monomer dispersed in an aqueous medium, wherein the composition contains a nonionic surfactant having an HLB value of at most 11 and a cationic surfactant, and a homopolymer of at lest one monomer constituting the polymer has Tg of at most 50null C.
摘要翻译：通过含有分散在水性介质中的含有全氟烷基的烯键式不饱和单体的聚合物的含水分散型含氟防水斥油剂组合物实现了由低温固化所产生的优异的拒水拒油性能，其中，组合物含有HLB值至多为11的非离子表面活性剂和阳离子表面活性剂，并且构成聚合物的至少一种单体的均聚物的Tg至多为50℃。

9. 发明授权

US4347278A Polytetrafluoroethylene fluorocarbon resin dispersion-containing coating composition for glass fibers, glass fibers, and glass fiber fabric coated therewith 失效
标题翻译：用于玻璃纤维的聚四氟乙烯氟碳树脂分散体涂料组合物，玻璃纤维和涂覆的玻璃纤维织物
公开(公告)号：US4347278A
公开(公告)日：1982-08-31
申请号：US200675
申请日：1980-10-27
申请人： Martin C. Flautt , Robert Wong , Joseph F. Walsh
发明人： Martin C. Flautt , Robert Wong , Joseph F. Walsh
IPC分类号： C03C25/26 , C03C25/30 , B32B7/00 , D02G3/00
CPC分类号： C03C25/305 , C03C25/26 , Y10T428/2962 , Y10T428/2964 , Y10T442/232 , Y10T442/2402 , Y10T442/2992
摘要： Polytetrafluoroethylene fluorocarbon resin dispersion-containing coatings for glass fibers are disclosed. In one embodiment, the polytetrafluoroethylene fluorocarbon resin dispersion-containing composition also comprises a lubricant and is suitable for use as a padding composition for glass fiber fabric. In another embodiment, the polytetrafluoroethylene fluorocarbon resin dispersion-containing composition also comprises a film-forming polymer, a thixotropic gelling agent, a silane coupling agent and, optionally, a lubricant and is suitable for use as a size composition for glass fibers.
摘要翻译：公开了用于玻璃纤维的聚四氟乙烯氟碳树脂分散体涂层。在一个实施方案中，聚四氟乙烯氟碳树脂分散体组合物还包含润滑剂，并且适合用作玻璃纤维织物的填料组合物。在另一个实施方案中，含聚四氟乙烯氟碳树脂分散体的组合物还包含成膜聚合物，触变胶凝剂，硅烷偶联剂和任选的润滑剂，并且适合用作玻璃纤维的尺寸组合物。

10. 发明授权

US3896071A Storage stable aqueous dispersion of tetrafluorethylene polymer 失效
标题翻译：四氯丙烯聚合物储存稳定的水性分散体
公开(公告)号：US3896071A
公开(公告)日：1975-07-22
申请号：US48726674
申请日：1974-07-10
申请人： DU PONT
发明人： POIRIER ROBERT VICTOR
IPC分类号： C03C25/30 , C08L27/18 , C08F45/24
CPC分类号： C03C25/305 , C08K5/06 , C08L27/18 , C08L71/02 , C08L2666/14
摘要： Aqueous dispersion of tetrafluoroethylene polymer is made storage stable by adding to the dispersion a moderate amount of nonionic surfactant, e.g., from about 1 to 6% by weight thereof, and about 1 to 6% by weight of an essentially hydrophilic water soluble alkylene oxide polymer such as polyethylene glycol. The resultant dispersion is useful as a coating composition, for example to coat glass fabric, with a minimal loss of tetrafluoroethylene polymer by settling in the dispersion during storage of the dispersion prior to coating.

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