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    • 6. 发明申请
    • Fabrication of optical fibers incorporating volatile constituents
    • 掺入挥发性成分的光纤的制造
    • US20020054741A1
    • 2002-05-09
    • US09978201
    • 2001-10-17
    • Gilberto BrambillaValerio Pruneri
    • G02B006/16C03B037/023
    • C03B37/02754C03B37/01205C03B37/01211C03B37/027C03B2201/28C03B2201/30C03B2201/32C03B2201/34C03B2201/50C03B2205/13C03B2205/14C03B2205/16C03C13/04C03C13/046
    • A method of fabricating an optical fiber incorporating a volatile constituent, involving: (a) providing a preform comprising a cladding glass having an axial aperture and a core glass arranged in the axial aperture, wherein the working temperature of the core glass lies below the working temperature of the cladding glass; and (b) drawing the preform into an optical fiber at a drawing temperature that lies between the working temperatures of the core and cladding glasses and above the softening temperature of the cladding glass, wherein the core glass prior to drawing includes a dioxide or higher oxide compound of the volatile constituent having a Gibbs free energy of disassociation into a monoxide compound of the volatile constituent that is negative at the drawing temperature, whereby the dioxide or higher oxide compound tends to disassociate into the monoxide compound during drawing. The volatile constituent may be Sn or Pb. The method may also be adapted for incorporating P as the volatile constituent. With this method, the core material melts while the cladding glass remains solid but in a deformable state. Melting the core material, provides more freedom in the choice of combinations of core and cladding glasses. The starting material for the core may be a powder or a solid rod, i.e. the invention may be embodied as a powder-in-tube (PIT) or a rod-in-tube (RIT) method.
    • 一种制造包含挥发性成分的光纤的方法,其包括:(a)提供包括具有轴向孔径的包层玻璃和布置在所述轴向孔中的芯玻璃的预成型件,其中所述芯玻璃的工作温度位于所述工作 包层玻璃的温度; 和(b)在处于芯和包层玻璃的工作温度之间并高于包层玻璃的软化温度的拉伸温度下将预成型件拉制成光纤,其中在拉拔之前的芯玻璃包括二氧化物或更高的氧化物 挥发性成分的化合物具有解离的吉布斯自由能,在拉伸温度下为负的挥发性成分的一氧化物化合物,由此二氧化物或更高级的氧化物化合物倾向于在拉伸期间分解成一氧化合物。 挥发性成分可以是Sn或Pb。 该方法还可以适于将P作为挥发性成分掺入。 利用这种方法,芯材料熔化,同时包层玻璃保持固体但处于可变形状态。 熔化芯材料可提供更多的自由选择芯和包层玻璃的组合。 芯的起始材料可以是粉末或实心棒,即本发明可以实施为管内粉末(PIT)或棒内管(RIT)方法。
    • 10. 发明授权
    • Optical fiber preforms
    • 光纤预制棒
    • US06723435B1
    • 2004-04-20
    • US10229937
    • 2002-08-28
    • Craig R. HorneJesse S. JurRonald J. MossoEric H. EuvrardXiangxin Bi
    • Craig R. HorneJesse S. JurRonald J. MossoEric H. EuvrardXiangxin Bi
    • B32B1706
    • C03B37/018C03B37/0128C03B37/014C03B37/027C03B2205/13Y02P40/57
    • Optical fiber preforms can comprise a glass preform structure with an inner cavity. A powder can be placed within the inner cavity having an average primary particle size of less than about one micron. The powder can be in the form of an unagglomerated particles or a powder coating with a degree of agglomeration or hard fusing ranging from none to significant amounts as long as the primary particles are visible in a micrograph. Powders can be placed within a preform structure by forming a slurry with a dispersion of submicron/nanoscale particles within a cavity within the prefrom. In other embodiments, a powder coating is formed within a preform structure by depositing the powder coating directly from a reaction product stream. The formation of the powder coating can be formed within the reaction chamber or outside of the reaction chamber by flowing the product particle stream through a conduit leading to the preform structure. In additional embodiments, a powder coating is placed on an insert, e.g., a glass insert, that is subsequently placed within a preform structure.
    • 光纤预制件可以包括具有内腔的玻璃预制件结构。 粉末可以放置在具有小于约一微米的平均一次粒径的内腔内。 只要初级颗粒在显微照片中可见,粉末可以是非聚集颗粒或具有聚集程度或硬熔点的粉末涂层的形式,其范围从无至大量。 粉末可以通过在预成型体内的空腔内形成具有亚微米/纳米级颗粒的分散体的浆料而放置在预成型体结构内。 在其它实施方案中,通过直接从反应产物流沉积粉末涂料,在预成型体结构内形成粉末涂料。 粉末涂层的形成可以通过使产物颗粒流通过导致预成型结构的导管而在反应室内或反应室外形成。 在另外的实施例中,将粉末涂层放置在随后放置在预成型结构内的插入件上,例如玻璃插入件上。