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1. 发明授权

US07405359B2 Mg-Al-based hydrotalcite-type particles, chlorine-containing resin composition and process for producing the particles 失效
标题翻译： Mg-Al系水滑石型颗粒，含氯树脂组合物及其制造方法
公开(公告)号：US07405359B2
公开(公告)日：2008-07-29
申请号：US11188783
申请日：2005-07-26
申请人： Naoya Kobayashi , Torayuki Honmyo , Tsutomu Katamoto , Akinori Yamamoto
发明人： Naoya Kobayashi , Torayuki Honmyo , Tsutomu Katamoto , Akinori Yamamoto
IPC分类号： H01B3/44 , C08K3/22 , C08L27/06
CPC分类号： C08K3/26 , C01F7/005 , C01G1/04 , C01P2002/22 , C01P2004/54 , C01P2004/61 , C01P2004/62 , C01P2006/12 , C01P2006/32 , C01P2006/40 , C08K3/22 , C09C3/06 , C09C3/10 , H01B3/441 , C08L57/08
摘要： A chlorine-containing resin composition for covering an electric wire of the present invention, has a heat stability of not less than 240 minutes and a volume resistivity of 5.0×1013 to 1.0×1016 Ω·cm when measured according to JIS K6723, and comprises: 100 parts by weight of a chlorine-containing resin, and 1.5 to 10 parts by weight of Mg—Al-based hydrotalcite-type particles having a composition represented by the formula: [MgxCay].Alz.(OH)2.An−p.mH2O wherein 0.2≦z/(x+z)≦0.6; 0.01≦y/(x+z)≦0.20; x+y+z=1; p=(2(x+y−1)+3z)/n; A is a n-valent anion; and m is more than 0 and not more than 0.75, having a plate surface diameter of 0.1 to 1.0 μm and a thickness of 0.02 to 0.08 μm, and containing calcium at a molar ratio of Ca to a sum of Mg and Al of 0.01:1 to 0.20:1, and having a heat-resisting time of not less than 4 hours upon a chlorine-containing resin composition containing the Mg—Al-based hydrotalcite-type particles.
摘要翻译：本发明的电线覆盖用含氯树脂组合物的热稳定性不低于240分钟，体积电阻率为5.0×10 13〜1.0×10 16，根据JIS K6723测量时，SUP> Omeg·cm，包含：100重量份含氯树脂和1.5〜10重量份具有式（I）所示组成的Mg-Al系水滑石型颗粒，：<？in-line-formula description =“In-line Formulas”end =“lead”？> [Mg Ca /SUB>.(OH)₂.A^n-_p.mH₂O其中0.2 <= z /（x + z）<= 0.6; 0.01 <= y /（x + z）<= 0.20; x + y + z = 1; p =（2（x + y-1）+ 3z）/ n; A是n价阴离子; m为0以上且0.75以下，板表面直径为0.1〜1.0μm，厚度为0.02〜0.08μm，Ca与Mg与Al之和的摩尔比为0.01： 1〜0.20：1，并且在含有Mg-Al系水滑石类粒子的含氯树脂组合物上具有不低于4小时的耐热时间。

2. 发明申请

US20080145296A1 Mg-Al-based hydrotalcite-type particles, chlorine-containing resin composition and process for producing the particles 审中-公开
标题翻译： Mg-Al系水滑石型颗粒，含氯树脂组合物及其制造方法
公开(公告)号：US20080145296A1
公开(公告)日：2008-06-19
申请号：US12068165
申请日：2008-02-04
申请人： Naoya Kobayashi , Torayuki Honmyo , Tsutomu Katamoto , Akinori Yamamoto
发明人： Naoya Kobayashi , Torayuki Honmyo , Tsutomu Katamoto , Akinori Yamamoto
IPC分类号： C01G1/04
CPC分类号： C08K3/26 , C01F7/005 , C01G1/04 , C01P2002/22 , C01P2004/54 , C01P2004/61 , C01P2004/62 , C01P2006/12 , C01P2006/32 , C01P2006/40 , C08K3/22 , C09C3/06 , C09C3/10 , H01B3/441 , C08L57/08
摘要： A chlorine-containing resin composition for covering an electric wire of the present invention, has a heat stability of not less than 240 minutes and a volume resistivity of 5.0∞1013 to 1.0×1016 Ω·cm when measured according to JIS K6723, and comprises: 100 parts by weight of a chlorine-containing resin, and 1.5 to 10 parts by weight of Mg—Al-based hydrotalcite-type particles having a composition represented by the formula: [MgxCay]·Alz·(OH)2·An−p·mH2O wherein 0.2≦z/(x+z)≦0.6; 0.01≦y/(x+z)≦0.20; x+y+z=1; p=(2(x+y−1)+3z)/n; A is a n-valent anion; and m is more than 0 and not more than 0.75, having a plate surface diameter of 0.1 to 1.0 μm and a thickness of 0.02 to 0.08 μm, and containing calcium at a molar ratio of Ca to a sum of Mg and Al of 0.01:1 to 0.20:1, and having a heat-resisting time of not less than 4 hours upon a chlorine-containing resin composition containing the Mg—Al-based hydrotalcite-type particles.
摘要翻译：本发明的电线覆盖用含氯树脂组合物的热稳定性不低于240分钟，体积电阻率为5.0〜10 13〜1.0×10 16，根据JIS K6723测定的/SUP≥Omega.cm，包含：100重量份含氯树脂和1.5〜10重量份具有以下成分表示的组成的Mg-Al类水滑石型粒子公式：<？in-line-formula description =“In-line Formulas”end =“lead”？> [Mg Ca ] （OH）2 N - - - - - - - - - - - - - - - - - - - - - - - - line-formula description =“In-line Formulas”end =“tail”？>其中0.2 <= z /（x + z）<= 0.6; 0.01 <= y /（x + z）<= 0.20; x + y + z = 1; p =（2（x + y-1）+ 3z）/ n; A是n价阴离子; m为0以上且0.75以下，板表面直径为0.1〜1.0μm，厚度为0.02〜0.08μm，Ca与Mg与Al之和的摩尔比为0.01： 1〜0.20：1，并且在含有Mg-Al系水滑石类粒子的含氯树脂组合物上具有不低于4小时的耐热时间。

3. 发明授权

US06939909B2 Mg-Al-based hydrotalcite-type particles, chlorine-containing resin composition and process for producing the particles 失效
标题翻译： Mg-Al系水滑石型颗粒，含氯树脂组合物及其制造方法
公开(公告)号：US06939909B2
公开(公告)日：2005-09-06
申请号：US10976873
申请日：2004-11-01
申请人： Naoya Kobayashi , Torayuki Honmyo , Tsutomu Katamoto , Akinori Yamamoto
发明人： Naoya Kobayashi , Torayuki Honmyo , Tsutomu Katamoto , Akinori Yamamoto
IPC分类号： C08L27/04 , C01F7/00 , C08K3/10 , C08K3/22 , C08K3/26 , H01B3/44 , C08L3/10
CPC分类号： C08K3/26 , C01F7/005 , C01G1/04 , C01P2002/22 , C01P2004/54 , C01P2004/61 , C01P2004/62 , C01P2006/12 , C01P2006/32 , C01P2006/40 , C08K3/22 , C09C3/06 , C09C3/10 , H01B3/441 , C08L57/08
摘要： A chlorine-containing resin composition for covering an electric wire of the present invention, has a heat stability of not less than 240 minutes and a volume resistivity of 5.0×1013 to 1.0×1016 Ω·cm when measured according to JIS K6723, and comprises: 100 parts by weight of a chlorine-containing resin, and 1.5 to 10 parts by weight of Mg—Al-based hydrotalcite-type particles having a composition represented by the formula: [MgxCay].Alz.(OH)2.An−p.mH2O wherein 0.2≦z/(x+z)≦0.6; 0.01≦y/(x+z)≦0.20; x+y+z=1; p=(2(x+y−1)+3z)/n; A is a n-valent anion; and m is more than 0 and not more than 0.75, having a plate surface diameter of 0.1 to 1.0 μm and a thickness of 0.02 to 0.08 μm, and containing calcium at a molar ratio of Ca to a sum of Mg and Al of 0.01:1 to 0.20:1, and having a heat-resisting time of not less than 4 hours upon a chlorine-containing resin composition containing the Mg—Al-based hydrotalcite-type particles.
摘要翻译：本发明的电线覆盖用含氯树脂组合物的热稳定性不低于240分钟，体积电阻率为5.0×10 13〜1.0×10 16，根据JIS K6723测量时，SUP> Omeg·cm，包含：100重量份含氯树脂和1.5〜10重量份具有式（I）所示组成的Mg-Al系水滑石型颗粒，：<？in-line-formula description =“In-line Formulas”end =“lead”？> [Mg Ca /SUB>.(OH)₂.A^n-_p.mH₂O其中0.2 <= z /（x + z）<= 0.6; 0.01 <= y /（x + z）<= 0.20; x + y + z = 1; p =（2（x + y-1）+ 3z）/ n; A是n价阴离子; m为0以上且0.75以下，板表面直径为0.1〜1.0μm，厚度为0.02〜0.08μm，Ca与Mg与Al之和的摩尔比为0.01： 1〜0.20：1，并且在含有Mg-Al系水滑石类粒子的含氯树脂组合物上具有不低于4小时的耐热时间。

4. 发明授权

US3989799A Divalent metal salts of dodecametal triaconta carbonyls 失效
标题翻译：十二烷基三羧酸羰基的二价金属盐
公开(公告)号：US3989799A
公开(公告)日：1976-11-02
申请号：US455379
申请日：1974-03-27
申请人： Earle S. Brown
发明人： Earle S. Brown
IPC分类号： B01J31/20 , C01G1/04 , C07C29/156 , C07C29/157 , C07C29/158 , C01F13/00
CPC分类号： C07C29/158 , B01J31/20 , C01G1/04 , C07C29/156 , C07C29/157 , B01J2231/641 , B01J2231/648 , B01J2531/0211 , B01J2531/822 , B01J2531/827 , B01J2531/845 , B01J2531/96 , Y02P20/52
摘要： This invention relates to novel carbonyl mixed metal salts, containing more than one metal and having the formula:M [T.sub.y T'.sub.12.sub.-y (CO).sub.30 ]wherein M is a divalent metal cation which is one of beryllium, magnesium, calcium, strontium, radium, manganese, iron, ruthenium, cobalt, nickel, palladium, platinum, zinc, cadmium, mercury, cerium and europium, T and T' are each different metals selected from the group consisting of cobalt, iridium and rhodium, and y may be any whole number between 1 and 11.These compounds are useful catalysts in the reaction between carbon monoxide and hydrogen to produce oxygenated compounds such as methanol, ethylene glycol, glycerine and 1,2-propylene glycol.
摘要翻译：本发明涉及含有多于一种金属并具有下式的新型羰基混合金属盐：

5. 发明授权

US3966886A Method of preparing and isolating metal hydrocarbonyls and recovery of pure metals therefrom 失效
标题翻译：制备和分离金属烃基并从中回收纯金属的方法
公开(公告)号：US3966886A
公开(公告)日：1976-06-29
申请号：US213725
申请日：1971-12-29
申请人： Lubertus Bakker
发明人： Lubertus Bakker
IPC分类号： C01G1/04
CPC分类号： C01G1/04
摘要： This invention comprises a novel method for the preparation of metal hydrocarbonyls of metals of Groups 1b, 2b, 3b, 4b, 5b, 6b, 7b and 8 of the Periodic Table of the Elements and the attendant method for isolation of pure metals by the separation of a single metal as a metal hydrocarbonyl from any mixture and the subsequent decomposition of the metal hydrocarbonyl to metal powder. The methods of this invention are of particular value in recovering valuable metals in pure state from such sources as exhausted or poisoned metal-based catalysts, low grade ores, filter cakes or mining tailings. Gaseous metal hydrocarbonyl products of this invention also make possible isotope separation.
摘要翻译：本发明包括用于制备元素周期表第1b，2b，3b，4b，5b，6b，7b和8族金属的金属烃基的新方法和通过分离分离纯金属的附带方法作为任何混合物的金属烃基的单一金属，随后将金属烃基分解成金属粉末。本发明的方法在从诸如排出或中毒的金属基催化剂，低等级矿石，滤饼或采矿尾矿的源中回收纯状态的有价值金属中具有特别的价值。本发明的气态金属烃基产物也可能产生同位素分离。

6. 发明授权

US3880612A Stabilization of metal carbonyls 失效
标题翻译：金属羰基化物的稳定化
公开(公告)号：US3880612A
公开(公告)日：1975-04-29
申请号：US35413173
申请日：1973-04-24
申请人： OSTERGREN JARL OLLE BORJE , REISINGER KURT HANS
发明人： OSTERGREN JARL OLLE BORJE , REISINGER KURT HANS
IPC分类号： C01G1/04 , C07F5/06 , C10L1/10 , C10L1/12 , C10L1/14 , C10L1/18 , C10L1/30 , C10L1/32
CPC分类号： C10L1/10 , C01G1/04 , C07F5/066 , C10L1/103 , C10L1/1241 , C10L1/14 , C10L1/1814 , C10L1/1828 , C10L1/301 , C10L1/305
摘要： A process for stabilizing solutions of metal carbonyls in organic solvents, preferably in hydrocarbons, in which one or more aluminum-containing, organic compounds are dissolved in the solutions as stabilizers. The aluminum in such compounds is directly bonded to carbon and/or oxygen atoms. More specifically, the aluminum containing organic compounds are reaction products between aluminum alkoxides and one or more compounds having the formula:

WHEREIN R1 represents hydrogen, alkyl having up to 8 carbon atoms, aryl or aralkyl having up to 10 carbon atoms, alkoxy having up to 8 carbon atoms, aryloxy or aralkoxy having up to 10 carbon atoms, or a group having the formula:

AND THE GROUPS R2, R3, R4 and R5 each, and independently of each other, represent hydrogen, alkyl having up to 8 carbon atoms, or aryl or aralkyl having up to 10 carbon atoms. The aluminumcontaining organic compounds can be added to the solutions of metal carbonyls in an amount corresponding to 1 part by weight of aluminum to 50 to 200 parts by weight of the metal in the metal carbonyl.
摘要翻译：一种用于将一种或多种含铝的有机化合物溶解在有机溶剂中，优选在烃中的金属羰基化溶液作为稳定剂的方法。这种化合物中的铝直接键合到碳和/或氧原子上。更具体地说，含铝有机化合物是烷氧基铝与一种或多种下式的化合物之间的反应产物：

7. 发明授权

US3878214A Trivalent metal salts of dodecarhodiumtriaconta carbonyls 失效
标题翻译：十二烷基三羰基的三价金属盐
公开(公告)号：US3878214A
公开(公告)日：1975-04-15
申请号：US37134173
申请日：1973-06-19
申请人： UNION CARBIDE CORP
发明人： WALKER WELLINGTON E , BROWN EARLE S , PRUETT ROY L
IPC分类号： B01J31/20 , C01G1/04 , C01G55/00 , C07C29/158
CPC分类号： B01J31/20 , B01J2231/641 , B01J2231/648 , B01J2531/0211 , B01J2531/822 , B01J2531/96 , C01G1/04 , C01G55/007 , C07C29/158
摘要： This invention relates to novel rhodium carbonyl salts of trivalent metals having the formula
摘要翻译：本发明涉及具有式M2 [Rh12（CO）30] 3的三价金属的新型铑羰基盐，其中M是选择类型的三价金属阳离子。这些化合物是在一氧化碳和氢气之间的反应中的有用的催化剂，以产生氧化的化合物如甲醇，乙二醇，甘油和1,2-丙二醇，如共同待批申请的Ser。第371,350号，即日提交。

8. 发明授权

US2964387A Method of preparing group vi-b metal hexacarbonyls 失效
标题翻译：制备vi-b族金属六羰基的方法
公开(公告)号：US2964387A
公开(公告)日：1960-12-13
申请号：US78307058
申请日：1958-12-29
申请人： ETHYL CORP
发明人： PODALL HAROLD E , HYMIN SHAPIRO
IPC分类号： C01G1/04
CPC分类号： C01G1/04

9. 发明授权

US2952518A Manufacture of metal carbonyls 失效
公开(公告)号：US2952518A
公开(公告)日：1960-09-13
申请号：US2425660
申请日：1960-04-25
申请人： ETHYL CORP
发明人： PODALL HAROLD E , HYMIN SHAPIRO
IPC分类号： C01G1/04
CPC分类号： C01G1/04

10. 发明授权

US2601022A Purification of metal carbonyls 失效
标题翻译：金属羰基化物的纯化
公开(公告)号：US2601022A
公开(公告)日：1952-06-17
申请号：US16655250
申请日：1950-06-06
申请人： GEN ELECTRIC
发明人： HURD DALLAS T
IPC分类号： C01G1/04
CPC分类号： C01G1/04

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