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    • 8. 发明授权
    • Process for manufacture of lithium hexafluorophosphate
    • 六氟磷酸锂的制造方法
    • US5935541A
    • 1999-08-10
    • US89188
    • 1998-06-03
    • Philippe BonnetSylvain PerdrieuxSteven G. Schon
    • Philippe BonnetSylvain PerdrieuxSteven G. Schon
    • C01B25/455C01D15/00C01D15/04C01B25/10
    • C01D15/005
    • The process of the present invention consists in bringing into contact, on the one hand, (A) gaseous phosphorus pentafluoride or a gaseous mixture comprising phosphorus pentafluoride and hydrochloric acid, and, on the other hand, (B) a solution of lithium fluoride in hydrofluoric acid, in a column (10) having a sufficient number of transfer units to carry out the reaction of PF.sub.5 with LiF under the chosen conditions of temperature, of pressure and of molar ratio of the two contrasting reactants and with complete or substantially complete absorption of the PF.sub.5 in the column. This process makes it possible to solve the problems of blockage by preventing recrystallizations of salts; to discharge the heat given off by the reaction by the evaporation of a portion of the HF; and to separate the HCl which may be contained in the starting PF.sub.5, without loss of PF.sub.5, thus allowing subsequent recovery/value enhancement of this HCl. Moreover, this process is very simple, with a very small number of stages, which makes it possible to avoid any entry of air or moisture capable of contaminating the final LiPF.sub.6.
    • 本发明的方法是一方面与(A)气态五氟化磷或包含五氟化磷和盐酸的气态混合物接触,另一方面,(B)将氟化锂溶液 氢氟酸在具有足够数目的转移单元的塔(10)中,在选择的温度,压力和两种对比反应物的摩尔比条件下进行PF5与LiF的反应,并且具有完全或基本上完全的吸收 的PF5在列中。 该方法可以通过防止盐的再结晶来解决堵塞的问题; 通过HF的一部分的蒸发来排出由反应产生的热量; 并分离可能包含在起始PF5中的HCl,而不损失PF5,从而允许该HCl随后的恢复/增值。 此外,该方法非常简单,具有非常少的阶段,这使得可以避免任何进入能够污染最终LiPF 6的空气或水分。